(a) Interpretation: The structure corresponding to the given name, 5 , 6 − dimethylhept − 2 − yne is to be identified. Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

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Answer 1

Question

Chapter 11, Problem 28P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name, 5,6−dimethylhept−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name, 5−tert−butyl−6,6−dimethylinon−3−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name, (S)−4−chloropent−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name, cis−1−ethynyl−2−methylcyclopentane is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to the given name, 3,4−dimethylocta−1,5−diyne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to the given name, (Z)−6−methylocta−6−ene−1−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

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Give the structure corresponding to each name. a. 5,6-dimethylhept-2-yne b. 5-tert-butyl-6,6-dimethylnon-3-yne c. (S)-4-chloropent-2-yne d. cis-1-ethynyl-2-methylcyclopentane e. 3,4-dimethylocta-1,5-diyne f. (Z)-6-methyloct-6-en-1-yne

1. Give the IUPAC name for the following structures. 6-methylhept-4-en-2-one hig a. C. 5-isopropyl-2-heptanone HO pentan-2-yl-5-bromoheptanoate m la Ď

Draw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reaction occurs. a.H2 + Pd-C b.H2 + Lindlar catalyst c.Na, NH3 d.CH3CO3H e.[1] CH3CO3H; [2] H2O, HO− f.[1]OsO4 + NMO; [2] NaHSO3, H2O g.KMnO4, H2O, HO− h.[1] LiAlH4; [2] H2O i. [1] O3; [2] CH3SCH3 j.(CH3)3COOH, Ti[OCH(CH3)2]4, (−)-DET k.mCPBA l.Product in (k); then [1] LiAlH4; [2] H2O

Answer 2

Question

Chapter 11, Problem 28P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name, 5,6−dimethylhept−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name, 5−tert−butyl−6,6−dimethylinon−3−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name, (S)−4−chloropent−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name, cis−1−ethynyl−2−methylcyclopentane is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to the given name, 3,4−dimethylocta−1,5−diyne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to the given name, (Z)−6−methylocta−6−ene−1−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

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Answer 3

Question

Chapter 11, Problem 28P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name, 5,6−dimethylhept−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name, 5−tert−butyl−6,6−dimethylinon−3−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name, (S)−4−chloropent−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name, cis−1−ethynyl−2−methylcyclopentane is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to the given name, 3,4−dimethylocta−1,5−diyne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to the given name, (Z)−6−methylocta−6−ene−1−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

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Answer 4

Question

Chapter 11, Problem 28P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name, 5,6−dimethylhept−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name, 5−tert−butyl−6,6−dimethylinon−3−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name, (S)−4−chloropent−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name, cis−1−ethynyl−2−methylcyclopentane is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to the given name, 3,4−dimethylocta−1,5−diyne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to the given name, (Z)−6−methylocta−6−ene−1−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

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Answer 5

Chapter 11, Problem 28P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name, 5,6−dimethylhept−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name, 5−tert−butyl−6,6−dimethylinon−3−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name, (S)−4−chloropent−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name, cis−1−ethynyl−2−methylcyclopentane is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to the given name, 3,4−dimethylocta−1,5−diyne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to the given name, (Z)−6−methylocta−6−ene−1−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 6

Chapter 11, Problem 28P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name, 5,6−dimethylhept−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 7

Chapter 11, Problem 28P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name, 5,6−dimethylhept−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 8

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name, 5−tert−butyl−6,6−dimethylinon−3−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 9

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name, 5−tert−butyl−6,6−dimethylinon−3−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 10

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name, (S)−4−chloropent−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 11

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name, (S)−4−chloropent−2−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 12

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name, cis−1−ethynyl−2−methylcyclopentane is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 13

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name, cis−1−ethynyl−2−methylcyclopentane is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 14

Interpretation Introduction

(e)

Interpretation: The structure corresponding to the given name, 3,4−dimethylocta−1,5−diyne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 15

Interpretation Introduction

(e)

Interpretation: The structure corresponding to the given name, 3,4−dimethylocta−1,5−diyne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 16

Interpretation Introduction

(f)

Interpretation: The structure corresponding to the given name, (Z)−6−methylocta−6−ene−1−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 17

Interpretation Introduction

(f)

Interpretation: The structure corresponding to the given name, (Z)−6−methylocta−6−ene−1−yne is to be identified.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The full form of IUPAC is International Union of Pure and Applied Chemistry. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 11.1 - Problem 11.1 Neopheliosyne B is a novel acetylenic...Ch. 11.2 - Give the IUPAC name for each compound.Ch. 11.2 - Give the structures corresponding to each of the...Ch. 11.3 - Prob. 4P Ch. 11.5 - Prob. 5P Ch. 11.6 - Which bases can deprotonate acetylene? The pKa...Ch. 11.7 - Draw the organic products formed when each alkyne...Ch. 11.7 - Draw additional resonance structures for each...Ch. 11.8 - Problem 11.9 Draw the products formed when is...Ch. 11.8 - Explain the following result. Although alkenes...

Solution Summary: The author explains IUPAC's systematic naming of organic compounds. The structure corresponding to the given name is shown in Figure 1.

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