Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 13, Problem 52P

What combination of acyl chloride or acid anhydride and arene would you choose to

prepare each of the following compounds by Friedel–Crafts acylation?

Chapter 13, Problem 52P, What combination of acyl chloride or acid anhydride and arene would you choose to prepare each of , example  1

Chapter 13, Problem 52P, What combination of acyl chloride or acid anhydride and arene would you choose to prepare each of , example  2

Chapter 13, Problem 52P, What combination of acyl chloride or acid anhydride and arene would you choose to prepare each of , example  3

Chapter 13, Problem 52P, What combination of acyl chloride or acid anhydride and arene would you choose to prepare each of , example  4

Chapter 13, Problem 52P, What combination of acyl chloride or acid anhydride and arene would you choose to prepare each of , example  5

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Explain how the class I carbonyl compound reacts? What will be the product when ethylamine and propyl amine reacts with acetyl chloride? Why only one amide obtained after the reaction of acetyl chloride with a mixture of ethylamine and trimethylamine?  Excess amine is required in the reaction of acetyl chloride with amine whereas excess alcohol is not required in the reaction of acetyl chloride and alcohol. Why? List the following ester in order of decreasing reactivities towards hydrolysis with reason: Methyl benzoate, p-nitro methyl benzoate and p-methoxy methyl benzoate
Linalool and lavandulol are two of the major components of lavender oil. (a) What organolithium reagent and carbonyl compound can be used to make each alcohol? (b) How might lavandulol be formed by reduction of a carbonyl compound? (c) Why can't linalool be prepared by a similar pathway?
arrange the following compounds in order of decreasing reactivity towards hydrolysis

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