Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Textbook Question
Chapter 10, Problem 10.13EP
Predict the function of each of the following enzymes.
- a. Pyruvate carboxylase
- b. Alcohol dehydrogenase
- c. L-Amino acid reductase
- d. Maltase
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 10 Solutions
Organic And Biological Chemistry
Ch. 10.1 - Which of the following statements concerning the...Ch. 10.1 - Prob. 2QQCh. 10.2 - Which of the following statements about a...Ch. 10.2 - Which of the following statements about cofactors...Ch. 10.2 - Prob. 3QQCh. 10.3 - Which of the following statements concerning an...Ch. 10.3 - Most enzyme names end with the suffix ase, but a...Ch. 10.3 - Which of the following pairings of enzyme type and...Ch. 10.3 - Which of the following pairings of enzyme type and...Ch. 10.4 - An enzyme active site is the location in an enzyme...
Ch. 10.4 - Which of the following statements concerning the...Ch. 10.4 - Which of the following enzyme properties is...Ch. 10.5 - The specificity of an enzyme that catalyzes the...Ch. 10.5 - Linkage-specific enzymes will act on a particular...Ch. 10.6 - The number of substrate molecules converted to...Ch. 10.6 - Prob. 2QQCh. 10.6 - Prob. 3QQCh. 10.7 - Extremozyme presence is not possible in which of...Ch. 10.7 - Prob. 2QQCh. 10.8 - Which of the following statements concerning a...Ch. 10.8 - Which of the following statements concerning an...Ch. 10.8 - Which of the following binds to an enzyme at a...Ch. 10.9 - Which of the following is an incorrect...Ch. 10.9 - Prob. 2QQCh. 10.9 - Which of the following statements applies to a...Ch. 10.10 - Prob. 1QQCh. 10.10 - Prob. 2QQCh. 10.11 - Prob. 1QQCh. 10.11 - Prob. 2QQCh. 10.12 - Prob. 1QQCh. 10.12 - Prob. 2QQCh. 10.12 - Prob. 3QQCh. 10.13 - Prob. 1QQCh. 10.13 - Which of the following statements about...Ch. 10.13 - In the recharging of a metal-containing enzyme by...Ch. 10.14 - Prob. 1QQCh. 10.14 - Prob. 2QQCh. 10.14 - Prob. 3QQCh. 10.14 - Which of the B vitamins has a name that draws...Ch. 10.14 - Prob. 5QQCh. 10.14 - Prob. 6QQCh. 10.15 - Prob. 1QQCh. 10.15 - Prob. 2QQCh. 10.15 - Prob. 3QQCh. 10.15 - Prob. 4QQCh. 10.15 - Prob. 5QQCh. 10 - What is the general role of enzymes in the human...Ch. 10 - Prob. 10.2EPCh. 10 - List two ways in which enzymes differ from...Ch. 10 - Occasionally the delicate nature of enzymes is...Ch. 10 - Indicate whether each of the following phrases...Ch. 10 - Indicate whether each of the following phrases...Ch. 10 - Prob. 10.7EPCh. 10 - Prob. 10.8EPCh. 10 - Prob. 10.9EPCh. 10 - Prob. 10.10EPCh. 10 - Prob. 10.11EPCh. 10 - Based on its name, indicate whether each of the...Ch. 10 - Predict the function of each of the following...Ch. 10 - Predict the function of each of the following...Ch. 10 - Prob. 10.15EPCh. 10 - What is the substrate for each of the enzymes...Ch. 10 - Suggest a name for an enzyme that catalyzes each...Ch. 10 - Suggest a name for an enzyme that catalyzes each...Ch. 10 - Prob. 10.19EPCh. 10 - Indicate whether each of the following pairings of...Ch. 10 - Prob. 10.21EPCh. 10 - Prob. 10.22EPCh. 10 - Identify the enzyme needed in each of the...Ch. 10 - Identify the enzyme needed in each of the...Ch. 10 - Indicate whether each of the following statements...Ch. 10 - Indicate whether each of the following statements...Ch. 10 - Indicate whether each of the statements in Problem...Ch. 10 - Indicate whether each of the statements in Problem...Ch. 10 - Prob. 10.29EPCh. 10 - Prob. 10.30EPCh. 10 - Prob. 10.31EPCh. 10 - Prob. 10.32EPCh. 10 - Prob. 10.33EPCh. 10 - Indicate whether each of the following statements...Ch. 10 - Prob. 10.35EPCh. 10 - Prob. 10.36EPCh. 10 - Prob. 10.37EPCh. 10 - Prob. 10.38EPCh. 10 - What type of specificity (absolute, group,...Ch. 10 - What type of specificity (absolute, group,...Ch. 10 - The following graph shows the relationship between...Ch. 10 - Based on the graphical information in Problem...Ch. 10 - Prob. 10.43EPCh. 10 - Based on the graphical information in Problem...Ch. 10 - Prob. 10.45EPCh. 10 - Prob. 10.46EPCh. 10 - Prob. 10.47EPCh. 10 - Prob. 10.48EPCh. 10 - Prob. 10.49EPCh. 10 - Prob. 10.50EPCh. 10 - Describe the effect that each of the following...Ch. 10 - Prob. 10.52EPCh. 10 - Prob. 10.53EPCh. 10 - Prob. 10.54EPCh. 10 - Indicate whether each of the following pairings of...Ch. 10 - Indicate whether each of the following pairings of...Ch. 10 - Prob. 10.57EPCh. 10 - Prob. 10.58EPCh. 10 - Prob. 10.59EPCh. 10 - Prob. 10.60EPCh. 10 - Prob. 10.61EPCh. 10 - Indicate whether each of the following statements...Ch. 10 - Prob. 10.63EPCh. 10 - Indicate whether each of the following statements...Ch. 10 - Prob. 10.65EPCh. 10 - Prob. 10.66EPCh. 10 - Prob. 10.67EPCh. 10 - Prob. 10.68EPCh. 10 - Prob. 10.69EPCh. 10 - What occurs during the covalent modification of an...Ch. 10 - Prob. 10.71EPCh. 10 - Prob. 10.72EPCh. 10 - Explain the difference in meaning, if any, between...Ch. 10 - Prob. 10.74EPCh. 10 - Prob. 10.75EPCh. 10 - Prob. 10.76EPCh. 10 - Prob. 10.77EPCh. 10 - Prob. 10.78EPCh. 10 - Prob. 10.79EPCh. 10 - Prob. 10.80EPCh. 10 - Prob. 10.81EPCh. 10 - What enzyme is denoted by each of the following...Ch. 10 - What is the medical diagnostic value associated...Ch. 10 - What is the medical diagnostic value associated...Ch. 10 - Indicate whether each of the following is a...Ch. 10 - Indicate whether each of the following is a...Ch. 10 - Prob. 10.87EPCh. 10 - Indicate whether each of the vitamins in Problem...Ch. 10 - Prob. 10.89EPCh. 10 - Prob. 10.90EPCh. 10 - Prob. 10.91EPCh. 10 - What are the structural differences between the...Ch. 10 - Prob. 10.93EPCh. 10 - Prob. 10.94EPCh. 10 - Prob. 10.95EPCh. 10 - Prob. 10.96EPCh. 10 - Prob. 10.97EPCh. 10 - Only eight of the nine water-soluble vitamins are...Ch. 10 - Indicate whether each of the following B vitamin...Ch. 10 - Indicate whether each of the following B vitamin...Ch. 10 - Which of the B vitamins has a structure that fits...Ch. 10 - Prob. 10.102EPCh. 10 - Prob. 10.103EPCh. 10 - Prob. 10.104EPCh. 10 - Prob. 10.105EPCh. 10 - Prob. 10.106EPCh. 10 - The coenzyme forms of B vitamins are involved in...Ch. 10 - Prob. 10.108EPCh. 10 - Prob. 10.109EPCh. 10 - What is the relationship between the plant pigment...Ch. 10 - Prob. 10.111EPCh. 10 - Prob. 10.112EPCh. 10 - Prob. 10.113EPCh. 10 - Prob. 10.114EPCh. 10 - Prob. 10.115EPCh. 10 - In terms of their source, how do vitamin D2 and...Ch. 10 - Prob. 10.117EPCh. 10 - Why is vitamin D often called the sunshine...Ch. 10 - Prob. 10.119EPCh. 10 - Prob. 10.120EPCh. 10 - Prob. 10.121EPCh. 10 - Prob. 10.122EPCh. 10 - What is the principal function of vitamin E in the...Ch. 10 - Why is vitamin E often given to premature infants...Ch. 10 - Prob. 10.125EPCh. 10 - Prob. 10.126EPCh. 10 - Prob. 10.127EPCh. 10 - Prob. 10.128EPCh. 10 - Indicate whether each of the following pairings of...Ch. 10 - Indicate whether each of the following pairings of...Ch. 10 - Prob. 10.131EPCh. 10 - Prob. 10.132EPCh. 10 - Prob. 10.133EPCh. 10 - Which of the 13 vitamins has a structure that fits...
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