Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Write by equations the formation of O3 in a photochemical smog
In 1995, Mario Molina, Paul Crutzen, and F. SherwoodRowland shared the Nobel Prize in chemistry for their work onatmospheric chemistry. One of several reaction sequences pro-posed for the role of chlorine in the decomposition of strato-spheric ozone is (1) Cl(g) +O3(g)→ ClO(g) +O₂(g) (2) ClO(g) +ClO(g)→ Cl₂O₂(g) (3) Cl₂O₂→ (g)2Cl(g)+ O₂(g).Over the tropics, O atoms are more common in the stratosphere:(4) ClO(g) +O(g)→ Cl(g) +O₂(g).(a) Which, if any, of these are oxidation-reduction reactions?(b) Write an overall equation combining reactions 1–3
234
CHAPTER 8
23. Using the following thermochemical equations:
2 SO,(g) → 2 SO,(g) + O,(g)
ΔΗ
TXn 1
= +198 kJ/molm
So;(g) + H,0(g) → H,SO,(e)
ΔΗ
Ixn 2
=-176 kJ/molm
Determine the enthalpy of the reaction represented below:
SO,(g) +0,(g) + H,O(g) → H,SO,(€) AH°,
= ?
Txn 3
= +22 kJ/molxn
=-77 kJ/mol,pn
=-275 kJ/molxn
(А) ДНО
KOH)
Ixn
(B) ДНе
(C) AHÓ
(D) AH°,
Ixn
=-374 kJ/molxn
Chapter 13 Solutions
Chemistry: An Atoms-Focused Approach
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