Organic Chemistry, Books a la Carte Edition (8th Edition)
Organic Chemistry, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134074580
Author: Bruice, Paula Yurkanis
Publisher: PEARSON
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Chapter 12, Problem 28P
Interpretation Introduction

Interpretation:

The reason should be explained why iodine does not react with ethane, even though it is more easily cleaved homolytically than other halogens.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

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Explain why iodine (I2) does not react with ethane, even though I2 is more easily cleaved homolytically than the other halogens.
1. For the reaction (CH3)2O + C₂H5F → [(CH3)2OC₂H5]+F¯ (a) draw the structure for the cation
Using Friedel Crafts alkylation of benzene, a group of scientists discovered compound A, C3H3O, an optically inactive compound. They discovered that compound B, CsH;BrO, is produced during the halogenation process. When compound B is reacted with nitric acid, compound C, C3H,B1NO3, is formed. While Friedel Crafts alkylation of compound A produces compound D. This compound D was oxidised to produce compound E, C9H§O3 as a major product. Compound F, C10H1002, was produced by Friedel Crafts acylation of compound A. This compound F reacts positively with alkaline iodine and 2,4- dinitrophenylhydrazine. However, it returns negative results for Tollens' and Benedict's tests. Identify the possible structural formulae compounds A to F and explain your answers.

Chapter 12 Solutions

Organic Chemistry, Books a la Carte Edition (8th Edition)

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