CHEMISTRY-TEXT
CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Chapter 12, Problem 12.138MP

Assume that 1588 g of an alkali metal undergoes complete reaction with the amount of gaseous halogen in a 0.500 L flask at 298 and 755 mm Hg pressure. In the reaction, 22.83 kJ is released ( Δ H = 22.83  kJ) . The product, a binary ionic compound, crystallizes in a unit cell with anions in a face-centered cubic arrangement and with cations centered along each edge between anions. In addition, there is a cation in the center of the cube.

  1. What is the identity of the alkali metal?
  2. The edge length of the unit cell is 535 pm. Find the radius of the alkali metal cation from the data Figure 6.1, and then calculate the radius of the halide anion.Identify the anion from the data in Figure 6.2.
  3. Sketch a space-filling, head-on view of the unit cell, labeling the ions. Are the anions in contact with one another?
  4. What is the density of the compound in g/cm3?
  5. What is the standard heat of formation for the compound?

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Chapter 12 Solutions

CHEMISTRY-TEXT

Ch. 12 - Prob. 12.11PCh. 12 - Prob. 12.12ACh. 12 - Prob. 12.13PCh. 12 - Prob. 12.14PCh. 12 - Prob. 12.15PCh. 12 - Prob. 12.16PCh. 12 - Prob. 12.17PCh. 12 - Identify each of the following kinds of packingCh. 12 - Prob. 12.19CPCh. 12 - Titanium oxide crystallizes in the following cubic...Ch. 12 - Prob. 12.21CPCh. 12 - Prob. 12.22CPCh. 12 - Prob. 12.23CPCh. 12 - Prob. 12.24CPCh. 12 - Prob. 12.25CPCh. 12 - Prob. 12.26SPCh. 12 - Prob. 12.27SPCh. 12 - Prob. 12.28SPCh. 12 - Prob. 12.29SPCh. 12 - Prob. 12.30SPCh. 12 - Prob. 12.31SPCh. 12 - Diffraction of X rays with =154.2 pm at an angle...Ch. 12 - Diffraction of X rays with =154.2 pm at an angle...Ch. 12 - Which of the four kinds of packing used by metals...Ch. 12 - What is a unit cell? How many atoms are in one...Ch. 12 - Copper crystallizes in a face-centered cubic unit...Ch. 12 - Lead crystallizes in a cubic unit cell with anedge...Ch. 12 - Prob. 12.38SPCh. 12 - Tungsten crystallizes in a body-centered cubic...Ch. 12 - Prob. 12.40SPCh. 12 - Prob. 12.41SPCh. 12 - Titanium metal has a density of and an atomic...Ch. 12 - Calcium metal has a density of 1.55 g/cm3 and...Ch. 12 - The atomic radius of Pb is 175 pm, and the density...Ch. 12 - The density of a sample of metal was measured to...Ch. 12 - If a protein can be induced to crystallize, its...Ch. 12 - The molecular structure of a scorpion toxin, a...Ch. 12 - Iron crystallizes in a body-centered cubic unit...Ch. 12 - Silver metal crystallizes in a face-centered cubic...Ch. 12 - Sodium hydride, NaH, crystallizes in a...Ch. 12 - Cesium chloride crystallizers in a cubic unit cell...Ch. 12 - If the edge length of an NaH unit cell is 488 pm,...Ch. 12 - The edge length of a CsCI unit cell (Problem...Ch. 12 - Silicon carbide, SiC, is a covalent network solid...Ch. 12 - Prob. 12.55SPCh. 12 - Prob. 12.56SPCh. 12 - Prob. 12.57SPCh. 12 - Prob. 12.58SPCh. 12 - Prob. 12.59SPCh. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Prob. 12.76SPCh. 12 - Prob. 12.77SPCh. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Prob. 12.80SPCh. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Prob. 12.85SPCh. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - Prob. 12.94SPCh. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Prob. 12.101SPCh. 12 - A photovoltaic cell contains a p-n junction that...Ch. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104SPCh. 12 - Prob. 12.105SPCh. 12 - Prob. 12.106SPCh. 12 - Prob. 12.107SPCh. 12 - Prob. 12.108SPCh. 12 - Prob. 12.109SPCh. 12 - Prob. 12.110SPCh. 12 - Prob. 12.111SPCh. 12 - Prob. 12.112SPCh. 12 - Prob. 12.113SPCh. 12 - Prob. 12.114SPCh. 12 - Prob. 12.115SPCh. 12 - Prob. 12.116SPCh. 12 - Prob. 12.117SPCh. 12 - Prob. 12.118SPCh. 12 - Prob. 12.119SPCh. 12 - Prob. 12.120SPCh. 12 - Prob. 12.121SPCh. 12 - Prob. 12.122SPCh. 12 - Prob. 12.123SPCh. 12 - Prob. 12.124SPCh. 12 - Prob. 12.125SPCh. 12 - Prob. 12.126SPCh. 12 - Prob. 12.127SPCh. 12 - Prob. 12.128SPCh. 12 - Prob. 12.129SPCh. 12 - Prob. 12.130SPCh. 12 - Prob. 12.131SPCh. 12 - Prob. 12.132SPCh. 12 - Prob. 12.133SPCh. 12 - Prob. 12.134MPCh. 12 - Prob. 12.135MPCh. 12 - Prob. 12.136MPCh. 12 - Prob. 12.137MPCh. 12 - Assume that 1588 g of an alkali metal undergoes...Ch. 12 - Prob. 12.139MPCh. 12 - Prob. 12.140MPCh. 12 - Prob. 12.141MPCh. 12 - Prob. 12.142MPCh. 12 - Prob. 12.143MPCh. 12 - Prob. 12.144MP
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