Thermodynamics: An Engineering Approach
9th Edition
ISBN: 9781259822674
Author: Yunus A. Cengel Dr., Michael A. Boles
Publisher: McGraw-Hill Education
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Chapter 16.6, Problem 55P
(a)
To determine
The value of enthalpy of reaction.
(b)
To determine
The value of equilibrium constant for the process.
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Students have asked these similar questions
Using the enthalpy of reaction he data at 3000K and the Kp value at 2800 K of the combustion process A2
+ B2 = 2AB (Kp = 0.385 @2800 K)
1.
a) Estimate the Kp value at 3200 K
b) Determine the equilibrium mole fraction of AB when the pressure is 101 kPa and the temperature is 3200 K
ħ298K
ħ3000K
kJ/kmol
kJ/kmol
kJ/kmol
A2
8,682
106,780
B2
8,669
105,115
АВ
91,290
94,970
Q1) A constant volume tank contain 1 mole of C8H18 and 12 mole of O2 gas at a temperature of 25 °C and 1 bar. The contents of the tank is ignited and C;H14 is burned completely and final products temperature is found to be 1700 K. Determine the heat transfer during this process. ( take AHo = -47800 kJ/kg).
A 10% rich mixture of Heptane (C,H16) and air is initially at a pressure of 1 bar and
temperature of 100°C, and is polytropically compressed through a volumetric ratio of 6 to
1. It is ignited and adiabatic combustion proceeds at constant volume. The maximum
temperature reached is 2627°C and at this temperature the equilibrium constants are
PH₂OPCO
= 6.72
PCO₂PH₂
P²coPo₂
= 0.054
Pco2po
' = 1bar is a reference pressure for the equilibrium constants. if the constituents of the
gas are CO2, CO, H₂O, H₂, O2 and N₂:
(a) Calcuate the reaction equation without dissociation
(b) Calculate the equilibrium product composition.
(c) Verify that approximately 30.2 % of the carbon has burned incompletely.
Notes:
the number of moles is not conserved in this reaction!
You may use any method to solve the (nonlinear) equations you derive.
Chapter 16 Solutions
Thermodynamics: An Engineering Approach
Ch. 16.6 - Why is the criterion for chemical equilibrium...Ch. 16.6 - Write three different KPrelations for reacting...Ch. 16.6 - Is a wooden table in chemical equilibrium with the...Ch. 16.6 - A reaction chamber contains a mixture of CO2, CO,...Ch. 16.6 - A reaction chamber contains a mixture of N2and N...Ch. 16.6 - A reaction chamber contains a mixture of CO2, CO,...Ch. 16.6 - Which element is more likely to dissociate into...Ch. 16.6 - Prob. 8PCh. 16.6 - Prob. 9PCh. 16.6 - Prob. 10P
Ch. 16.6 - Prob. 11PCh. 16.6 - Prob. 12PCh. 16.6 - Prob. 13PCh. 16.6 - Prob. 14PCh. 16.6 - Prob. 15PCh. 16.6 - Prob. 16PCh. 16.6 - Prob. 17PCh. 16.6 - Prob. 18PCh. 16.6 - Prob. 19PCh. 16.6 - Prob. 20PCh. 16.6 - Prob. 21PCh. 16.6 - Prob. 22PCh. 16.6 - Prob. 23PCh. 16.6 - Determine the equilibrium constant KP for the...Ch. 16.6 - Prob. 26PCh. 16.6 - Prob. 27PCh. 16.6 - Carbon monoxide is burned with 100 percent excess...Ch. 16.6 - Prob. 30PCh. 16.6 - Prob. 31PCh. 16.6 - Estimate KP for the following equilibrium reaction...Ch. 16.6 - Prob. 33PCh. 16.6 - A mixture of 3 mol of N2, 1 mol of O2, and 0.1 mol...Ch. 16.6 - Prob. 35PCh. 16.6 - Prob. 36PCh. 16.6 - Prob. 37PCh. 16.6 - Prob. 38PCh. 16.6 - Prob. 40PCh. 16.6 - What is the equilibrium criterion for systems that...Ch. 16.6 - Prob. 43PCh. 16.6 - Prob. 44PCh. 16.6 - Prob. 45PCh. 16.6 - Prob. 47PCh. 16.6 - Prob. 48PCh. 16.6 - Prob. 51PCh. 16.6 - Prob. 52PCh. 16.6 - Prob. 53PCh. 16.6 - Prob. 54PCh. 16.6 - Prob. 55PCh. 16.6 - Prob. 56PCh. 16.6 - Prob. 58PCh. 16.6 - Prob. 59PCh. 16.6 - Prob. 60PCh. 16.6 - Prob. 61PCh. 16.6 - Using the Henrys constant data for a gas dissolved...Ch. 16.6 - Prob. 63PCh. 16.6 - Prob. 64PCh. 16.6 - Prob. 65PCh. 16.6 - Prob. 66PCh. 16.6 - A liquid-vapor mixture of refrigerant-134a is at...Ch. 16.6 - Prob. 68PCh. 16.6 - Prob. 69PCh. 16.6 - An oxygennitrogen mixture consists of 30 kg of...Ch. 16.6 - Prob. 71PCh. 16.6 - Prob. 72PCh. 16.6 - Prob. 73PCh. 16.6 - Prob. 74PCh. 16.6 - Prob. 75PCh. 16.6 - Prob. 76PCh. 16.6 - An ammoniawater absorption refrigeration unit...Ch. 16.6 - Prob. 78PCh. 16.6 - Prob. 79PCh. 16.6 - Prob. 80PCh. 16.6 - One lbmol of refrigerant-134a is mixed with 1...Ch. 16.6 - Prob. 82RPCh. 16.6 - Prob. 83RPCh. 16.6 - Prob. 84RPCh. 16.6 - Prob. 85RPCh. 16.6 - Prob. 88RPCh. 16.6 - Prob. 89RPCh. 16.6 - Prob. 90RPCh. 16.6 - Prob. 91RPCh. 16.6 - Prob. 92RPCh. 16.6 - A constant-volume tank contains a mixture of 1 mol...Ch. 16.6 - Prob. 94RPCh. 16.6 - Prob. 95RPCh. 16.6 - Prob. 96RPCh. 16.6 - Prob. 97RPCh. 16.6 - Prob. 99RPCh. 16.6 - Consider a glass of water in a room at 25C and 100...Ch. 16.6 - Prob. 101RPCh. 16.6 - Prob. 102RPCh. 16.6 - Prob. 105RPCh. 16.6 - Prob. 106RPCh. 16.6 - Prob. 107RPCh. 16.6 - Prob. 108RPCh. 16.6 - Prob. 109FEPCh. 16.6 - Prob. 110FEPCh. 16.6 - Prob. 111FEPCh. 16.6 - Prob. 112FEPCh. 16.6 - Prob. 113FEPCh. 16.6 - Prob. 114FEPCh. 16.6 - Propane C3H8 is burned with air, and the...Ch. 16.6 - Prob. 116FEPCh. 16.6 - Prob. 117FEPCh. 16.6 - The solubility of nitrogen gas in rubber at 25C is...
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