EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 1, Problem 1.34AP
Interpretation Introduction
Interpretation:
The nodes of the given
Concept introduction:
Orbital is a three-dimensional region where the probability of finding of an electron is high. The principal quantum number describes the size of the orbital, azimuthal quantum number describes the shape of the orbital and magnetic quantum number describes the direction of an orbital.
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Using only the periodic table and the rules we learned in class, write the ground state electronic structure of the ground state of the Zn2+ in condensed notation.Use this sample format to enter your answer: [Xe] 4f14 5d10 6s2 6p2 (the electronic structure of Pb). The outer shell orbitals must be listed with increasing n first and increasing l second as in this example. Do not list empty orbitals. The atomic symbol of the noble gas must be typed exactly and in the correct case.
Part C
Construct the orbital diagram for the ion Mo³+.
3+
Drag the appropriate labels to their respective targets. Labels can be used once, more than once, or not at all. Not all group 2 targets will be filled.
1s 4d
2
2s
2p 5s
3s 5p
3p
3d
4f
4s
4p
5d
5f
-
1L
G1 G2
G1 G2
G1 G2
G1
G2
G1 G2
G1 G2 G2 G2
G1 G2 G2 G2
G1 G2 G2 G2
G1 G2 G2 G2 G2 G2
G1 G2 G2 G2 G2 G2
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True or false?
The 4d orbital does not exist in the carbon atom.
Justify your answer in 1 sentence or 2.
Chapter 1 Solutions
EBK ORGANIC CHEMISTRY
Ch. 1 - Prob. 1.1PCh. 1 - Prob. 1.2PCh. 1 - Prob. 1.3PCh. 1 - Prob. 1.4PCh. 1 - Prob. 1.5PCh. 1 - Prob. 1.6PCh. 1 - Prob. 1.7PCh. 1 - Prob. 1.8PCh. 1 - Prob. 1.9PCh. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Prob. 1.14PCh. 1 - Prob. 1.15PCh. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Prob. 1.21APCh. 1 - Prob. 1.22APCh. 1 - Prob. 1.23APCh. 1 - Prob. 1.24APCh. 1 - Prob. 1.25APCh. 1 - Prob. 1.26APCh. 1 - Prob. 1.27APCh. 1 - Prob. 1.28APCh. 1 - Prob. 1.29APCh. 1 - Prob. 1.30APCh. 1 - Prob. 1.31APCh. 1 - Prob. 1.32APCh. 1 - Prob. 1.33APCh. 1 - Prob. 1.34APCh. 1 - Prob. 1.35APCh. 1 - Prob. 1.36APCh. 1 - Prob. 1.37APCh. 1 - Prob. 1.38APCh. 1 - Prob. 1.39APCh. 1 - Prob. 1.40APCh. 1 - Prob. 1.41APCh. 1 - Prob. 1.42APCh. 1 - Prob. 1.43APCh. 1 - Prob. 1.44APCh. 1 - Prob. 1.45APCh. 1 - Prob. 1.46APCh. 1 - Prob. 1.47APCh. 1 - Prob. 1.48APCh. 1 - Prob. 1.49AP
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- (Q1). Out of these atoms (S,N,Mn, Ni) determine which one has the most unpaired electrons in its ground state electron configuration.arrow_forwardPart 1: Using the information provided below, derive an expression to show that the energy of an electronic transition measured from UV-VIS spectroscopy is a function of the wavelength of the light absorbed using the equations below. ν λ = cΔE = hν where E is the energy for the transition, ν is the frequency of light, λ is the wavelength, c and h are the speed of light and Plank's constant respectively (both constants). Part 2:From the derived equation, as the absorption maximum (λmax) for a molecule increases to a longer wavelength (for example from 300 to 700 nm), how does this affect the energy for the electronic transition?arrow_forwardWrite the complete ground-state electron configuration of Cd²+. For multi-digit superscripts or coefficients, use each number in succession.arrow_forward
- This question pertains to electronic transitions in a (light) multielectron atom. What are the selection rules for these transitions? The ground-state electron configuration for Zr2+ is [Kr]3d2. What are the possible values for the total orbital angular momentum for this species? For Zr2+, write the term symbol that represents the lowest energy Within the term symbol, you wrote in part c, which level of that term has the lowest energy? How many states belong to that lowest level? Classify the following three transitions as forbidden or allowed in the emission spectrum of a multielectron atom: 3D2 ->3P1 3P2 ->1S0 3F4 ->3D3arrow_forward(a) (i) Draw a pz orbital and a dx2-y2 orbital. (4)(ii) What are the differences between a 5pz orbital and a 4dx2-y2 orbital in the H atom?arrow_forwardIs it true that the smaller the azimutal quantum number the more penetrating the orbitals? If yes/no why?arrow_forward
- 11.88. Calculate (V) for ₁5 of the H atom and compare it to 1s the total energy.arrow_forwardHow many electrons does an Fe atom have in its 3d subshell and how many of those are unpaired?arrow_forwardthe orbital diagram for the ion Cd²+. Enter Drag the appropriate labels to their respective targets. Labels can be used once, more than once, or not at all. Not all group 2 targets will be filled. 1s 4d 2s 2p 3s 3p 3d 4s 4p 4f 5s 5p 5d 5f 1L G1 G2 G1 G2 G1 G2 G1 G2 G1 G2 G1 G2 G2 G2 G1 G2 G2 G2 G1 G2 G2 G2 G1 G2 G2 G2 G2 G2 G1 G2 G2 G2 G2 G2 Reset Helparrow_forward
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