Physical Universe
16th Edition
ISBN: 9780077862619
Author: KRAUSKOPF, Konrad B. (konrad Bates), Beiser, Arthur
Publisher: Mcgraw-hill Education,
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Chapter 11, Problem 10E
To determine
The ions that is expected to be found in crystal structures of
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Consider a hexagonal close packed cell with cell constants c and a (see figures below). Each
atom in the central layer forms equilateral tetrahedron structures with the 3 atoms directly below
it (bottom, red tetrahedron in figure on the right).
a) Derive the ratio
b) How many tetrahedral and octahedral interstitial sites are there per hcp unit cell? Explain
your reasoning.
Fe3+ ion was reduced to its amalgam from solutions that were 2.0 x 10 3 M Fe3+, 0.1 M KNO,.
Fe3+ + 3e + Hg Fe(Hg)
Addition of Br ions forms a complex. E was shifted with each addition of the anion.
The shifts in E,, were plotted against log[Br ]. The slope was found to be -0.021 with an intercept of -0.13.
Calculate the formation constant (Kf) of the complex.
O 2.7 x 107
3.9 x 10-6
O 1.9 x 10-5
5.4 x 104
O 4.8 x 1013
Given that the radius of the Ca2+ and F- ions are 1.03 Å and 1.36 Å, respectively, show that the packing fraction of the CaF2 (Fluorite) structure is 0.61.
Chapter 11 Solutions
Physical Universe
Ch. 11 - Prob. 1MCCh. 11 - Prob. 2MCCh. 11 - Prob. 3MCCh. 11 - Prob. 4MCCh. 11 - Prob. 5MCCh. 11 - Prob. 6MCCh. 11 - Prob. 7MCCh. 11 - Prob. 8MCCh. 11 - Prob. 9MCCh. 11 - Prob. 10MC
Ch. 11 - Prob. 11MCCh. 11 - Suppose there were molecules that had no...Ch. 11 - Prob. 13MCCh. 11 - Prob. 14MCCh. 11 - Prob. 15MCCh. 11 - Prob. 16MCCh. 11 - Prob. 17MCCh. 11 - Prob. 18MCCh. 11 - Prob. 19MCCh. 11 - Prob. 20MCCh. 11 - Prob. 21MCCh. 11 - Prob. 22MCCh. 11 - Prob. 23MCCh. 11 - Prob. 24MCCh. 11 - Prob. 25MCCh. 11 - Prob. 26MCCh. 11 - Prob. 27MCCh. 11 - Prob. 28MCCh. 11 - Prob. 29MCCh. 11 - Prob. 30MCCh. 11 - Prob. 31MCCh. 11 - Prob. 32MCCh. 11 - Prob. 33MCCh. 11 - Prob. 34MCCh. 11 - Prob. 35MCCh. 11 - Prob. 36MCCh. 11 - Prob. 37MCCh. 11 - Prob. 38MCCh. 11 - Prob. 39MCCh. 11 - Prob. 40MCCh. 11 - Prob. 41MCCh. 11 - Prob. 42MCCh. 11 - Prob. 1ECh. 11 - What kind of solid is ice? Why does ice float when...Ch. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - How could you tell experimentally whether a...Ch. 11 - From which class of solids would you expect...Ch. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Van der Waals forces are strong enough to hold...Ch. 11 - Prob. 10ECh. 11 - What ions would you expect to find in the crystal...Ch. 11 - Why is the solubility of one gas in another...Ch. 11 - Why do bubbles of gas form in a glass of soda...Ch. 11 - Ordinary tap water tastes different after it has...Ch. 11 - How do unsaturated, saturated, and supersaturated...Ch. 11 - Prob. 16ECh. 11 - Give two ways to tell whether a sugar solution is...Ch. 11 - At 10C, which is more concentrated, a saturated...Ch. 11 - Prob. 19ECh. 11 - What is the difference between a molecular ion and...Ch. 11 - How could you distinguish experimentally between...Ch. 11 - Prob. 22ECh. 11 - You have a solution that contains Cl- ions and...Ch. 11 - You have a solution that contains Ca2+ ions and...Ch. 11 - You have a solution that contains Ag+ ions and...Ch. 11 - What is the easiest way to distinguish between a...Ch. 11 - Prob. 27ECh. 11 - Seawater freezes at a lower temperature than pure...Ch. 11 - Prob. 29ECh. 11 - What are the two chief ions found in seawater?Ch. 11 - (a) Is the percentage of the worlds water that is...Ch. 11 - The pesticide DDT concentrates in the fat of...Ch. 11 - Prob. 33ECh. 11 - Which of the following are weak acids?...Ch. 11 - Would you expect HBr to be a weak or strong acid?...Ch. 11 - Even though ammonia is not a base because its...Ch. 11 - What is the difference, if any, between a basic...Ch. 11 - Is it correct to say that the only ions an acidic...Ch. 11 - Which is more strongly acidic, a solution of pH 3...Ch. 11 - In an acidic solution, why is the OH concentration...Ch. 11 - Prob. 41ECh. 11 - When a salt that contains the negative ion of a...Ch. 11 - Prob. 43ECh. 11 - What salt is formed when a solution of calcium...Ch. 11 - What salt is formed when a solution of calcium...Ch. 11 - What salt is formed when a solution of sodium...Ch. 11 - What salt is formed when a solution of potassium...Ch. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Boric acid (H3BO3) is a very weak acid. What would...Ch. 11 - The Al3+ ion tends to form AlOH2+ ions in water...Ch. 11 - Prob. 52ECh. 11 - Prob. 53E
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