Physical Universe
16th Edition
ISBN: 9780077862619
Author: KRAUSKOPF, Konrad B. (konrad Bates), Beiser, Arthur
Publisher: Mcgraw-hill Education,
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Question
Chapter 11, Problem 4E
To determine
How the given two solids, which is held together by ionic bond and by van der Waals force has to be given.
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Calculate the Packing factor for hexagonal closed-
Packed Structure ?
In solid KCI the smallest distance between the centers of a. potassium ion and a chloride ion is 314 pm. Calculate the length of the edge of the unit cell and the density of KCI, assuming it has the same structure as sodium chloride.
In the methane molecule, CH4, each hydrogen atom is at the corner of a regular tetrahedron with the carbon atom at the center. If one of the C-H is in the direction of
A= i-hat + j-hat + k-hat
and an adjacent C-H bond is at the direction
B= i-hat - j-hat - k-hat
results to an angular bond of approximately 109o for a static frozen molecule.
However, the molecule we can encounter everyday continuously vibrates and interact with the surrounding causing its bond vector to vary slightly. According to a new spectroscopy analysis, the adjacent bond vectors was found to be
A = 1.09i + 1.06j + 1.02k
B = 1.01i + -0.89j + -1.02k
What is the angle (in degrees) between the bonds based on this new data?
Note: Only 1% of error is permitted for the correct answer.
Chapter 11 Solutions
Physical Universe
Ch. 11 - Prob. 1MCCh. 11 - Prob. 2MCCh. 11 - Prob. 3MCCh. 11 - Prob. 4MCCh. 11 - Prob. 5MCCh. 11 - Prob. 6MCCh. 11 - Prob. 7MCCh. 11 - Prob. 8MCCh. 11 - Prob. 9MCCh. 11 - Prob. 10MC
Ch. 11 - Prob. 11MCCh. 11 - Suppose there were molecules that had no...Ch. 11 - Prob. 13MCCh. 11 - Prob. 14MCCh. 11 - Prob. 15MCCh. 11 - Prob. 16MCCh. 11 - Prob. 17MCCh. 11 - Prob. 18MCCh. 11 - Prob. 19MCCh. 11 - Prob. 20MCCh. 11 - Prob. 21MCCh. 11 - Prob. 22MCCh. 11 - Prob. 23MCCh. 11 - Prob. 24MCCh. 11 - Prob. 25MCCh. 11 - Prob. 26MCCh. 11 - Prob. 27MCCh. 11 - Prob. 28MCCh. 11 - Prob. 29MCCh. 11 - Prob. 30MCCh. 11 - Prob. 31MCCh. 11 - Prob. 32MCCh. 11 - Prob. 33MCCh. 11 - Prob. 34MCCh. 11 - Prob. 35MCCh. 11 - Prob. 36MCCh. 11 - Prob. 37MCCh. 11 - Prob. 38MCCh. 11 - Prob. 39MCCh. 11 - Prob. 40MCCh. 11 - Prob. 41MCCh. 11 - Prob. 42MCCh. 11 - Prob. 1ECh. 11 - What kind of solid is ice? Why does ice float when...Ch. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - How could you tell experimentally whether a...Ch. 11 - From which class of solids would you expect...Ch. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Van der Waals forces are strong enough to hold...Ch. 11 - Prob. 10ECh. 11 - What ions would you expect to find in the crystal...Ch. 11 - Why is the solubility of one gas in another...Ch. 11 - Why do bubbles of gas form in a glass of soda...Ch. 11 - Ordinary tap water tastes different after it has...Ch. 11 - How do unsaturated, saturated, and supersaturated...Ch. 11 - Prob. 16ECh. 11 - Give two ways to tell whether a sugar solution is...Ch. 11 - At 10C, which is more concentrated, a saturated...Ch. 11 - Prob. 19ECh. 11 - What is the difference between a molecular ion and...Ch. 11 - How could you distinguish experimentally between...Ch. 11 - Prob. 22ECh. 11 - You have a solution that contains Cl- ions and...Ch. 11 - You have a solution that contains Ca2+ ions and...Ch. 11 - You have a solution that contains Ag+ ions and...Ch. 11 - What is the easiest way to distinguish between a...Ch. 11 - Prob. 27ECh. 11 - Seawater freezes at a lower temperature than pure...Ch. 11 - Prob. 29ECh. 11 - What are the two chief ions found in seawater?Ch. 11 - (a) Is the percentage of the worlds water that is...Ch. 11 - The pesticide DDT concentrates in the fat of...Ch. 11 - Prob. 33ECh. 11 - Which of the following are weak acids?...Ch. 11 - Would you expect HBr to be a weak or strong acid?...Ch. 11 - Even though ammonia is not a base because its...Ch. 11 - What is the difference, if any, between a basic...Ch. 11 - Is it correct to say that the only ions an acidic...Ch. 11 - Which is more strongly acidic, a solution of pH 3...Ch. 11 - In an acidic solution, why is the OH concentration...Ch. 11 - Prob. 41ECh. 11 - When a salt that contains the negative ion of a...Ch. 11 - Prob. 43ECh. 11 - What salt is formed when a solution of calcium...Ch. 11 - What salt is formed when a solution of calcium...Ch. 11 - What salt is formed when a solution of sodium...Ch. 11 - What salt is formed when a solution of potassium...Ch. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Boric acid (H3BO3) is a very weak acid. What would...Ch. 11 - The Al3+ ion tends to form AlOH2+ ions in water...Ch. 11 - Prob. 52ECh. 11 - Prob. 53E
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- Which one of the following ionic solids would have the largest lattice energy? NaCl ONAF CaBr2 ○ CsI CaCl2arrow_forwardIn the methane molecule, CH4, each hydrogen atom is at the corner of a regular tetrahedron with the carbon atom at the center. If one of the C-H is in the direction of A= i-hat + j-hat + k-hat and an adjacent C-H bond is at the direction B= i-hat - j-hat - k-hat results to an angular bond of approximately 109o for a static frozen molecule. However, the molecule we can encounter everyday continuously vibrates and interact with the surrounding causing its bond vector to vary slightly. According to a new spectroscopy analysis, the adjacent bond vectors was found to be A = 0.96i + 0.87j + 0.8k B = 0.94i + -0.98j + -1.07k What is the angle (in degrees) between the bonds based on this new data?arrow_forward3. Show that in an ideal hexagonal-close-packed (hcp) structure, where the atomic spheres touch each other, the ratio c/a is given by :-()* ( 8 \ 1/2 = 1.633. (The hep structure is discussed in Section 7.) 4 The packing ratio is defined as the fraction of the total volume of the cell that is filled by atoms. Determine the maximum values of this ratio for equal spheres located at the points of simple-cubic, body-centered-cubic, and face-centered-cubic crystals.arrow_forward
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