Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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The reaction for the Haber process, the industrial production of ammonia, is
N2(g) + 3H2(g) → 2NH3(g)
Assume that under certain laboratory conditions ammonia is produced at the rate of 6.29 mol L-1 s-1. At what rate is hydrogen consumed?
Suppose that the gas-phase reaction
2 NO(g) + O₂(g) →2 NO₂ (g) were carried out in a constant-
volume container at constant temperature.
In a study of the formation of HI from its elements,
H2(g) + 12(g) == 2HI(g) equal amounts of H2 and 12
were placed in a container, which was then sealed and
heated. (a) On one set of axes, sketch concentration vs.
time curves for H and HI, and explain how Q changes
as a function of time. (b) Is the value of Q different if [12]
is plotted instead of [H2]?
Chapter 13 Solutions
Chemistry: An Atoms-Focused Approach
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- Substances burn more rapidly in pure oxygen than in air. Explain why.arrow_forwardCalcium carbide, CaC2, is manufactured by reducing lime with carbon at high temperature. (The carbide is used in turn to make acetylene, an industrially important organic chemical.) Is the reaction endothermic or exothermic?arrow_forwardUse the appropriate tables to calculate H for (a) the reaction between copper(II) oxide and carbon monoxide to give copper metal and carbon dioxide. (b) the decomposition of one mole of methyl alcohol (CH3OH) to methane and oxygen gases.arrow_forward
- Determine rxnH 25 C for the following reaction: NO g O2 g NO2 g This reaction is a major participant in the formation of smog.arrow_forwardOne of the components of polluted air is NO. It is formed in the high-temperature environment of internal combustion engines by the following reaction: N2(g)+O2(g)2NO(g)H=180KJ Why are high temperatures needed to convert N2 and O2 to NO?arrow_forwardThe catalytic decomposition of hydrogen peroxide can be expressed as: 2H2O2(aq) → 2H2O(l) + O2(g) Calculate the number of moles of oxygen gas produced from the completely catalyzed decomposition of 6.60 mL sample of a 3.5% solution of H2O2. The density of the 3.5% solution of H2O2 is 1.01 g/mL.arrow_forward
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- MN IN The 1995 Nobel Prize in Chemistry was shared by Paul Crutzen, F. Sherwood Rowland, and Mario Molina for their work concerning the formation and decomposition of ozone in the stratosphere. Rowland and Molina hypothesized that chlorofluorocarbons (CFCS) in the stratosphere break down upon exposure to UV radiation, producing chlorine atoms. Chlorine was previously identified as a catalyst in the breakdown of ozone into oxygen gas. Using the enthalpy of reaction for two reactions with ozone, determine the enthalpy of reaction for the reaction of chlorine with ozone. (1) CIO(g) + O,(g) → Cl(g) + 20,(g) AHxn = -122.8 kJ AHn = -285.3 kJ | rxn AHn = ? (3)°O + (3)OIƆ (3)1Ɔ+(3)*o (£) (3) 0E – (3)°07 (2) rxn %3D = UXHV kJ MacBook Pro Q Search or enter website name The & %23 $4 3. 4. 5. 7. 6. delete R H. K. re B. HE MOSISO command optionarrow_forwardThe data below were collected for the following reaction at 35° C: 2(CH3)3 CSOH(g) → (CH3)3CS(O)SC(CH3)3 (g) Time (min) [(CH3)3 CSOH] (mol · L−¹) 0.0 1.554 10.8 0.661 19.1 0.343 37.0 0.083 59.5 0.014 75.1 0.004 Part C From the slope of the appropriate plot, determine the value of the rate constant at this temperature. VG ΑΣΦ Submit Request Answer ? 5-1arrow_forward= 14 15 16 17 18 19 20 21 22 23 24 25 26 A chemical engineer must calculate the maximum safe operating temperature of a high-pressure gas reaction vessel. The vessel is a stainless-steel cylinder that measures 39.0 cm wide and 46.8 cm high. The maximum safe pressure inside the vessel has been measured to be 8.50 MPa. For a certain reaction the vessel may contain up to 5.53 kg of boron trifluoride gas. Calculate the maximum safe operating temperature the engineer should dlo recommend for this reaction. Write your answer in degrees Celsius. Round your answer to 3 significant digits. temperature: || °Carrow_forward
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