Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Textbook Question
Chapter 11, Problem 33QAP
Nitrosyl bromide decomposes to nitrogen oxide and bromine. Use the following data to determine the order of the decomposition of nitrosyl bromide.
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What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Chapter 11 Solutions
Chemistry: Principles and Reactions
Ch. 11 - Express the rate of the reaction...Ch. 11 - Express the rate of the reaction...Ch. 11 - Consider the following hypothetical reaction: X( g...Ch. 11 - Consider the following hypothetical reaction:...Ch. 11 - Consider the combustion of ethane:...Ch. 11 - For the reaction 5Br(aq)+BrO3(aq)+6...Ch. 11 - Nitrosyl chloride (NOCI) decomposes to nitrogen...Ch. 11 - Ammonia is produced by the reaction between...Ch. 11 - Experimental data are listed for the following...Ch. 11 - Experimental data are listed for the hypothetical...
Ch. 11 - A reaction has two reactants X and Y. What is the...Ch. 11 - A reaction has two reactants Q and P. What is the...Ch. 11 - What will the units of the rate constants in...Ch. 11 - What will the units of the rate constants in...Ch. 11 - Consider the reaction ZproductsThe data below give...Ch. 11 - Consider the reaction YproductsThe graph below...Ch. 11 - Complete the following table for the reaction...Ch. 11 - Complete the following table for the reaction...Ch. 11 - The decomposition of nitrogen dioxide is a...Ch. 11 - The decomposition of ammonia on tungsten at 1100C...Ch. 11 - The reaction ICl(g)+12 H2(g)12 I2(g)+HCl(g)is...Ch. 11 - The hypothetical reaction X(g)+12Y(g)productsis...Ch. 11 - For a reaction involving the decomposition of Z at...Ch. 11 - For a reaction involving the decomposition of Y,...Ch. 11 - When boron trifluoride reacts with ammonia, the...Ch. 11 - When nitrogen dioxide reacts with carbon monoxide,...Ch. 11 - Hydrogen bromide is a highly reactive and...Ch. 11 - Diethylhydrazine reacts with iodine according to...Ch. 11 - The equation for the reaction between iodide and...Ch. 11 - Prob. 30QAPCh. 11 - In a solution at a constant H+ concentration,...Ch. 11 - Consider the reaction Â...Ch. 11 - Nitrosyl bromide decomposes to nitrogen oxide and...Ch. 11 - Prob. 34QAPCh. 11 - Azomethane decomposes into nitrogen and ethane at...Ch. 11 - The decomposition of sulfuryl chloride, SO2Cl2, to...Ch. 11 - The first-order rate constant for the...Ch. 11 - Consider the first-order decomposition of phosgene...Ch. 11 - The decomposition of azomethane, (CH3)2N2, to...Ch. 11 - The first-order rate constant for the...Ch. 11 - In the first-order decomposition of acetone at...Ch. 11 - The decomposition of sulfuryl chlorideSO2Cl2fur...Ch. 11 - Dinitrogen pentoxide gas decomposes to form...Ch. 11 - Sucrose (C12H22O11) hydrolyzes into glucose and...Ch. 11 - Iodine-131 is used to treat tumors in the thyroid....Ch. 11 - Cesium-131 is the latest tool of nuclear medicine....Ch. 11 - Prob. 47QAPCh. 11 - A sample of sodium-24 chloride contains 0.050 mg...Ch. 11 - The decomposition of A at 850C is a zero-order...Ch. 11 - The decomposition of R at 33C is a zero-order...Ch. 11 - For the zero-order decomposition of HI on a gold...Ch. 11 - For the zero-order decomposition of ammonia on...Ch. 11 - Ammonium cyanate, NH4NCO, in water rearranges to...Ch. 11 - Butadiene, C4H6, dimerizes according to the...Ch. 11 - The rate constant for the second-order reaction...Ch. 11 - The decomposition of nitrosyl chloride...Ch. 11 - An increase in temperature from 23C to 36C...Ch. 11 - If the activation energy of a reaction is 9.13 kJ,...Ch. 11 - The following data are obtained for the gas-phase...Ch. 11 - The following data are obtained for the...Ch. 11 - Consider the following hypothetical reaction:...Ch. 11 - For the reaction: Q+RY+ZH=128kJ Draw a...Ch. 11 - The uncoiling of deoxyribonucleic acid (DNA) is a...Ch. 11 - The precipitation of egg albumin in water at 100C...Ch. 11 - Prob. 65QAPCh. 11 - Prob. 66QAPCh. 11 - For the reaction 2N2O(g)2N2(g)+O2(g) the rate...Ch. 11 - For the decomposition of a peroxide, the...Ch. 11 - Consider a 5.000 M solution of the hypothetical...Ch. 11 - The decomposition of N2O5 to NO2 and NO3 is a...Ch. 11 - For a certain reaction, Ea is 135 kJ and H=45 kJ....Ch. 11 - Consider a reaction in which E a=129 kJ and H=29...Ch. 11 - A catalyst lowers the activation energy of a...Ch. 11 - A reaction has an activation energy of 363 kJ at...Ch. 11 - Write the rate expression for each of the...Ch. 11 - Write the rate expression for each of the...Ch. 11 - For the reaction between hydrogen and iodine,...Ch. 11 - For the reaction 2H2(g)+2NO(g)N2(g)+2H2O(g) the...Ch. 11 - At low temperatures, the rate law for the reaction...Ch. 11 - Two mechanisms are proposed for the reaction...Ch. 11 - The hypothetical reaction QR+Xproductswas...Ch. 11 - When a base is added to an aqueous solution of...Ch. 11 - The decomposition of sulfuryl chloride, SO2Cl2, to...Ch. 11 - How much faster would a reaction proceed at 46C...Ch. 11 - Prob. 85QAPCh. 11 - Prob. 86QAPCh. 11 - A drug decomposes in the blood by a first-order...Ch. 11 - Prob. 88QAPCh. 11 - Prob. 89QAPCh. 11 - Prob. 90QAPCh. 11 - Consider the decomposition of A represented by...Ch. 11 - Consider the decomposition reaction 2X2Y+ZThe...Ch. 11 - Consider the following activation energy diagram....Ch. 11 - Three first-order reactions have the following...Ch. 11 - Consider the first-order decomposition reaction...Ch. 11 - Consider the following energy diagram (not to...Ch. 11 - Prob. 97QAPCh. 11 - Prob. 98QAPCh. 11 - The gas-phase reaction between hydrogen and iodine...Ch. 11 - Consider the coagulation of a protein at 100C. The...Ch. 11 - Prob. 101QAPCh. 11 - Prob. 102QAPCh. 11 - Prob. 103QAPCh. 11 - In a first-order reaction, suppose that a quantity...Ch. 11 - Consider the hypothetical first-order reaction...
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