Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 19, Problem 27P
Interpretation Introduction

Interpretation:

In citric acid cycle, the enzyme having a name that indicates the reverse reaction has to be identified.

Concept Introduction:

Protein catabolism: It is defined as breakdown of proteins into smaller units that is into amino acids. These amino acids get transported finally polymerized to give new proteins.

Citric Acid Cycle: It involves 8 series reaction which converts acetyl group present in acetyl coenzyme A into 2 CO2 molecules.

Substrate: The molecule where the reaction takes place with help of enzymes.

Enzyme: The proteins that helps chemical reaction to occur.

Oxidation: The oxidation is reaction that involves addition of oxygen atom or loss of electrons or removal of hydrogen atom present in the chemical compound.

Reduction: It involves removal of oxygen or addition of hydrogen to the chemical compound.

Coenzyme: They are non-proteins molecules which helps enzymes for catalyzing the reaction.

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There are eight chemical reactions that occur in the citric acid cycle process.  The reactions of the citric acid cycle are shown in the figure below. You were introduced to several classes of organic reactions.  These classes include esterification, decarboxylation, hydration reactions, dehydration of alcohols, oxidation of alcohols, oxidation of aldehydes, reduction of aldehydes, and reduction of ketones.  Find at least one of these reaction classes in the citric acid cycle.  List the reaction number and the reaction. Write a sentence or two on how you were able to make the classification.
Write a balanced chemical reaction for the catalyzed by citrate synthase in the acetic acid cycle and determine the type of the reaction.
Which of the eight enzymes in the citric acid cycle has a name that refers to the reverse reaction?
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