Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 10.4, Problem 9P
Interpretation Introduction
Interpretation:
The structure of the major organic products formed by free-radical bromination of each of the given compounds is to be written.
Concept Introduction:
>Halogenation of
The tertiary free radicals are more stable than primary and secondary free radicals.
>In the free radical bromination of alkanes, preferably, the tertiary hydrogen is replaced by bromine.
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10) For the reaction between isopropyl 1-propyl (or 'n-propyl') ether and HBr, which type of reaction best
matches the expected products?
A) Acid-catalyzed dehydration
B) Nucleophilic substitution reaction
C) Ether cleavage reaction
D) Nucleophilic addition-elimination reaction
1) The carbon-oxygen double bond present in aldehydes and ketones is very polar. What does this mean and how does it arise?
2) The carbon-oxygen double bond is readily attacked by nucleophiles like cyanide ions or ammonia.
(i) What do you understand by the term nucleophile?
(ii) Which part of the carbon-oxygen double bond is attractive to nucleophiles?
3) Why is there a difference between aldehydes and ketones in their response to oxidizing agents such as potassium dichromate(VI) solution acidified with dilute sulfuric acid?
Draw out the structures (condensed structural formulas) for the following reactions (reactants and
products) and name the product formed.
a) Hydrohalogenation of 1,3-dimethylcyclopentene with HBr
Name product:
b) Hydrogenation of 3,4-dimethylcyclobutene
Name product:
c) Hydration of 3-ethyl-2-pentene
cturslomeo
Name product:
d) Alkylation of benzene with 2-chloropropane (isopropylchloride)
Name product:
e) Mono-halogenation of 2,2-dimethylbutane with Cl2
Name product:
Chapter 10 Solutions
Organic Chemistry - Standalone book
Ch. 10.1 - Prob. 1PCh. 10.1 - Prob. 2PCh. 10.2 - Use the data in Table 10.1 to calculate H for the...Ch. 10.3 - Prob. 4PCh. 10.4 - Prob. 5PCh. 10.4 - Prob. 6PCh. 10.4 - Do the arithmetic involved in converting the...Ch. 10.4 - How many constitutionally isomeric...Ch. 10.4 - Prob. 9PCh. 10.5 - Prob. 10P
Ch. 10.5 - Prob. 11PCh. 10.5 - Prob. 12PCh. 10.6 - Prob. 13PCh. 10.7 - Prob. 14PCh. 10.8 - Prob. 15PCh. 10 - Carboncarbon bond dissociation enthalpies have...Ch. 10 - Use the bond dissociation enthalpy data in Table...Ch. 10 - Use the bond dissociation enthalpy data in Table...Ch. 10 - Write the structure of the major organic product...Ch. 10 - Excluding enantiomers, free-radical chlorination...Ch. 10 - Prob. 21PCh. 10 - Prob. 22PCh. 10 - Prob. 23PCh. 10 - Prob. 24PCh. 10 - Compound A (C6H14) gives three different...Ch. 10 - Prob. 26PCh. 10 - Prob. 27PCh. 10 - Prob. 28PCh. 10 - Prob. 29PCh. 10 - Guiding your reasoning by retrosynthetic analysis,...Ch. 10 - (Z)-9-tricosene [(Z)-CH3(CH2)7CH=CH(CH2)12CH3] is...Ch. 10 - Prob. 32PCh. 10 - Prob. 33PCh. 10 - Prob. 34DSPCh. 10 - Prob. 35DSPCh. 10 - Prob. 36DSPCh. 10 - Prob. 37DSPCh. 10 - Prob. 38DSP
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