Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 1, Problem 41AP
Interpretation Introduction
Interpretation: The modifications required for four of the five original postulates of Dalton’s 1808 atomic theory of matter needs to be explained.
Concept Introduction: The major postulates of Dalton’s atomic theory are represented as follows:
- The atoms are the indivisible particles forming matter.
- For all the atoms of an element, the property such as mass is the same. For atoms of different elements, the masses are also different.
- Atoms can be combined in different ratios to form different compounds.
- Atoms can neither be created nor destroyed.
- Compounds are formed by a combination of atoms of different elements by a fixed ratio.
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In 1808, John Dalton proposed a series of statements regarding the atom that became known as Dalton's postulates or
Dalton's atomic theory. Since Dalton's original proposal, some of the statements have been updated or changed due to new
discoveries.
Which of the statements was not a' part of Dalton's original atomic theory?
Atoms of the same element have the same size, mass, and structure.
Atoms cannot be created or destroyed in a chemical reaction.
All four statements are part of Dalton's original atomic theory.
Matter is comprised of small particles called atoms.
Different elements have atoms of different masses and properties.
Incorrect
A sample of compound X (a clear, colorless, combustible liquid with a noticeable odor) is analyzed and found to contain 14.13 g carbon and 2.96 g hydrogen. A sample of compound Y (a clear, colorless, combustible liquid with a noticeable odor that is slightly different from X’s odor) is analyzed and found to contain 19.91 g carbon and 3.34 g hydrogen. Are these data an example of the law of definite proportions, the law of multiple proportions, or neither? What do these data tell you about substances X and Y?
Which of Dalton's five postulates are a consequence of the law of definite proportions?
Note:Hand written solutions are strictly prohibited.
Chapter 1 Solutions
Principles of Modern Chemistry
Ch. 1 - Classify the following materials as substances or...Ch. 1 - Classify the following materials as substances or...Ch. 1 - A 17th-century chemist wrote of the “simple bodies...Ch. 1 - Since 1800, almost 200 sincere but erroneous...Ch. 1 - A sample of ascorbic acid (vitamin C) is...Ch. 1 - A sample of a compound synthesized and purified in...Ch. 1 - Nitrogen (N) and silicon (Si) form two binary...Ch. 1 - Iodine (I) and fluorine (F) form a series of...Ch. 1 - Vanadium (V) and oxygen (O) form a series of...Ch. 1 - Prob. 10P
Ch. 1 - Prob. 11PCh. 1 - Prob. 12PCh. 1 - Pure nitrogen dioxide (NO2) forms when dinitrogen...Ch. 1 - Gaseous methanol (CH3OH) reacts with oxygen (O2)...Ch. 1 - In J. J. Thompson’s experiment depicted in Figures...Ch. 1 - In the problem 15 above, what is vy , the...Ch. 1 - The natural abundances and isotopic masses of the...Ch. 1 - The natural abundances and isotopic masses of the...Ch. 1 - Prob. 19PCh. 1 - More than half of all the atoms in naturally...Ch. 1 - The isotope of plutonium used for nuclear fission...Ch. 1 - The last “missing” element from the first six...Ch. 1 - Prob. 23PCh. 1 - In 1982, the production of a single atom of...Ch. 1 - Prob. 25PCh. 1 - Prob. 26PCh. 1 - Compute the relative molecular masses of the...Ch. 1 - Prob. 28PCh. 1 - Suppose that a person counts out gold atoms at the...Ch. 1 - A gold atom has a diameter of 2.881010m . Suppose...Ch. 1 - The vitamin A molecule has the formula C20H30O ,...Ch. 1 - Arrange the following in order of increasing mass:...Ch. 1 - Mercury is traded by the “flask,” a unit that has...Ch. 1 - Gold costs $400 per troy ounce, and...Ch. 1 - Aluminum oxide (Al2O3) occurs in nature as a...Ch. 1 - Prob. 36PCh. 1 - Soft wood chips weighing 17.2 kg are placed in an...Ch. 1 - In a reproduction of the Millikan oil-drop...Ch. 1 - A rough estimate of the radius of a nucleus is...Ch. 1 - In a neutron star, gravity causes the electrons to...Ch. 1 - Prob. 41APCh. 1 - Naturally occurring rubidium (Rb) consists of two...Ch. 1 - A sample of a gaseous binary compound of boron and...
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