Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 15, Problem 24P
Draw a structure corresponding to each name.
a.
b.
c.
d.
e.
f.
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Give the structure corresponding to each name.
a. 7,7-dimethyloctan-4-ol
b. 5-methyl-4-propylheptan-3-ol
c. 2-tert-butyl-3-methylcyclohexanol
d. trans-cyclohexane-1,2-diol
Which is the major organic product of this reaction?
A.
B.
4
ОА
O
OB
O C
COD
AICI3
benzene
C.
D.
Draw the organic product(s) formed when CH3CH2CH2OH is treated with each reagent.
a.H2SO4
b.NaH
c.HCl + ZnCl2
d.HBr
e.SOCl2, pyridine
f.PBr3
g.TsCl, pyridine
h. [1] NaH; [2] CH3CH2Br [1]
i.TsCl, pyridine; [2] NaSH
j.POCl3, pyridine
Chapter 15 Solutions
Organic Chemistry (6th Edition)
Ch. 15.2 - Prob. 1PCh. 15.2 - Problem 17.2 What orbitals are used to form the...Ch. 15.3 - Prob. 4PCh. 15.3 - Problem-17.5 What is the structure of propofol,...Ch. 15.6 - Prob. 7PCh. 15.8 - Prob. 8PCh. 15.8 - Prob. 11PCh. 15.8 - Prob. 12PCh. 15.8 - Problem 17.16 Rank the following compounds in...Ch. 15.8 - Problem 17.17 Draw the seven resonance structures...
Ch. 15 - 17.23 Name each compound and state how many lines...Ch. 15 - Prob. 21PCh. 15 - Prob. 22PCh. 15 - 17.27 Give the IUPAC name for each compounds.
a....Ch. 15 - 17.28 Draw a structure corresponding to each...Ch. 15 - 17.29 a. Draw the 14 constitutional isomers of...Ch. 15 - Prob. 26PCh. 15 - Prob. 27PCh. 15 - 17.38
How many electrons does C contain?
How...Ch. 15 - Prob. 36PCh. 15 - 17.40 Explain the observed rate of reactivity of...Ch. 15 - 17.41 Draw a stepwise mechanism for the following...Ch. 15 - Prob. 39PCh. 15 - 17.43 Draw additional resonance structures for...Ch. 15 - Prob. 41PCh. 15 - Prob. 42PCh. 15 - 17.46 Which compound in each pair is the stronger...Ch. 15 - 17.47 Treatment of indene with forms its...Ch. 15 - Prob. 45PCh. 15 - 17.49 Draw the conjugate bases of pyrrole and...Ch. 15 - 17.50 a. Explain why protonation of pyrrole occurs...Ch. 15 - Prob. 48PCh. 15 - Prob. 49PCh. 15 - 17.53 How many signals does each compound...Ch. 15 - 17.54 Which of the diethylbenzene isomers (ortho,...Ch. 15 - 17.55 Propose a structure consistent with each...Ch. 15 - 17.56 Propose a structure consistent with each...Ch. 15 - 17.57 Thymol (molecular formula ) is the major...Ch. 15 - 17.58 You have a sample of a compound of molecular...Ch. 15 - 17.59 Explain why tetrahydrofuran has a higher...Ch. 15 - 17.60 Rizatriptan (trade name Maxalt) is a...Ch. 15 - 17.61 Zolpidem (trade name Ambien) promotes the...Ch. 15 - 17.62 Answer the following questions about...Ch. 15 - 17.63 Stanozolol is an anabolic steroid that...Ch. 15 - Prob. 61P
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- Nitration of chlorobenzene gives A. o - chloronitrobenzene B. p - chloronitrobenzene C. m – chloronitrobenzene D. A and B BO DO CO A Oarrow_forwardDraw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent. a. HCl b. CH3COCl c. (CH3CO)2O d. excess CH3I e. (CH3)2C = O f. CH3COCl, AlCl3 g. CH3CO2H h. NaNO2, HCl i. Part (b), then CH3COCl, AlCl j. CH3CHO, NaBH3CNarrow_forward1. Give the IUPAC name for the following structures. 6-methylhept-4-en-2-one hig a. C. 5-isopropyl-2-heptanone HO pentan-2-yl-5-bromoheptanoate m la Ďarrow_forward
- Draw the products formed when each compound is treated with HNO3 and H2SO4.State whether the reaction occurs faster or slower than a similar reaction with benzene.arrow_forwardDraw the organic products formed in each reaction.arrow_forwardcis-Cyclohexane-1,2-diol can be synthesized from cyclohexene by using which reagent? a.O3 b.OsO4 c.H2SO4 d.mCPBAarrow_forward
- Synthesize each compound from (CH3)3CH.arrow_forwardTell whether each stereogenic isomer is either R or S. Assign the correct priority of each group comnected to the stereogenic cemter. a. b. c,H d. NH2 .S. OCH, "Br HO HS CHarrow_forward64. Which of the following reactant-product relationship is correct? A. 2-methylbutan-2-ol 2-methylbutanoic acid KMnO4 B. 2-methylbutan-2-ol 2-methylbut-3-ene H2504 C. 4-tert-butylcyclohexanol 4- tertbutylcyclohexanone Na2Cr207 D. 4- tertbutylcyclohexanol 4- tertbutylcyclohexanone 7 H2504 65. Choose the correct steps in the dehydration of secondary alcohol; then, arrange in chronological order. 1- Formation of Alkene Il-Formation of Aldehyde III- Formation of Protonated alcohol IV-Undergoes E2 mechanism V-Undergoes E1 mechanism A. V-III-I B. IV-III-II C. III-V-I D. III-IV-II 66. ALL of the following Ether can be prepared by Williamson's method, EXCEPT: A. Ditert-butyl ether B. Ethyl-tert-butyl ether C. anisole D. Both A & B 67. Ethanol is heated with an acidified potassium manganate (VII) solution. What would be the product of this reaction? A. Ethanal B. Ethene C. Ethanoic acid D. Ethanearrow_forward
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