Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 11.9, Problem 13P
(a) Draw two different enol tautomers of
constitutional isomers that are not tautomers, but contain a
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(a) Draw the structure of the hemiacetal formed from one mole of benzaldehyde and one mole of
ethanol.
(b) Draw the structure of the acetal formed from one mole of benzaldehyde and two moles of ethanol.
(c) Draw the structure of 2-methoxy-2-butanol. What compounds could you prepare this from?
(d) Draw the structure of 3-methoxyl-2-butanol. What functional groups are present? Is this an acetal, a
hemiacetal, or neither? Explain.
(e) Identify the functional groups in the molecules shown below. Circle any acetals or hemiacetal, and
identify which they are.
0-
(a) Draw the structure of the hemiacetal formed from one mole of benzaldehyde and one mole of
ethanol.
(b) Draw the structure of the acetal formed from one mole of benzaldehyde and two moles of ethanol.
(c) Draw the structure of 2-methoxy-2-butanol. What compounds could you prepare this from?
c)
rite in the reagent(s) over the arrow.
a) C6H5N₂+
b) C6H5C=N
H3C-
An
OH
H₂C
→ benzene
H3C
benzylamine
CI
CH3
Chapter 11 Solutions
Organic Chemistry (6th Edition)
Ch. 11.1 - Problem 11.1 Neopheliosyne B is a novel acetylenic...Ch. 11.2 - Give the IUPAC name for each compound.Ch. 11.2 - Give the structures corresponding to each of the...Ch. 11.3 - Prob. 4PCh. 11.5 - Prob. 5PCh. 11.6 - Which bases can deprotonate acetylene? The pKa...Ch. 11.7 - Draw the organic products formed when each alkyne...Ch. 11.7 - Draw additional resonance structures for each...Ch. 11.8 - Problem 11.9 Draw the products formed when is...Ch. 11.8 - Explain the following result. Although alkenes...
Ch. 11.9 - Problem 11.11 Draw the keto tautomer of each...Ch. 11.9 - Prob. 12PCh. 11.9 - a Draw two different enol tautomers of...Ch. 11.10 - Prob. 14PCh. 11.10 - Problem 11.15 Draw the organic products formed in...Ch. 11.11 - Problem 11.16 What acetylide anion and alkyl...Ch. 11.11 - Problem. 11.17 Show how , and can be used to...Ch. 11.11 - Prob. 18PCh. 11.11 - Draw the products of each reaction. a. b.Ch. 11.11 - Prob. 20PCh. 11 - Prob. 25PCh. 11 - 11.25 Answer the following questions about...Ch. 11 - 11.26 Give the IUPAC name for each alkyne.
a. ...Ch. 11 - Prob. 28PCh. 11 - Which of the following pairs of compounds...Ch. 11 - Prob. 30PCh. 11 - 11.30 How is each compound related to A? Choose...Ch. 11 - Prob. 32PCh. 11 - 11.33 Draw the products formed when is treated...Ch. 11 - What reagents are needed to convert (CH3CH2)3CCCH...Ch. 11 - 11.36 What alkynes give each of the following...Ch. 11 - 11.37 What alkyne gives each compound as the only...Ch. 11 - 11.38 Draw the organic products formed in each...Ch. 11 - 11.42 What reactions are needed to convert alcohol...Ch. 11 - 11.50 What acetylide anion and alkyl halide are...Ch. 11 - 11.52 Devise a synthesis of each compound using ...Ch. 11 - Prob. 58PCh. 11 - 11.59 N-Chlorosuccinimide (NCS) serves as a source...Ch. 11 - 11.60 Draw a stepwise mechanism for the following...Ch. 11 - 11.61 Draw a stepwise mechanism for the following...
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