Basic Chemistry
Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 15, Problem 63APP

(a)

Interpretation Introduction

Interpretation:

The given redox chemical equation in acidic medium should be balanced.

  Zn(s)+NO3(aq)Zn2+(aq)+NO2(g)

Concept Introduction:

A redox reaction is a chemical reaction in which oxidation and reduction reactions takes place simultaneously. In such type of reaction one of the chemical species is getting oxidized while the other species gets reduced at the same time.

Oxidation state or oxidation number of an atom is defined as the positive or the negative charge that an atom would possess if it is present as ions in the given compound. In such type of reaction, the oxidation state of the atom undergoing oxidation will increase which depends upon the number of electrons lost by a particular atom. Reduction of a chemical species refers to the gain of electrons by the chemical species which results in decrease in oxidation state of that atom.

(b)

Interpretation Introduction

Interpretation:

The given redox chemical equation in acidic medium should be balanced.

  MnO4(aq)+SO32(aq)Mn2+(aq)+SO42(aq)

Concept Introduction:

A redox reaction is a chemical reaction in which oxidation and reduction reactions takes place simultaneously. In such type of reaction one of the chemical species is getting oxidized while the other species gets reduced at the same time.

Oxidation state or oxidation number of an atom is defined as the positive or the negative charge that an atom would possess if it is present as ions in the given compound. In such type of reaction, the oxidation state of the atom undergoing oxidation will increase which depends upon the number of electrons lost by a particular atom. Reduction of a chemical species refers to the gain of electrons by the chemical species which results in decrease in oxidation state of that atom.

(c)

Interpretation Introduction

Interpretation:

The given redox chemical equation in acidic medium should be balanced.

  ClO3(aq)+I(aq)Cl(aq)+I2(g)

Concept Introduction:

A redox reaction is a chemical reaction in which oxidation and reduction reactions takes place simultaneously. In such type of reaction one of the chemical species is getting oxidized while the other species gets reduced at the same time.

Oxidation state or oxidation number of an atom is defined as the positive or the negative charge that an atom would possess if it is present as ions in the given compound. In such type of reaction, the oxidation state of the atom undergoing oxidation will increase which depends upon the number of electrons lost by a particular atom. Reduction of a chemical species refers to the gain of electrons by the chemical species which results in decrease in oxidation state of that atom.

(c)

Interpretation Introduction

Interpretation:

The given redox chemical equation in acidic medium should be balanced.

  Cr2O72(aq)+C2O42(aq)Cr3+(aq)+CO2(g)

Concept Introduction:

A redox reaction is a chemical reaction in which oxidation and reduction reactions takes place simultaneously. In such type of reaction one of the chemical species is getting oxidized while the other species gets reduced at the same time.

Oxidation state or oxidation number of an atom is defined as the positive or the negative charge that an atom would possess if it is present as ions in the given compound. In such type of reaction, the oxidation state of the atom undergoing oxidation will increase which depends upon the number of electrons lost by a particular atom. Reduction of a chemical species refers to the gain of electrons by the chemical species which results in decrease in oxidation state of that atom.

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Fill in the blanks: (7.14) In the electrolysis of CUSO4, how much copper is plated out on the cathode by a current of a 0.75A in 10 minutes? (Cu 63.546 g/mol) Analysis/Strategy: ampere & time coulombs ® mol e¯ (or Faraday) ® mol Cu (R mass of Cu Reduction half-reaction of copper solution to copper metal: Cu*²(aq) + e¯ ® Cu(s) copper solution, CUSO4, has the ions: [Cu*2 SOq] Answer: The mass of copper plated out is g Cu. (3 sig fig)
(7.1b) Complete and balance the following by ion-electron method. Reactions are taking place in acidic solution. b) Mn*2(aq) + BiO3 (aq) Bi* (aq) + Mn04 (aq) Analysis: Oxidation-Half reation: Balancing atoms & charges: Mn*2(aq) Mn04 (aq) H20 - + H* + e Reduction-Half reation: Balancing atoms and charges: BiO3 (aq) H* + Bi* (aq) e H20 Balancing electrons lost & gained Multiply oxidation-half reaction by e's Multiply reduction-half reaction by es Final balanced equation: Continue next
Fill in the blanks: (7.13) Using a current of 4.75 A, how many minutes does it take to plate a sculpture with 1.50 g of Cu from a CuS04 solution? (Cu 63.546 g/mol) Analysis/Strategy: mass of Cu ® mol Cu ® mol e" (or Faraday) ® coulombs ® time in minutes (given current in amperes) Reduction half-reaction of copper solution to copper metal: Cu*2(aq) · + e¯ ® Cu(s) copper solution, CUSO4, has the ions: [Cu*2_SOq] Answer: The time needed to plate out a sculpture is minutes. (3 sig fig)

Chapter 15 Solutions

Basic Chemistry

Ch. 15.1 - Prob. 11PPCh. 15.1 - Prob. 12PPCh. 15.1 - What is the oxidation number of the specified...Ch. 15.1 - What is the oxidation number of the specified...Ch. 15.1 - Prob. 15PPCh. 15.1 - Prob. 16PPCh. 15.1 - Prob. 17PPCh. 15.1 - Prob. 18PPCh. 15.1 - Prob. 19PPCh. 15.1 - Prob. 20PPCh. 15.2 - Balance each of the following half-reactions in...Ch. 15.2 - Prob. 22PPCh. 15.2 - Prob. 23PPCh. 15.2 - Use the half-reaction method to balance each of...Ch. 15.2 - Use the half-reaction method to balance each of...Ch. 15.2 - Use the half-reaction method to balance each of...Ch. 15.3 - Use the activity series in Table 15.3 to predict...Ch. 15.3 - Use the activity series in Table 15.3 to predict...Ch. 15.3 - Prob. 29PPCh. 15.3 - Prob. 30PPCh. 15.3 - Prob. 31PPCh. 15.3 - Prob. 32PPCh. 15.3 - The following half-reaction takes place in a...Ch. 15.3 - The following half-reaction takes place in a...Ch. 15.3 - The following half-reaction takes place in a...Ch. 15.3 - Prob. 36PPCh. 15.4 - What we call "tin cans" are really iron cans...Ch. 15.4 - Prob. 38PPCh. 15.4 - Prob. 39PPCh. 15.4 - Prob. 40PPCh. 15.4 - Prob. 41PPCh. 15.4 - Prob. 42PPCh. 15 - Prob. 43UTCCh. 15 - Prob. 44UTCCh. 15 - Prob. 45UTCCh. 15 - Prob. 46UTCCh. 15 - The chapter sections to review are shown in...Ch. 15 - The chapter sections to review are shown in...Ch. 15 - The chapter sections to review are shown in...Ch. 15 - Prob. 50UTCCh. 15 - Prob. 51UTCCh. 15 - Prob. 52UTCCh. 15 - The chapter sections to review are shown in...Ch. 15 - The chapter sections to review are shown in...Ch. 15 - Which of the following are oxidation-reduction...Ch. 15 - Which of the following are oxidation-reduction...Ch. 15 - In the mitochondria of human cells, energy is...Ch. 15 - Prob. 58APPCh. 15 - Prob. 59APPCh. 15 - Prob. 60APPCh. 15 - Prob. 61APPCh. 15 - Prob. 62APPCh. 15 - Prob. 63APPCh. 15 - Write the balanced half-reactions and a balanced...Ch. 15 - Prob. 65APPCh. 15 - Use the activity series in Table 15.3 to predict...Ch. 15 - Prob. 67APPCh. 15 - Prob. 68APPCh. 15 - Prob. 69APPCh. 15 - Prob. 70APPCh. 15 - Prob. 71APPCh. 15 - In an acidic dry-cell battery, the following...Ch. 15 - Steel bolts made for sailboats are coated with...Ch. 15 - Copper cooking pans are stainless steel pans...Ch. 15 - Prob. 75CPCh. 15 - Prob. 76CPCh. 15 - Prob. 77CPCh. 15 - The following problems are related to the topics...Ch. 15 - The following problems are related to the topics...Ch. 15 - The following problems are related to the topics...Ch. 15 - Prob. 81CPCh. 15 - Prob. 82CPCh. 15 - Prob. 83CPCh. 15 - Prob. 84CPCh. 15 - Prob. 85CPCh. 15 - Prob. 86CPCh. 15 - Prob. 87CPCh. 15 - Prob. 88CP
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