Laboratory Techniques in Organic Chemistry
Laboratory Techniques in Organic Chemistry
4th Edition
ISBN: 9781464134227
Author: Jerry R. Mohrig, David Alberg, Gretchen Hofmeister, Paul F. Schatz, Christina Noring Hammond
Publisher: W. H. Freeman
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Chapter 12, Problem 2Q
Interpretation Introduction

Interpretation:

Vapor phase composition present above liquid is to be calculated. Also, vapor phase composition present above second liquid is to be calculated.

Concept introduction:

Distillation is a liquid-gas separation technique for two or more liquids on the basis of their difference in boiling point or vapor pressure.

Vapor pressure is pressure exerted by vapor phase of liquid produced due to an increase in the molecular kinetic energy of the liquid phase or due to the increase in temperature.

The temperature at which atmospheric pressure exerted on liquid equals to its vapor pressure is known to be its boiling point. Vapor pressure of the component decide boiling point of any mixture. Impurities in the mixture might result in an increase or decrease of observed boiling point.

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