Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 11.9, Problem 12P
Interpretation Introduction

Interpretation: Two enols that are formed by the reaction of pent2yne with H2O, H2SO4 and HgSO4 are to be identified. The ketones that are formed by the two resultant enols are to be identified.

Concept introduction: The chemical equilibrium that exists between a keto form of a compound and an enol form of the same compound is known as keto-enol tautomerism. Tautomers refer to these keto and enol forms.

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What two enols are formed when pent-2-yne is treated with H2O, H2SO4, and HgSO4? Draw the ketones formed from these enols after tautomerization.
Draw the products (including stereoisomers) formed when 2- methylhex-2-ene is treated with HBr in the presence of peroxides.
Draw the organic products formed when each alkyne is treated with two equivalents of HBr.

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Organic Chemistry (6th Edition)

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