Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 10, Problem 20P
Excluding enantiomers, free-radical chlorination of
monochloro derivatives but
formulas for each.
![Chapter 10, Problem 20P, Excluding enantiomers, free-radical chlorination of bicyclo[2.2.1]heptane yields four monochloro](https://content.bartleby.com/tbms-images/9780073511214/Chapter-10/images/11214-10-20p-question-digital_image043.png)
Which of the compounds in your answer to part (a) are chiral? Draw the structural
formula of the enantiomer of each chiral monochloro derivative.
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Compounds X and Y both have the formula C7H₁4.
Both X and Y react with one molar equivalent of hydrogen in the presence of a palladium catalyst to form 2-methylhexane.
The heat of hydrogenation of X is greater than that of Y.
Both X and Y react with HCI to give the same single C7H15Cl compound as the major product.
What is the structure of X?
• In cases where there is more than one answer, just draw one.
23
▾
Sn [F
ChemDoodleⓇ
146
Draw a structural formula for the one constitutional isomer of the
unbranched alkane C7H16 in which the longest carbon chain has 4
atoms.
• You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• In cases where there is more than one answer, just draw
one.
21.) Calculate the enthalpy of hydrogenation of benzene to cyclohexane from the following
reactions
A,H (kJ/mol)
C6H6 (1) + 15/2 02 (g) → 6 CO2 (g) + 3 H20 (1)
C6H12 (1) + 9 02 (g) → 6 CO2 (g) + 6 H20 (1)
H2 (g) + ½ 02 (g) → H2O (1)
-3268
-3920
-285.83
a.) -205 kJ/mol
b.) -1507 kJ/mol
c.) -938 kJ/mol
d.) -366 kJ/mol
Chapter 10 Solutions
Organic Chemistry - Standalone book
Ch. 10.1 - Prob. 1PCh. 10.1 - Prob. 2PCh. 10.2 - Use the data in Table 10.1 to calculate H for the...Ch. 10.3 - Prob. 4PCh. 10.4 - Prob. 5PCh. 10.4 - Prob. 6PCh. 10.4 - Do the arithmetic involved in converting the...Ch. 10.4 - How many constitutionally isomeric...Ch. 10.4 - Prob. 9PCh. 10.5 - Prob. 10P
Ch. 10.5 - Prob. 11PCh. 10.5 - Prob. 12PCh. 10.6 - Prob. 13PCh. 10.7 - Prob. 14PCh. 10.8 - Prob. 15PCh. 10 - Carboncarbon bond dissociation enthalpies have...Ch. 10 - Use the bond dissociation enthalpy data in Table...Ch. 10 - Use the bond dissociation enthalpy data in Table...Ch. 10 - Write the structure of the major organic product...Ch. 10 - Excluding enantiomers, free-radical chlorination...Ch. 10 - Prob. 21PCh. 10 - Prob. 22PCh. 10 - Prob. 23PCh. 10 - Prob. 24PCh. 10 - Compound A (C6H14) gives three different...Ch. 10 - Prob. 26PCh. 10 - Prob. 27PCh. 10 - Prob. 28PCh. 10 - Prob. 29PCh. 10 - Guiding your reasoning by retrosynthetic analysis,...Ch. 10 - (Z)-9-tricosene [(Z)-CH3(CH2)7CH=CH(CH2)12CH3] is...Ch. 10 - Prob. 32PCh. 10 - Prob. 33PCh. 10 - Prob. 34DSPCh. 10 - Prob. 35DSPCh. 10 - Prob. 36DSPCh. 10 - Prob. 37DSPCh. 10 - Prob. 38DSP
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- For the following, you must draw an appropriate structure that has the chemical formula C5H7O2Cl with the indicated functional group(s) and/or property. In each case, identify any other functional groups in the molecule you draw, that were not indicated in the question. You may use Lewis or bond- line structures to draw your molecules. You may not use the same structure to answer more than 1 question. a) An acyclic molecule that cannot form hydrogen bonds with itself b) A tertiary chloride c) A cyclic etherarrow_forwardThe molar heat of combustion of gaseous cyclopropane is -2089 kJ/mol; that for gaseous cyclopentane is -3317 kJ/mol. Calculate the heat of combustion per CH2 group in the two cases, and account for the difference.arrow_forwardDraw the structure of 2,3-dimethyl-1-butene. • Show stereochemistry only if given in the name. • You do not have to explicitly draw H atoms.arrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License