Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 14.4, Problem 7P
Interpretation Introduction
Interpretation:
Among the chlorination or bromination product for 2,3-dimethylbutane, the reaction which gives a greater yield of 1-halo-2,3-dimethylbutane should be determined.
Concept Introduction:
- In a halogenation reaction, one or more halogen atoms are introduced into an organic compound. Generally, these reactions are initiated in the presence of light or heat.
- Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
- Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
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Chapter 14 Solutions
Essential Organic Chemistry, Global Edition
Ch. 14.2 - Write the mechanism for the monobromination of...Ch. 14.2 - Prob. 2PCh. 14.4 - Prob. 3PCh. 14.4 - Which of the hydrogens in the structure in the...Ch. 14.4 - How many alkyl chlorides can be obtained from...Ch. 14.4 - Prob. 7PCh. 14.5 - Prob. 9PCh. 14.6 - a. Which ether is most apt to form a peroxide? b....Ch. 14.7 - Prob. 11PCh. 14 - Prob. 12P
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- Alkylation of benzene with 1-chlorobutane in the presence of AlCl3 gave not only the expected butylbenzene product but also, as a major product, (1-methylpropyl)benzene. Write an equation for the reaction Propose a mechanism to account for the formation of butylbenzene Propose a mechanism to account for the formation of (1-methylpropyl)benzenearrow_forwardHow to synthesize 1-phenyl-1-bromopropane from benzene?arrow_forwardYou are required to synthesize 2-bromopentane from the reaction between an alkene with HBr. Which alkene, 1-pentene or 2-pentene, should you react with HBr in order to get 2-bromopentane? Give an explanation.arrow_forward
- what are the reagents used to covert butane into (e)-2-butene and then into C4H8O? How would C4H8O be structured?arrow_forwardDescribe a sequence of reactions by which 1,2-dichlorobutane could be prepared from ethyne.arrow_forwardDescribe a sequence of reactions by which 3-methyl-1-butyne can be straightforwardly prepared from acetylene.arrow_forward
- When 2-bromo-2-methylbutane is treated with a base, a mixture of 2-methyl-2-butene and 2-methyl-1- butene is produced. When potassium hydroxide is the base, 2-methyl-1-butene accounts for 45% of the product mixture. However, when potassium tert-butoxide is the base, 2-methyl-1-butene accounts for 70% of the product mixture. What percent of 2-methyl-1-butene would be in the mixture if potassium propoxide were the base? base Br A. Less than 45% B. C. 45% Between 45% and 70% D. More than 70%arrow_forwardHow will you bring about the following conversions? (i)Aniline to chlorobenzene (ii) 2-Methyl-1-propene to 2-chloro-2-methylpropane (iii) Ethyl chloride to propanoic acid (iv) But-1-ene to n-butyliodide (v) Benzene to Phenyl chloromethane. (vi) Tert-butylbromide to isobutylbromide.arrow_forwardElimination of HBr from 2-bromobutane affords a mixture of 1-butene and 2-butene. With sodium ethoxide as base, 2-butene constitutes 81% of the alkene products, but with potassium tert-butoxide, 2-butene constitutes only 67% of the alkene products. Offer an explanation for this difference.arrow_forward
- What hydrocarbon forms the following products after reaction first with ozone and then with dimethyl sulfide?arrow_forwardWhich functional group(s) would be added to 1-methylcyclohexene using the reagents below: H3O+ hydrogen hydroxyl ketone and aldehyde bromine and hydroxyl bromine and hydrogen bromine hydrogen and hydroxyl aldehyde ketone Save for Laterarrow_forwardEthers can be prepared by reaction of an alkoxide or phenoxide ion with a primary alkyl halide. Draw the structure of the expected organic product of the reaction of 1-iodo-2-methylpropane with the following alkoxide ic + O Na You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include counter-ions, e.g., Na", I", in your answer. C opy astearrow_forward
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