Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 19, Problem 23P
Interpretation Introduction
Interpretation:
The reactions in the citric acid cycle which forms a product with a new asymmetric centre has to be given.
Concept Introduction:
Citric acid cycle: The cycle in which acetyl group of each molecule of
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Which reactions in the citric acid cycle form a product with a new asymmetric center?
The image below shows the reactions of the citric acid cycle. Label the reaction types on the diagram.
COO
CH-OH
CH₂
COO
8-5-9-8
HC
H₂O
NADH
+H+
NAD+-
FADH2
"7
FAD
COO
C=O
CH₂
COO™
COO
CH3-C-COA + H₂O
acetyl-CoA COA
COO™
Ī
CH₂
HỌ—C—COO
CH₂
COO™
COO
HO-C-H
COO™
COO™
CH₂
CH-COO
NAD+
NAD+
+ COA
Attempt 2
NADH + H+
+ CO2
NADH + H+
+ CO2
COO™
CH₂
CH₂
C=O
COO™
Which intermediate(s) in the citric acid cycle contain one chirality center? Which intermediate(s) contain a tertiary alcohol?
Chapter 19 Solutions
Essential Organic Chemistry, Global Edition
Ch. 19.4 - Prob. 1PCh. 19.4 - How many molecules of NADH are formed from the...Ch. 19.4 - Why does the OH group add to the -carbon rather...Ch. 19.5 - Prob. 4PCh. 19.5 - Prob. 5PCh. 19.5 - The oxidation of glyceraldehyde-3-phosphate to...Ch. 19.5 - Prob. 7PCh. 19.6 - Prob. 8PCh. 19.6 - Prob. 9PCh. 19.6 - Propose a mechanism for the reduction of...
Ch. 19.7 - Prob. 11PCh. 19.8 - Acid-catalyzed dehydration reactions are normally...Ch. 19.8 - Prob. 13PCh. 19.8 - Prob. 14PCh. 19.8 - Prob. 15PCh. 19.9 - Prob. 16PCh. 19.10 - a. What is the name of the enzyme that converts...Ch. 19.13 - Prob. 18PCh. 19 - Prob. 19PCh. 19 - Prob. 20PCh. 19 - Prob. 21PCh. 19 - Prob. 22PCh. 19 - Prob. 23PCh. 19 - Prob. 24PCh. 19 - Prob. 25PCh. 19 - Prob. 26PCh. 19 - Prob. 27PCh. 19 - Prob. 28PCh. 19 - Prob. 29PCh. 19 - Prob. 30PCh. 19 - Prob. 31PCh. 19 - Prob. 32PCh. 19 - Prob. 33PCh. 19 - Prob. 34PCh. 19 - Prob. 35PCh. 19 - Prob. 36PCh. 19 - Prob. 37PCh. 19 - Prob. 38PCh. 19 - Prob. 39PCh. 19 - Prob. 40PCh. 19 - Prob. 41PCh. 19 - Prob. 42PCh. 19 - Prob. 43PCh. 19 - Prob. 44PCh. 19 - UDP-galactose-4-epimerase converts UDP-galactose...Ch. 19 - A student is trying to determine the mechanism for...Ch. 19 - What would be the results of the experiment in...
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- How many electron carrier molecules (both NADH and FADH₂) are made per glucose put in to glycolysis? How many electron carrier molecules (both NADH and FADH₂) are made per pyruvate put in to the Krebs Cycle? How many electron carrier molecules (both NADH and FADH₂) are made by the Krebs Cycle per glucose consumed by the organism? How many electron carrier molecules in total (both NADH and FADH₂) have been made from a single glucose after both glycolysis and the Krebs Cycle? How many electrons are being carried from glucose at this point (Hint: 2 per molecule)?arrow_forwardWhich process below produces FADH2? The citric acid cycle The conversion of pyruvate Oxidative Phosphorylation O Glycolysisarrow_forwardGlucose-6-phosphate detours to the hexose monophosphate shunt pathway in erythrocytes because: Question 73 options: A) They lack mitochondria making them incapable of the TCA cycle B) They lack endoplasmic reticulum making them incapable of the TCA cycle C) Erythrocytes have no energy needs D) Erythrocytes utilize glucose directly for energyarrow_forward
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