A chemical engineer is studying the following reaction: 4 HC1(g) + 0₂(g) →2 H₂O(g)+2C1₂(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 0.31. The engineer charges ("fills") four reaction vessels with hydrogen chloride and oxygen, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction vessel A B с compound HCI 0₂ H₂O Cl₂ HCI %₂ H₂O C1₂ HCI 0₂ H₂O Cl₂ pressure 5.09 atm 5.63 atm 3.31 atm 4.48 atm 3.91 atm 5.34 atm 3.90 atm 5.07 atm 2.74 atm 5.05 atm 4.48 atm 5.65 atm expected change in pressure O↑ increase O ↑ increase ↑ increase increase ↑ increase O↑ increase ↑ increase Ot increase ↑ increase ↑ increase O † increase Ot increase O↓ decrease O↓ decrease O↓ decrease O↓ decrease O ↓ decrease O↓ decrease O↓ decrease O↓ decrease ↓decrease ↓ decrease O ↓ decrease O↓ decrease O (no change) O (no change) O (no change) O (no change) O (no change) O (no change) (no change) O (no change) (no change) (no change) O (no change) O (no change)
A chemical engineer is studying the following reaction: 4 HC1(g) + 0₂(g) →2 H₂O(g)+2C1₂(g) At the temperature the engineer picks, the equilibrium constant K for this reaction is 0.31. The engineer charges ("fills") four reaction vessels with hydrogen chloride and oxygen, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction vessel A B с compound HCI 0₂ H₂O Cl₂ HCI %₂ H₂O C1₂ HCI 0₂ H₂O Cl₂ pressure 5.09 atm 5.63 atm 3.31 atm 4.48 atm 3.91 atm 5.34 atm 3.90 atm 5.07 atm 2.74 atm 5.05 atm 4.48 atm 5.65 atm expected change in pressure O↑ increase O ↑ increase ↑ increase increase ↑ increase O↑ increase ↑ increase Ot increase ↑ increase ↑ increase O † increase Ot increase O↓ decrease O↓ decrease O↓ decrease O↓ decrease O ↓ decrease O↓ decrease O↓ decrease O↓ decrease ↓decrease ↓ decrease O ↓ decrease O↓ decrease O (no change) O (no change) O (no change) O (no change) O (no change) O (no change) (no change) O (no change) (no change) (no change) O (no change) O (no change)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Step 1: Relation between reaction quotient and equilibrium constant
Answer:
Relation between reaction quotient QP and equilibrium constant KP is shown below:
1. When reaction mixture is at equilibrium.
2. When reaction mixture is not be at equilibrium and to establish the equilibrium reaction will move forward so that QP can increase and become equal to KP.
3. When reaction mixture is not at equilibrium and to establish the equilibrium reaction will move in reverse direction so that QP can decrease and become equal to KP.
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