Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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What will be the pH change when 20.0 mL of 0.100 M NaOH is added to 80.0 mL of a buffer solution consisting of 0.162 M NH3 and 0.181 M NH4Cl? (Assume that there is no change in total volume when the two solutions mix.)
pKa = 9.25
6.)Calculate the pH of a solution formed by adding 5.00 grams of solid sodium formate, NaCHO₂, to 180.0 ml of 0.220 M formic acid solution, HCHO₂. You may assume that the salt dissolves completely and that the change in volume is negligible upon addition of the solid.
A buffer is prepared by adding 5.0 g of ammonia, NH3, and 20.0 g of ammonium chloride, NH4Cl, to enough water to form 2.50 L of solution. (a) What is the pH of the buffer? (b) Write the complete ionic equation for the reaction that occurs when a few drops of nitric acid are added to the buffer. (c) Write the complete ionic equation for the reaction that occurs when a few drops of potassium hydroxide solution are added to the buffer.
Chapter 15 Solutions
Chemistry: An Atoms-Focused Approach
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- A buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to enough water to make 155 mL of solution. (a) What is the pH of the buffer? (b) If enough water is added to double the volume, what is the pH of the solution?arrow_forwardAn aqueous solution of 0.057 M weak acid, HX, has a pH of 4.65. What is the pH of the solution if 0.018 mol of KX is dissolved in one liter of the weak acid?arrow_forwardA buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to enough water to make 155 mL of solution. (a) What is the pH of the buffer? (b) If enough water is added to double the volume, what is the pH of the solution?arrow_forward
- How many grams of NaF must be added to 70.00 mL of 0.150 M HNO3 to obtain a buffer with a pH of 4.68?arrow_forwardA buffer solution is prepared from 5.15 g NH4NO3 and 0.10 L of 0.15-M NH3; calculate the pH of the solution.arrow_forward1.56 g of sodium acetate, NaCH;CO, has been 0.20 M ammonia, NH3, and 0.20 M ammonium 4. What is the pH of 0.15 M acetic acid to which 3. What is the pH of a solution that consists of aqueous solution of NH3? the same when you (c) add solid NaCl to a dilute aqueous solution of (b) add solid sodium acetate to a dilute a (a) add solid ammonium chloride to a dilute 1. Does the pH of the solution increase, decrease, or 17.1 and 17.2.) stay solution of acetic acid? aqueous NaOH? 2 Does the pH of the solution increase, decrease, or stay the same when you (a) add solid sodium oxalate, Na,C,O4, to 50.0 mL of 0.015 M oxalic acid, H,C,O4? (b) add solid ammonium chloride to 75 mL of 0.016 M HCl? (c) add 20.0 acetate, NaCH;CO2? of NaCl to 1.0 L of 0.10 M sodium *What is the pH of a solution that consists of chloride, NH4CI? added?arrow_forward
- A buffer solution contains 0.444 M NaHSO3 and 0.246 M K,SO3. If 0.0239 moles of potassium hydroxide are added to 150. mL of this buffer, what is the pH of the resulting solution ? (Assume that the volume does not change upon adding potassium hydroxide) pH =arrow_forward5:50 1 Search Question 5 of 20 Submit Determine the mass of solid NaCH;COO that must be dissolved in an existing 500.0 mL solution of 0.200 M CH3COOH to form a buffer with a pH equal to 5.00. The value of Ka for CH-COОH is 1.8 х 10-5. 1 2 Let x represent the original concentration of CH;COO in the water. Based on the given values, set up the ICE table in order to determine the unknown. CH3COOH+ H20(1) =H;O*(aq) +CH3COO-(a Initial (M) Change (M) Equilibrium (M) 5 RESET 0.200 5.00 -5.00 1.0 x 10-9 -1.0 × 10-9 1.0 x 10-5 -1.0 x 10-5 1.8 x 10-5 -1.8 x 10-5 х+ 5.00 x - 5.00 x + 1.0 × 10-9 х - 1.0 х 10-9 1.0 x 10-5 x - 1.0 × 10-5 x + 1.8 × 10-5 х - 1.8 х 10-5arrow_forwardA buffer solution was prepared that contained 0.60 M hydrogen fluoride, HF (Ka = 7.2 x 104) and 1.00M potassium fluoride, KF. The total volume was 250 mL. (a) What ions and molecules are present in the solution? List them in order of decreasing concentration: Decreasing order of Concentration (b) What is the pH of the buffer solution described above? (c) What is the pH of 100. mL of the buffer solution if you add 100. x 10-3 g of NaOH? Assume negligible change in volume. (USEFUL INFORMATION: MM NaOH = 39.997 g mol-1)arrow_forward
- A buffer solution is prepared from equal volumes of 0.200 M acetic acid and 0.600 M sodium acetate. Use 1.80 ×× 10−5 as Ka for acetic acid. (a) What is the pH of the solution? (b) Is the solution acidic or basic? (c) What is the pH of a solution that results when 3.00 mL of 0.034 M HCl is added to 0.200 L of the original buffer?arrow_forward(a) Calculate the pH of the 0.30 M NH3 / 0.35 M NH4Cl buffer. What is the pH of the buffer after the addition of 0.030 mol HCl? note: Ka (NH4+) = 5.6 x 10 -10 NH3 (aq) + H+ (aq) → NH4+ (aq) (b) What are the hydronium [H3O+] and hydroxide [OH-] ion concentrations at 25°C in a 4.0 M aqueous Mg(OH)2.arrow_forwardA buffer system is prepared by combining 0.603 moles of ammonium chloride (NH4CI) and 0.713 moles of ammonia (NH3). What will the solution pH be if 0.239 moles of the nitric acid (HNO3) is added to the solution. Nitric acid is a strong acid. The K₁ of ammonia is 1.8 x 10-5. (Two decimal places)arrow_forward
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