ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
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Chapter 16, Problem 16.19P
Interpretation Introduction

Interpretation:

Two different methods to prepare the given compound with the help of Friedel-crafts reaction is to be stated.

Concept introduction:

The reaction between acyl chloride with benzene in presence of AlCl3 is a friedal craft acylation reaction. In friedal craft acylation reaction, AlCl3 acts as a lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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When trichloroacetaldehyde is dissolved in water, almost all of it is converted to the hydrate. Chloral hydrate, the product of the reaction, is a sedative that can be lethal. A cocktail laced with it is known—in detective novels,at least—as a “Mickey Finn.” Explain why an aqueous solution of trichloroacetaldehyde is almost all hydrate.
When trichloroacetaldehyde is dissolved in water, almost all of it is converted to the hydrate. Chloral hydrate, the product of the reaction, is a sedative that can be lethal. A cocktail laced with it is known—in detective novels, at least—as a “Mickey Finn.” Explain why an aqueous solution of trichloroacetaldehyde is almost all hydrate.
Provide an explanation (in detail) on how base catalysts speed up nucleophilic reactions of carbonyl compounds.

Chapter 16 Solutions

ORGANIC CHEMISTRY SAPLING ACCESS + ETEX

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