Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 16, Problem 16.44QE
(a)
Interpretation Introduction
Interpretation:
Initial pH, final pH, and change in pH, when
(b)
Interpretation Introduction
Interpretation:
Initial pH, final pH, and change in pH, when
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You are asked to prepare a pH = 3.00 buffer solution startingfrom 1.25 L of a 1.00 M solution of hydrofluoric acid(HF) and any amount you need of sodium fluoride (NaF).(a) What is the pH of the hydrofluoric acid solution priorto adding sodium fluoride? (b) How many grams of sodiumfluoride should be added to prepare the buffer solution?Neglect the small volume change that occurs when the sodiumfluoride is added.
(a) Calculate the pH in a solution prepared by dissolving 0.050 mol of acetic acid and 0.020 mol of sodium acetate in water and adjusting the volume to 500 mL.(b) Suppose 0.010 mol of NaOH is added to the buffer from part (a).Calculate the pH of the solution that results.
A buffer solution is prepared from equal volumes of 0.200 M acetic acid and 0.600 M sodium acetate. Use 1.80 × 10−5 as Ka for acetic acid.(a) What is the pH of the solution?(b) Is the solution acidic or basic?(c) What is the pH of a solution that results when 3.00 mL of 0.034 M HCl is added to 0.200 L of the original buffer?
Chapter 16 Solutions
Chemistry: Principles and Practice
Ch. 16 - Prob. 16.1QECh. 16 -
Sketch a titration curve for the titration of...Ch. 16 - Prob. 16.4QECh. 16 - Prob. 16.5QECh. 16 - Explain why the HendersonHasselbalch equation...Ch. 16 - Prob. 16.7QECh. 16 - Prob. 16.8QECh. 16 - Prob. 16.9QECh. 16 - Prob. 16.11QECh. 16 - Prob. 16.13QE
Ch. 16 - Prob. 16.14QECh. 16 - Prob. 16.15QECh. 16 - Prob. 16.16QECh. 16 - Prob. 16.17QECh. 16 - Prob. 16.18QECh. 16 - Calculate the pH during the titration of 100.0 mL...Ch. 16 - Prob. 16.20QECh. 16 - Prob. 16.21QECh. 16 - Calculate the pH during the titration of 50.00 mL...Ch. 16 - Prob. 16.23QECh. 16 - Calculate the pH during the titration of 50.00 mL...Ch. 16 - Prob. 16.25QECh. 16 - Prob. 16.26QECh. 16 - Prob. 16.27QECh. 16 - Prob. 16.28QECh. 16 -
Calculate the pH of solutions that are
0.25 M...Ch. 16 - Prob. 16.30QECh. 16 - Prob. 16.31QECh. 16 - Prob. 16.32QECh. 16 - Prob. 16.35QECh. 16 - Prob. 16.36QECh. 16 - Prob. 16.37QECh. 16 - Prob. 16.38QECh. 16 - Prob. 16.39QECh. 16 -
How many grams of sodium acetate must be added to...Ch. 16 - Prob. 16.41QECh. 16 - Prob. 16.42QECh. 16 - A buffer solution that is 0.100 M acetate ion and...Ch. 16 - Prob. 16.44QECh. 16 - Prob. 16.45QECh. 16 - Prob. 16.46QECh. 16 - Prob. 16.47QECh. 16 - Prob. 16.48QECh. 16 - Estimate the pH that results when the following...Ch. 16 - Estimate the pH that results when the following...Ch. 16 - Prob. 16.51QECh. 16 - Prob. 16.52QECh. 16 - Prob. 16.53QECh. 16 - Prob. 16.54QECh. 16 - Prob. 16.55QECh. 16 - Prob. 16.56QECh. 16 - Prob. 16.57QECh. 16 - Prob. 16.58QECh. 16 - Prob. 16.59QECh. 16 - Consider all acid-base indicators discussed in...Ch. 16 - Prob. 16.61QECh. 16 - Chloropropionic acid, ClCH2CH2COOH, is a weak...Ch. 16 - Prob. 16.63QECh. 16 - Prob. 16.64QECh. 16 - Prob. 16.65QECh. 16 - Write the chemical equilibrium and expression for...Ch. 16 - Calculate the pH of 0.010 M ascorbic acid.Ch. 16 - Prob. 16.68QECh. 16 - Prob. 16.69QECh. 16 - Prob. 16.70QECh. 16 - Prob. 16.71QECh. 16 - Prob. 16.72QECh. 16 - Prob. 16.73QECh. 16 - Prob. 16.74QECh. 16 - Prob. 16.75QECh. 16 - Which compound in each pair is more soluble in...Ch. 16 - Prob. 16.77QECh. 16 - Prob. 16.78QECh. 16 - Prob. 16.79QECh. 16 - Calculate the pH of each of the following...Ch. 16 - Write the chemical equation and the expression for...Ch. 16 - Prob. 16.82QECh. 16 - Prob. 16.83QECh. 16 - Phenolphthalein is a commonly used indicator that...Ch. 16 - Prob. 16.85QECh. 16 - Prob. 16.86QECh. 16 - Prob. 16.87QECh. 16 - Determine the dominant acid-base equilibrium that...Ch. 16 - Prob. 16.89QECh. 16 - Prob. 16.90QECh. 16 - Prob. 16.91QECh. 16 - Prob. 16.92QECh. 16 - Prob. 16.93QECh. 16 - Prob. 16.94QECh. 16 - Prob. 16.95QECh. 16 - Prob. 16.96QECh. 16 - Prob. 16.97QECh. 16 - A monoprotic organic acid that has a molar mass of...Ch. 16 - A scientist has synthesized a diprotic organic...Ch. 16 - Prob. 16.100QECh. 16 - What is a good indicator to use in the titration...Ch. 16 - Prob. 16.102QECh. 16 - A bottle of concentrated hydroiodic acid is 57% HI...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to enough water to make 155 mL of solution. (a) What is the pH of the buffer? (b) If enough water is added to double the volume, what is the pH of the solution?arrow_forwardWhat is the pH of a buffer that is 0.150 M in a weak acid and 0.150 M in the acids conjugate base? The acids ionization constant is 6.8 106.arrow_forward8-71 Explain why you do not need to know the chemical formula of a buffer compound to use it.arrow_forward
- Consider the titration of HF (K a=6.7104) with NaOH. What is the pH when a third of the acid has been neutralized?arrow_forwardA 0.1724-g sample of an unknown monoprotic acid was dissolved in 26.9 mL of water and titrated with 0.0623 M NaOH solution. The volume of base required to bring the solution to the equivalence point was 19.8 mL. (a) Calculate the molar mass of the acid. (b) After 11.5 mL of base had been added during the titration, the pH was determined to be 5.66. What is the Ka of the unknown acid?arrow_forwardA buffer is prepared by adding 20.0 g of sodium acetate(CH3COONa) to 500 mL of a 0.150 M acetic acid(CH3COOH) solution. (a) Determine the pH of the buffer.(b) Write the complete ionic equation for the reaction thatoccurs when a few drops of hydrochloric acid are added tothe buffer. (c) Write the complete ionic equation for the reactionthat occurs when a few drops of sodium hydroxidesolution are added to the buffer.arrow_forward
- A 0.1276 g sample of an unknown monoprotic acid was dissolved in 25.0 mL of water and titrated with 0.0633 M NaOH solution. The volume of base required to bring the solution to the equivalence point was 18.4 mL. (a) Calculate the molar mass of the acid. (b) After 10.0 mL of base had been added during the titration, the pH was determined to be 5.87. What is the Ka of the unknown acid? *only need help with barrow_forward(a) Calculate the pH of a buffer solution containing 0.40 mole of KF and 0.50 mol of HF in 1.50 liter solution. (Ka of HF is 7.2*10–4); 15.0 mL of 1.00 M HCl is added to the original buffer in question (a). (b) Show the equation of reaction which take place when HCl is added. (c) What will the pH of the buffer solution in question (a) be after the addition of 15.0 mL of 1.00 M HCl.arrow_forwardA buffer solution is prepared by dissolving 4.7 g of nitrous acid, HNO2 , and 13.8 g of sodium nitrite, NaNO2, in 1.0 liter of solution. (a) Calculate the pH of the buffer. (b) Calculate the pH of the solution which results when the following are added to separate 100 mL portions of the buffer: (i) 5.0 mmol of HCI; (ii) 5.0 mmol of NaOH. Ka = 4.5 x 104 %3Darrow_forward
- Which of the following combination of solutions will form a buffer solution? (A) 50.0 mL of 0.20 M NH3 + 50.0 mL of 0.10 M HCl; (B) 50.0 mL of 0.20 M NH3 + 50.0 mL of 0.10 M NaOH; (C) 50.0 mL of 0.20 M HCl + 50.0 mL of 0.10 M NH3; (D) 50.0 mL of 0.20 M NaOH + 50.0 mL of 0.10 M HCl.arrow_forwardCalculate the pH at the following points in a titration of 40.0 mL of 0.100 M barbituric acid(Ka = 9.8 × 10−5) with 0.100 M KOH. (a) no KOH added (b) 20.0 mL of KOH solution added (c)39.0 mL of KOH solution added (d) 40.0 mL of KOH solution added (e) 41.0 mL of KOHSketch an appropriate pH titration curve indicating the buffer region, equivalence point,and excess base region. Why is the pH at the equivalence point not 7.00?arrow_forwardIn each of the following questions, assume that there is no volume change when HCl is added to water in part (a) or the phosphate buffer in part (c). (a) Calculate the pH when 0.091 moles of HCl are added to 1.000 liter of water. (b) What is the difference between the pH of pure water (pH 7.00) and the pH of the solution after HCl was added? (c) Calculate the pH when 0.091 moles of HCl are added to 1.000 liters of a buffer containing 0.352M KH2PO4 and 0.321 M K2HPO4. (d) The pH before the HCl was added is equal to 7.168. What is the difference between the pH before adding the HCl and after adding the HCl?arrow_forward
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