Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Calculating an equilibrium constant from a partial equilibrium composition Ammonia will decompose into nitrogen and hydrogen at high temperature. An industrial chemist studying this reaction fills a 2.0 L flask with 4.4 atm of ammonia gas, and when the mixture has come to equilibrium measures the amount of nitrogen gas to be 2.0 atm. Calculate the pressure equilibrium constant for the decomposition of ammonia at the final temperature of the mixture. Round your answer to 2 significant digits. K = р x10 Ś ? olo 18 Ar Barrow_forwardFor the following reaction, the equilibrium constant Keq is 6.40 x 10-7 at 2000°C. 2CO2 (g) 2CO (g) + O2 (g) If 0.250 moles of CO2(g) is introduced into a 1.00 L vessel, calculate the equilibrium concentrations of CO(g) and O2(g) at this temperature.arrow_forwardConsider the following chemical reaction and equilibrium constant at 20 °C :CH4 (g) + 2O2 (g) ⇌ 2H2O (g) + CO2 (g) K = 2.10 x 102Based on the previous chemical reaction, what is the equilibrium constant for the following reaction at 20 °C? (Please provide your answer to 3 significant figures in scientific notation (1.23*10^5)) 2CH4 (g) + 4O2 (g) ⇌ 4H2O (g) + 2CO2 (g) K = ?arrow_forward
- The equilibrium constant, K, for the following reaction is 1.29x10-2 at 600 K. COC,(g) CO(g) + Cl2(g) + C2(g) Calculate the equilibrium concentrations of reactant and products when 0.262 moles of COCI,(g) are introduced into a 1.00 L vessel at 600 K. [COCI,] = [CO] [Ch] MMMarrow_forwardWrite the equilibrium constant expression. Solid carbon and carbon dioxide gas react and form carbon monoxide: C(s) + CO₂(g) = 2CO(g)arrow_forwardThe following reaction has an equilibrium constant, Kc equal to 3.59 at 900 °C. CH4(g) + 2H₂S(g) — CS2(g) + 4 H2(g) At a particular time during the reaction, the following composition has been found: [CH4(g)] = 1.20 M, [CS2(g)] = 1.15 M, [H₂S(g)] = 1.31 M, [H2(g)] = 1.85. Predict the activity of the reaction during the particular time above. The reaction should go to the left (or reverse) The reaction should go to the right (or forward) The reaction is at a standstill The reaction activity cannot be determined There is no basis for prediction.arrow_forward
- The equilibrium constant, Kc, for the following reaction is 1.20×10-2 at 500 K.PCl5(g) PCl3(g) + Cl2(g)Calculate the equilibrium concentrations of reactant and products when 0.246 moles of PCl5(g) are introduced into a 1.00 L vessel at 500 K. [PCl5] = M [PCl3] = M [Cl2] = Marrow_forwardThe equilibrium constant, Kc, for the following reaction is 0.00650 at 298 K. 2NOBr(g) ⇒ 2NO(g) + Br₂ (g) If an equilibrium mixture of the three gases in a 15.6 L container at 298 K contains 0.201 mol of NOBr(g) and 0.284 mol of NO, the equilibrium concentration of Br₂ is | M.arrow_forwardN2(g) and O2(g) can exist in equilibrium with NO(g), as shown below. The equilibrium constant at 25.0°C is 4.8 x 10-31. If initially there are 1.35 mol of nitrogen and 0.60 mol of oxygen in a 2.00 L vessel, find the equilibrium concentrations of each species. N2(g) + O2(g) → 2NO(g)arrow_forward
- The equilibrium constant, K, for the following reaction is 9.52×10 2 at 350 K. CH, (g) + CCI, (g)=2 CH,Cl, (g) Calculate the equilibrium concentrations of reactants and product when 0.310 moles of CH, and 0.310 moles of CCI, are introduced into a 1.00 L vessel at 350 K. [CH ] M [CCL] =D M [CH,Cl, ] = Marrow_forwardThe equilibrium constant K₁, K2 and K3 for the reactions below are S(s) + O₂(g) → SO₂(g), K₁ = 4.2 × 1052 2S (s) +30₂(g)2SO3(g), K₂ = x 2SO2(g) + O2(g)2SO3(g), The value of K₂ is 9.8 × 1028 2.6 × 1075 □ 6.7 × 10¹2 1.34 × 1032 9.8 x 10128 K3= 5.6 x 1023arrow_forwardA chemical engineer is studying the following reaction: CH₂(g) + 2H₂S(g) → CS₂(g) + 4H₂(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.7 × 10³. р The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel A B compound CH4 H₂S CS₂ H₂ CHA H₂S CS₂ H₂ pressure 5.65 atm 3.56 atm 5.77 atm 7.93 atm 4.69 atm 1.62 atm 6.73 atm 11.81 atm OO expected change in pressure ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase olo ↓decrease ↓decrease ↓ decrease ↓decrease ↓ decrease ↓decrease ↓ decrease ↓ decrease (no change) (no change) (no change) (no change) (no change) (no change) (no change) (no…arrow_forward
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