Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- 3. For the reaction SO2(g) + NO2(g) 2 NO(g) + SO3(g), Ko = 85.0 at 4.60 x 102 °C. A reaction is started with 0.0500 M of both reactants (Note, initially no products). a) Calculate the equilibrium concentration in M of all species. (If you correctly set-up the ICE chart for this problem, you will see the equilibrium constant expression is a perfect square & so the quadratic formula is not needed. If yours is not a perfect square, check your work.)arrow_forwardA chemical engineer is studying the following reaction: N(g)+3 H,(9) - 2 NH;(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.0016. The engineer charges ("fills") three reaction vessels with nitrogen and hydrogen, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound pressure expected change in pressure vessel 11.39 atm Of increase O I decrease O (no change) H. 25.28 atm O t increase OI decrease O (no change) A NH, 16.95 atm O t increase OI decrease O (no change) 12.82 atm O t increase OI decrease O (no change) 28.45 atm O f increase OI decrease O (no change) B NH, 21.46 atm O f increase O I decrease O (no change) N 10.92 atm O f increase OI decrease O (no change) O I decrease O (no change) H. 23.86…arrow_forwardA chemical engineer is studying the following reaction: CH,CH,NH,(aq)+HCl(aq) → Cl (aq)+CH,CH,NH;(aq) At the temperature the engineer picks, the equilibrium constant K¸ for this reaction is 0.92. The engineer charges ("fills") four reaction vessels with ethylamine and hydrogen chloride, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound concentration expected change in concentration vessel CH, CH,NH, 0.79 M f increase I decrease (no change) HCl 0.69 M f increase I decrease (no change) А Cl 0.62 M f increase I decrease (no change) CH,CH,NH, 0.81 M f increase I decrease O (no change) CH, CH,NH, 1.09 M f increase I decrease (no change) HCl 0.99 M f increase I decrease (no change)arrow_forward
- A chemical engineer is studying the following reaction: H₂(g) + Cl₂(g) → 2 HCl(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 0.33. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction vessel A B с compound H₂ C1₂ HC1 H₂ CL, HCl H₂ CL₂2 HC1 pressure 4.42 atm 5.14 atm 1.90 atm 3.61 atm 4.33 atm 3.53 atm 4.59 atm 5.31 atm 1.57 atm expected change in pressure ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase ↓ decrease ↓decrease ↓ decrease ↓ decrease ↓ decrease ↓ decrease ↓decrease ↓decrease ↓ decrease (no change) (no change) (no change) (no change) (no change) (no change) (no…arrow_forwardAt a certain temperature, the equilibrium constant K for the following reaction is 5.36 x 10": H,(g) + Cl,(g) = 2 HCI(g) Use this information to complete the following table. Suppose a 33. L reaction vessel is filled with 0.63 mol of HCI. What can you say about the composition of the mixture in the vessel at equilibrium? O There will be very little H2 and Cl2. O There will be very little HCI. O Neither of the above is true. What is the equilibrium constant for the following reaction? Round your answer to 3 significant digits. K = ] 2 HCl(g) H,(9)+Cl,(9) What is the equilibrium constant for the following reaction? Round your answer to 3 significant digits. K = ] 2 H,(9)+2Cl,(9) 4 HCl(g) Continue O 2022 McGraw Hill LLC. All Rights Reserve 43,203 FEB 18 9 PP SESSarrow_forwardUsing the general properties of equilibrium constants At a certain temperature, the equilibrium constant K for the following reaction is 7.45 × 10-5: NO₂(g) + CO(g) ⇒ NO(g) + CO₂(g) Use this information to complete the following table. Suppose a 20. L reaction vessel is filled with 1.5 mol of NO and 1.5 mol of CO₂. What can you say about the composition of the mixture in the vessel at equilibrium? What is the equilibrium constant for the following reaction? Round your answer to 3 significant digits. NO(g)+CO,(9) NO₂(9)+CO(9) What is the equilibrium constant for the following reaction? Round your answer to 3 significant digits. 3 NO₂(g) + 3 CO(g) P 3 NO(g)+ 3 CO₂(9) There will be very little NO2 and CO. There will be very little NO and CO₂. Neither of the above is true. K = 0 K = 0 x10 Ś ? ollo 18 Ar BAarrow_forward
- Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. An industrial chemist studying this reaction fills a 5.0 L flask with 4.3 atm of sulfur dioxide gas and 3.9 atm of oxygen gas, and when the mixture has come to equilibrium measures the partial pressure of sulfur trioxide gas to be 3.9 atm. Calculate the pressure equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. Round your answer to 2 significant digits. K, = 0arrow_forwardA chemical engineer is studying the following reaction: H₂(g)+I₂(g) → 2 HI(g) At the temperature the engineer picks, the equilibrium constant The engineer charges ("fills") three reaction vessels with hydrogen and iodine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel A B C compound H₂ 1₂ HI H₂ 1₂ HI H₂ 1₂ HI pressure 2.39 atm 3.83 atm 4.71 atm 2.82 atm 4.26 atm 3.85 atm 3.81 atm 5.76 atm 5.21 atm expected change in pressure ↑ increase increase ↑ increase ↑ increase ↑ increase ↑ increase ↑ increase for this reaction is 1.2. р ↑ increase ↑ increase ↓ decrease ↓decrease ↓ decrease ↓ decrease ↓decrease ↓ decrease ↓ decrease ↓decrease ↓ decrease X (no change) (no change) (no change) (no change) (no change) (no change) (no change) (no change)…arrow_forwardA chemical engineer is studying the following reaction: H,(g)+L,(g) 2 HI(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.0. The engineer charges ("fills") three reaction vessels with hydrogen and iodine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel compound pressure expected change in pressure H, 2.86 atm O 1 increase O (no change) decrease 2.34 atm O t increase OI decrease O (no change) HI 1.38 atm O f increase decrease O (no change) H, 2.45 atm O t increase decrease O (no change) 1.93 atm O t increase O I decrease o (no change) B O t increase O (no change) HI 2.21 atm decrease 2.75 atm O t increase o (no change) H, decrease 2 23 atm O t Increase decrease O (no change) HI O T increase decrease…arrow_forward
- Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. An industrial chemist studying this reaction fills a 500. mL flask with 1.2 atm of sulfur dioxide gas and 4.7 atm of oxygen gas, and when the mixture has come to equilibrium measures the partial pressure of sulfur trioxide gas to be 0.60 atm. Calculate the pressure equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. Round your answer to 2 significant digits. K, -0 x10 5arrow_forwardSuppose a 500. mL flask is filled with 1.1 mol of NO2, 1.7 mol of NO and 0.90 mol of CO2. The following reaction becomes possible: NO, (g)+CO(g) NO(g) +CO,(s) The equilibrium constant K for this reaction is 0.292 at the temperature of the flask. Calculate the equilibrium molarity of NO. Round your answer to two decimal places. м B C olarrow_forwardA chemical engineer is studying the following reaction: 2 H,S(g)+302(9) → 2 SO,(g)+2H,O(9) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 3.2. The engineer charges ("fills") four reaction vessels with hydrogen sulfide and oxygen, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction compound pressure expected change in pressure vessel H,S 2.22 atm O f increase OI decrease O (no change) 3.39 atm O t increase O I decrease O (no change) so, O I decrease O (no change) 6.16 atm O t increase H,0 8.72 atm O increase O! decrease O (no change) H, S 1.96 atm O t increase OI decrease O (no change) 0, 3.00 atm O f increase O I decrease O (no change) so, OI decrease O (no change) 6.42 atm O f increase H,0 8.98 atm O f…arrow_forward
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