The reactant alcohol should be identified when the ketone is the product. Concept Introduction: Oxidation reaction: Alcohol undergoes oxidation reaction using oxidising agent like KMnO 4 or K 2 Cr 2 O 7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 14.25UKC

(a)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the ketone is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(b)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the aldehyde is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(c)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the acid is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 14.25UKC

(a)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the ketone is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(b)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the aldehyde is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(c)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the acid is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 14.25UKC

(a)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the ketone is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(b)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the aldehyde is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(c)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the acid is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 14.25UKC

(a)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the ketone is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(b)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the aldehyde is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(c)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the acid is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

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Answer 5

Chapter 14, Problem 14.25UKC

(a)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the ketone is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(b)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the aldehyde is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

(c)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the acid is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

Answer 6

Chapter 14, Problem 14.25UKC

(a)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the ketone is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

Answer 7

Chapter 14, Problem 14.25UKC

(a)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the ketone is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the aldehyde is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the aldehyde is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the acid is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reactant alcohol should be identified when the acid is the product.

Concept Introduction:

Oxidation reaction:

Alcohol undergoes oxidation reaction using oxidising agent like KMnO4or K2Cr2O7 which yields the corresponding carbonyl compounds. Primary alcohol undergoes oxidation reaction yields the corresponding aldehyde or acid, secondary alcohol undergoes oxidation reaction yields the corresponding ketone as the product.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 14.1 - Identify each of the following compounds as an...Ch. 14.1 - Prob. 14.2P Ch. 14.2 - Prob. 14.3P Ch. 14.2 - Prob. 14.4P Ch. 14.2 - Prob. 14.5P Ch. 14.3 - Prob. 14.6P Ch. 14.3 - For each of the following molecules, (i) redraw...Ch. 14.4 - Prob. 14.1MRP Ch. 14.4 - Provide the mechanism for the dehydration of...Ch. 14.4 - Prob. 14.3MRP

Solution Summary: The author explains that the reactant alcohol should be identified when the ketone is the product.

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Chapter 14 Solutions