Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 19, Problem 23P
Interpretation Introduction

Interpretation:

The reactions in the citric acid cycle which forms a product with a new asymmetric centre has to be given.

Concept Introduction:

Citric acid cycle: The cycle in which acetyl group of each molecule of acetyl-CoA is converted into two molecules of CO2  It is a series of eight reactions.

NAD+Molecule: It is the oxidized form of Nicotinamide adenine dinucleotide (NAD) which exists in all cells and needed for activation of enzymes.

NADHmolecule: It is coenzyme which gets oxidized on reducing another compound. The oxidized form of NADHisNAD+.

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Which reactions in the citric acid cycle form a product with a new asymmetric center?
The image below shows the reactions of the citric acid cycle. Label the reaction types on the diagram. COO CH-OH CH₂ COO 8-5-9-8 HC H₂O NADH +H+ NAD+- FADH2 "7 FAD COO C=O CH₂ COO™ COO CH3-C-COA + H₂O acetyl-CoA COA COO™ Ī CH₂ HỌ—C—COO CH₂ COO™ COO HO-C-H COO™ COO™ CH₂ CH-COO NAD+ NAD+ + COA Attempt 2 NADH + H+ + CO2 NADH + H+ + CO2 COO™ CH₂ CH₂ C=O COO™
Which intermediate(s) in the citric acid cycle contain one chirality center? Which intermediate(s) contain a tertiary alcohol?
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