Concept explainers
(a)
Interpretation:
The product for the exothermic reaction of nitrobenzene with chlorine gas and
Concept introduction:
An electrophilic
(b)
Interpretation:
The product for the reaction of nitrobenzene with fuming
Concept introduction:
An electrophilic aromatic substitution reaction is a type of reaction in which an electrophile substitutes a hydrogen atom of the aromatic ring. Aromatic ring does not easily undergo nucleophilic substitution reaction; however, it undergoes electrophilic substitution reaction easily.
(c)
Interpretation:
The product for the reaction of nitobenzene with acetyl chloride and
Concept introduction:
Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides.
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ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
- Write the reagent or draw structures of the starting material or organic product(s) in the following reactions. If more than one product is formed, identify the major product where possible. (a) (b) HO OH OH H2SO4 ? Cl₂ ? FeCl3arrow_forward4. Write the formula and name for the product when cyclopentene reacts with (a) Cl2(b) HBr(c) H2, Pt (d) H2O, H+arrow_forwardConsider the following structural formulas. OH -осн A в D E (a) Which of the compounds A-E can easily be oxidized? (b) Provide the typical oxidation products for all compounds selected in (a). (c) Explain why the compounds not selected in (a) cannot be easily oxidized.arrow_forward
- provide the structure of the intermediate and product for the following reaction : (c) H CH,OH/H (C)arrow_forwardDraw the structures of the following compounds:(a) Ethanoic acid(b) Bromopentane(c) Butanonearrow_forwarda) If the pH value of an aqueous solution of trimethylamine [(CH3) 3N] is 10.75, what should be the molarity of this solution? (CH3) 3N + H2O ↔ (CH3) 3NH + + OH-, Kb = 6.3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3 + Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7.4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .arrow_forward
- Identify (A) in the following reaction. 2H2 Pt (A) KMNO4 Warm conc. || С — С — о—н |CO,H + HO CO2H cis-cyclo hexane 1,2-dicarboxylic acid (a) (b) (c) (d)arrow_forwarda) If the pH value of an aqueous solution of trimethylamine [(CH3)3N] is 10.75, what should be the molarity of this solution? (CH3)3N + H2O ↔ (CH3)3NH+ + OH-, Kb = 6,3 × 10-5 b) What will be the pH of the solution prepared by dissolving 8.35 g of aniline hydrochloride (C6H5NH3+Cl-) in 750 mL of 0.215 M aniline (C6H5NH2)? Is this solution an effective buffer? Explain (Kb = 7,4 × 10-10 for aniline, C: 12.0 g / mol, H: 1.0 g / mol, N: 14.0 g / mol, Cl: 35.4 g / mol) .arrow_forwardDraw the reaction products of the following reactions of the compound 1-pentanol and name the compounds according to IUPAC! (a) B-elimination of H20 (b) SN reaction in the presence of hydrochloric acid (c) Condensation with acetic acid (d) Oxidation to the corresponding carbonyl compound (e) Condensation of two butanol moleculesarrow_forward
- When the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?arrow_forwardWhen aniline, C6H5NH2(Kb=7.41010) , reacts with a strong acid, its conjugate acid, C6H5NH3+, is formed. Calculate the pH of a 0.100 M solution of C6H5NH3+ and compare it with the pH of acetic acid (Ka=1.86105) .arrow_forwardName and draw a structural formula for the major product of each alkene addition reaction: CH S (a) CH₂C=CH₂ + HI →→→→ (b) CH 3 + HClarrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning