Chemistry
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 10, Problem 146AP
Interpretation Introduction

Interpretation:

The speed at which the target is moving and the time taken for the target to travel are to be calculated. The speed of the Bi atoms is to be determined.

Concept introduction:

The circumference of a cylinder is calculated as follows:

C=2πr

Here, r is the radius and C is the circumference.

The time taken iscalculated as follows:

t=distancespeed

The root mean square speed for molecules is calculated as

urms=3RTM

Here, urms represents the root mean square speed of the molecule, R represents the gas constant, T represents the temperature, and M represents its molar mass.

Expert Solution & Answer
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Answer to Problem 146AP

Solution:

(a) 61.2 m/s

(b) 4.58×104 s

(c) 366 m/s

Explanation of Solution

Given information:

Temperature T=850°C

Distance d=2.8 cm

Diameter=15 cm

Revolutions=130 revolutions/sec

a)The speed at which the target is moving

Calculate the radius as follows:

r=diameter2

Substitute 15 cm for the diameter in the above equation

r=152 cm=7.5 cm

The circumference of a cylinder is calculated as

C=2πr

Substitute 7.5 cm for r in the above equation

C=2π(7.5 cm)=2×3.14×7.5 cm=47.1 cm

In 1centimetre, there are 102 m.

Convert centimetre to meter as follows:

47.1 cm=(47.1 cm)(102m1 cm)=47.1×102m

The target speed can be calculated as follows:

s=circumference×revolutions/sec

Substitute 47.1×102m for the circumference and 130  for revolutions/sec in the above equation

s=47.1×102m×130=6123×102 m/s=61.2 m/s

Hence, the speed of the target is 61.2 m/s.

b) The time it takes for target to cover distance 2.8 cm.

In 1centimetre, there are 102 m.

Convert centimetre to meter as follows:

2.8 cm=(2.8 cm)(102m1 cm)=2.8×102m

The time taken iscalculated as

t=distancespeed

Substitute 2.8×102m for distance and 61.23 m/s for speed in the above equation

t=2.8×102 m61.23 m/s=0.0458×102 s=4.58×104 s

Hence, the time taken by the target to travel 2.8 cm is 4.58×104 s.

c) urmsof Bi at 850°C

The distance is 15 cm.

In 1centimetre, there are 102 m.

Convert centimetre to meter as follows:

15 cm=(15 cm)(102m1 cm)=15×102m

Calculate the speed as follows:

Speed=distancet

Substitute 15×102m for distance and 4.58×104 s for t in the above equation

Speed=15×102 m4.58×104 s=3.28×102 m/s=328 m/s

The temperature is 850°C.

The conversion of temperature from degree Celsius to Kelvin is done by using the formula given below:

T(K)=T(°C)+273.15=(850+273.15)=1123.15 K

The molar mass of bismuth is 209×103 kg/mol.

The root mean square speed for a moleculeis calculated as

urms=3RTM

Substitute 1123.15 K for T, 209×103 kg/mol for MBi, and 8.314 J/K.mol for R in the above equation

urms=3(8.314 J/K.mol)(1123.15 K)209×103 kg/mol=28013.6209×103  m/s=134×10 m/s=1340×10 m/s

So, the rms value of speed for bismuth is

urms=36.6×101 m/s=366 m/s

Hence, the rmsvalue of the speed for bismuth is 366 m/s.

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