Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Question
Chapter 15.11, Problem 15P
Interpretation Introduction
Interpretation:
The structure of the product including stereochemistry is to be deduced.
Concept Introduction:
The Suzuki cross coupling reaction is the reaction between the organohalide compound and the boronic acid.
This reactionis catalyzed by a pallium complex in which
The stereochemistry of
Other
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V) Outline a synthesis of the following compound from
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CO2H
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Ozonolysis of compound D will produce compound E and compound F as products. Hydrationof compound D will produce compound G as major product. Compound D is a major productobtained from dehydrohalogenation of 2-chloro-3-methylbutane.
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(b)
acid, HNO3 to produce compound L. The reaction of compound L with
bromine, Br2 in the presence of iron tribromide, FeBr3 produced compound
M. Benzene also undergoes Fridel-crafts alkylation reaction with
chloroethane, CH;CH2CI using catalyst N to produce compound P.
Benzene, CeHe undergoes substitution reaction with concentrated nitric
Benzena, CsHe menjalani tindak balas penukargantian dengan asid nitrik,
HNO, pekat untuk menghasilkan sebatian L. Tindak balas sebatian L
dengan bromin, Brz dengan kehadiran ferum tribromida, FeBrs
menghasilkan sebatian M. Benzena juga menjalani tindak balas alkilasi
Fridel-crafts dengan kloroetana, CH3CH2CI dengan menggunakan
pemangkin N untuk menghasilkan sebatian P.
(i)
Draw the structural formula of L, M and P.
Lukiskan formula struktur bagi sebatian L, M dan P.
(ii)
State catalyst N.
Nyatakan pemangkin N.
(iii) Show the formation of electrophile that will be reacted with benzene for the
formation of compound P.
Chapter 15 Solutions
Organic Chemistry - Standalone book
Ch. 15.1 - Each of the following organometallic reagents will...Ch. 15.3 - Write equations showing how you could prepare...Ch. 15.4 - Lithium diisopropylamide is often used as a strong...Ch. 15.5 - Write the structure of the organic product of each...Ch. 15.7 - Prob. 5PCh. 15.8 - Prob. 6PCh. 15.9 - Prob. 7PCh. 15.9 - Like nickel, iron reacts with carbon monoxide to...Ch. 15.9 - Prob. 9PCh. 15.9 - What is the oxidation state of manganese in the...
Ch. 15.9 - Prob. 11PCh. 15.10 - Prob. 12PCh. 15.10 - Prob. 13PCh. 15.11 - Give the structure including stereochemistry of...Ch. 15.11 - Prob. 15PCh. 15.12 - Homogeneous catalytic hydrogenation of the...Ch. 15.12 - Prob. 17PCh. 15.13 - What alkenes are formed from 2-pentene by olefin...Ch. 15.13 - The product of the following reaction was isolated...Ch. 15 - Suggest appropriate methods for preparing each of...Ch. 15 - Prob. 21PCh. 15 - Predict the principal organic product of each of...Ch. 15 - Prob. 23PCh. 15 - Predict the principal organic product of each of...Ch. 15 - Prob. 25PCh. 15 - A different stereoisomer of...Ch. 15 - Prob. 27PCh. 15 - Using phenyllithium and any necessary organic or...Ch. 15 - Prob. 29PCh. 15 - A number of drugs are prepared by reactions in...Ch. 15 - The following conversion was carried out in two...Ch. 15 - Outline syntheses of (a)...Ch. 15 - (S)-(+)-Ibuprofen can be prepared by...Ch. 15 - Like other hydroborations, the reaction of alkynes...Ch. 15 - The sex attractant of the female silkworm has been...Ch. 15 - Prob. 36PCh. 15 - (a) Exaltolide, a musk substance, has been...Ch. 15 - Prob. 38PCh. 15 - Prob. 39PCh. 15 - Cyclobutadiene and...Ch. 15 - Cyclobutadiene and (Cyclobutadiene)tricarbonyliron...Ch. 15 - Cyclobutadiene and...Ch. 15 - Cyclobutadiene and...Ch. 15 - Cyclobutadiene and...
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