Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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A chemical engineer is studying the following reaction:
CH₂(g) + 2H₂S(g) → CS₂(g) + 4H₂(g)
At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.7 × 10³.
р
The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. He then measures the composition of the
mixture inside each vessel from time to time. His first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time he measures the compositions.
reaction
vessel
A
B
compound
CH4
H₂S
CS₂
H₂
CHA
H₂S
CS₂
H₂
pressure
5.65 atm
3.56 atm
5.77 atm
7.93 atm
4.69 atm
1.62 atm
6.73 atm
11.81 atm
OO
expected change in pressure
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
olo
↓decrease
↓decrease
↓ decrease
↓decrease
↓ decrease
↓decrease
↓ decrease
↓ decrease
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
(no change)
expand button
Transcribed Image Text:A chemical engineer is studying the following reaction: CH₂(g) + 2H₂S(g) → CS₂(g) + 4H₂(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.7 × 10³. р The engineer charges ("fills") four reaction vessels with methane and hydrogen sulfide, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel A B compound CH4 H₂S CS₂ H₂ CHA H₂S CS₂ H₂ pressure 5.65 atm 3.56 atm 5.77 atm 7.93 atm 4.69 atm 1.62 atm 6.73 atm 11.81 atm OO expected change in pressure ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase olo ↓decrease ↓decrease ↓ decrease ↓decrease ↓ decrease ↓decrease ↓ decrease ↓ decrease (no change) (no change) (no change) (no change) (no change) (no change) (no change) (no change)
reaction
vessel
A
B
C
compound
CHA
H₂S
CS₂2
H₂
CHA
4
H₂S
CS₂2
#2
CH4
H₂S
CS,
H₂
pressure
5.65 atm
3.56 atm
5.77 atm
7.93 atm
4.69 atm
1.62 atm
6.73 atm
11.81 atm
5.53 atm
3.31 atm
5.89 atm
8.44 atm
expected change in pressure
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↑ increase
↓ decrease
↓ decrease
decrease
↓ decrease
↓decrease
↓ decrease
↓ decrease
↓ decrease
↓ decrease
decrease
↓ decrease
decrease
(no change)
(no change)
(no change)
8
(no change)
(no change)
(no change)
(no change)
O(no change)
(no change)
(no change)
(no change)
(no change)
expand button
Transcribed Image Text:reaction vessel A B C compound CHA H₂S CS₂2 H₂ CHA 4 H₂S CS₂2 #2 CH4 H₂S CS, H₂ pressure 5.65 atm 3.56 atm 5.77 atm 7.93 atm 4.69 atm 1.62 atm 6.73 atm 11.81 atm 5.53 atm 3.31 atm 5.89 atm 8.44 atm expected change in pressure ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↓ decrease ↓ decrease decrease ↓ decrease ↓decrease ↓ decrease ↓ decrease ↓ decrease ↓ decrease decrease ↓ decrease decrease (no change) (no change) (no change) 8 (no change) (no change) (no change) (no change) O(no change) (no change) (no change) (no change) (no change)
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