Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 10, Problem 70P
Phenolphthalein is an acid–base indicator. In solutions of pH < 8.5, it is colorless; in solutions of pH > 8.5, it is deep red-purple. Account for the change in color.
phenolphthalein
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Addition of phenolphthalein to an unknown colorlesssolution does not cause a color change. The addition ofbromthymol blue to the same solution leads to a yellowcolor. (a) Is the solution acidic, neutral, or basic? (b) Whichof the following can you establish about the solution: (i) Aminimum pH, (ii) A maximum pH, or (iii) A specific rangeof pH values? (c) What other indicator or indicators wouldyou want to use to determine the pH of the solution moreprecisely?
The normal pH of blood is 7.40 ± 0.05 and is controlled in part by a H2CO3/HCO3 2 buffer system.(a) Assuming that the Ka value for carbonic acid at 25°C applies toblood, what is the [H2CO3]/[HCO3-] ratio in normal blood?(b) In a condition called acidosis, the blood is too acidic. What isthe [H2CO3]/[HCO3-] ratio in a patient whose blood pH is 7.20?
The normal pH of blood is 7.40 6 0.05 and is controlled in part by the H2CO3/HCO3- buffer system.(a) Assuming that the Ka value for carbonic acid at 25oC applies to blood, what is the [H2CO3]/[HCO3-] ratio in normal blood?(b) In a condition called acidosis, the blood is too acidic. What is the [H2CO3]/[HCO3-] ratio in a patient whose blood pH is 7.20?
Chapter 10 Solutions
Essential Organic Chemistry, Global Edition
Ch. 10.1 - Prob. 1PCh. 10.2 - What would distinguish the mass spectrum of...Ch. 10.2 - Prob. 3PCh. 10.3 - Prob. 5PCh. 10.3 - Suggest possible molecular formulas for a compound...Ch. 10.3 - Prob. 7PCh. 10.4 - Prob. 8PCh. 10.4 - Prob. 9PCh. 10.5 - Prob. 10PCh. 10.5 - Prob. 11P
Ch. 10.6 - Identify the ketone responsible for the mass...Ch. 10.6 - Prob. 13PCh. 10.8 - Prob. 14PCh. 10.8 - Prob. 15PCh. 10.12 - Which will occur at a larger wavenumber: a. a C :...Ch. 10.13 - Which will occur at a larger wavenumber: a. the C...Ch. 10.13 - Prob. 18PCh. 10.13 - Prob. 19PCh. 10.13 - Which will show an O 8 H stretch at a larger...Ch. 10.14 - Prob. 21PCh. 10.14 - Prob. 22PCh. 10.15 - Prob. 23PCh. 10.15 - Prob. 24PCh. 10.17 - Prob. 25PCh. 10.18 - Prob. 26PCh. 10.18 - Prob. 27PCh. 10.19 - Prob. 28PCh. 10.19 - Prob. 29PCh. 10.22 - How many signals would you expect to see in the 1H...Ch. 10.22 - Prob. 31PCh. 10.22 - Prob. 32PCh. 10.23 - Where would you expect to find the 1H NMR signal...Ch. 10.24 - Prob. 34PCh. 10.25 - Prob. 35PCh. 10.25 - Prob. 36PCh. 10.25 - Prob. 37PCh. 10.26 - Prob. 38PCh. 10.26 - Which of the following compounds is responsible...Ch. 10.27 - Prob. 40PCh. 10.27 - Prob. 41PCh. 10.27 - The 1H NMR spectra of two carboxylic acids with...Ch. 10.28 - Prob. 43PCh. 10.28 - Prob. 44PCh. 10.28 - Prob. 45PCh. 10.28 - Describe the 1H NMR spectrum you would expect for...Ch. 10.28 - Identify the compound with molecular formula...Ch. 10.29 - Prob. 48PCh. 10.29 - Prob. 49PCh. 10.29 - Identify the compound with a molecular formula of...Ch. 10 - In the mass spectrum of the following compounds,...Ch. 10 - For each of the following pairs of compounds,...Ch. 10 - Draw the structure of a saturated hydrocarbon that...Ch. 10 - Prob. 54PCh. 10 - Prob. 55PCh. 10 - How could you use UV spectroscopy to distinguish...Ch. 10 - Prob. 57PCh. 10 - Predict the relative intensities of the molecular...Ch. 10 - Prob. 59PCh. 10 - List the following compounds in order from highest...Ch. 10 - How can 1H NMR be used to prove that the addition...Ch. 10 - There are four esters with molecular formula...Ch. 10 - Prob. 63PCh. 10 - Prob. 64PCh. 10 - Each of the IR spectra presented here is...Ch. 10 - Prob. 66PCh. 10 - Five compounds are shown for each of the following...Ch. 10 - Prob. 68PCh. 10 - Prob. 69PCh. 10 - Phenolphthalein is an acidbase indicator. In...Ch. 10 - Which one of the following five compounds produced...Ch. 10 - Prob. 72PCh. 10 - Prob. 73PCh. 10 - Prob. 74PCh. 10 - How could 1H NMR distinguish between the compounds...Ch. 10 - Prob. 76PCh. 10 - Prob. 77PCh. 10 - The 1H NMR spectra of three isomers with molecular...Ch. 10 - The 1H NMR spectra of three isomers with molecular...Ch. 10 - Identify the following compounds. (Relative...Ch. 10 - An alkyl halide reacts with an alkoxide ion to...Ch. 10 - Determine the structure of a compound with...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H) and the amine group (NHR) are protonated. However, as the pH of the solution increases (say, by adding base), the carboxylic acid proton is removed, usually at a pH between 2 and 3. In a middle range of pHs, therefore, the amine group is protonated, but the carboxylic acid group has lost the proton. (This is called a zwitterion.) At more basic pH values, the amine proton is dissociated. What is the pH of a 0.20 M solution of alanine hydrochloride, [NH3CHCH3CO2H]Cl?arrow_forward3. 40.00 mL of 0.0900 M NaOH is diluted to 100mL and titrated with 0.1000M HCI. Calculate the pH after the addition of the following volumes of titrant (mL); (a) 0.00; (b) 10.00 ; (c) 18.00: (d) 30.00 ; (e) 35.95 ; (f) 36.00 (g) 36.05 ; (h) 40.00.arrow_forwardPhenolphthalein is an acid–base indicator. In solutions of pH 6 8.5, it is colorless; in solutions of pH 7 8.5, it is deep red-purple. Account for thechange in color.arrow_forward
- I need help with this problem. Compare the pH of propionic acid and nitric acid when they are dissolved in water at a concentration of 20 mM using the "Arrhenius Concept". Include:a balanced equation describing the acid-base reactions involvedThe calculation of the pKa for bothThe calculation of the two pH's (of propionic acid and nitric acid when they are dissolved in water at a concentration of 20 mM)and A calculation of the percent of dissociation of both propionic acid and nitric acid.The gibbs free energy ΔG are listed as the following:Nitric acid: -152 kJ/molPropionic Acid : -291 kJ/molPropionate: -361 kJ/molarrow_forwardBased on the results obtained in the table, What is the color of acid-base indicator B when the pH of the medium is equal to its pKa?arrow_forward3. Complete neutralization of 10 ml of phosphoric acid solution by NaOH 0.I N in the presence of phenol phthalein until the appearance of purple color (pH, = 9) 11 ml. of NaOH is consumed. (a) What is the concentration of phosphoric acid? (b) Calculate the indicator error. pk2.1 pK. - 7.2 pK - 124arrow_forward
- HIn(aq) + H2O(l) H3O+(aq) + In-(aq)red yellowThe acid base indicator methyl orange is red at pH values below 3 and is yellow at pH values above 6. Usingyour knowledge of pH, indicators and pKa values, predict the pKa of methyl orange.arrow_forwardCitric acid (H₂CH₂O7) has pKa values of 3.128 (pKal), 4.761 (pKa2), and 6.396 (pKa3). What is the predominant form of citric acid at pH 4.37? O HC HẠO O H₂ Co H₂O, OC₂H₂O² O H,CH,O, What is the second most abundant species of citric acid at pH 4.37? O HC₂H₂O²- OC₂H₂O OH₂CH₂O7 O H₂CH₂O7 What is the predominant form of citric acid at pH 5.95? O HCHO H₂ CH₂O7 O H₂C₂H₂O, OC₂H₂O What is the second most abundant species of citric acid at pH 5.95? O HC HẠO OC₂H₂O² O H,C,H,O, O H₂CH₂O7arrow_forwardPhenolphthalein indicator is a weak acid with Ka = 10-9 mol/dm-3. It is colourless while its conjugate base is pink in solution. Define the term" WEAK ACID"arrow_forward
- The value of Ksp for Mg3(AsO4)2 is 2.1 x 10-20. TheAsO43 - ion is derived from the weak acid H3AsO4 (pKa1 =2.22; pKa2 = 6.98; pKa3 = 11.50). (a) Calculate the molarsolubility of Mg3(AsO4)2 in water. (b) Calculate the pH of asaturated solution of Mg3(AsO4)2 in water.arrow_forwardAssuming that the concentration of concentrated HCI is 10 M, estimate approximately how much concentrated HCI will be required to bring the pH of the 1.0 M Tris solution to 7.5, using the following information. log [conjugate base] [Iconjugate acid] H/H equation: pH pKa %3D + The total molarity of Tris in the solution is made up of: [Tris (conjugate base form) + Tris (conjugate acid form)] i.e. in this example, [Tris-c.base] + [Tris-c.acid] = 1.0M pka of Tris ~8.1 You wish to make 200 mL of Tris-CI bufferarrow_forwardProvide the chemical formulas and the names of the three predominant carbonic acid species indicated by arrows in the image below: Species 1 species 2 Species 3 Explain i) how you can determine the pH range at which a weak acid/conjugate base system will display buffering properties.ii) what is the reason/logic behind the rule applied in i)? and iii) indicate the pH ranges of the carbonic acid system based on the pka values provided above. Provide the chemical equilibrium that describes the carbonic acid buffer system that exists at pH 9.3. Clearly indicate the chemical formulas, identify the weak acid and it’s conjugate base, and the names of the chemical compounds.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY