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2. Explain the following observations: (a) Co(III) forms strong bonds to O- and N-donor ligands, moderately strong bonds to P-donor ligand, and weak bonds to As-donor ligands. (b) EDTA4 forms more stable complexes with trivalent first-row transition metals (M3+) than it does with the corresponding divalent metal (M²+) of each (e.g. Cr²+ vs Cr3+). EDTA is a common ligand which bonds a metal center through four oxygen and two nitrogen atoms in an octahedral geometry (Figure 1). Figure 1. EDTA binds in an octahedral geometry

2. Explain the following observations: (a) Co(III) forms strong bonds to O- and N-donor ligands, moderately strong bonds to P-donor ligand, and weak bonds to As-donor ligands. (b) EDTA4 forms more stable complexes with trivalent first-row transition metals (M3+) than it does with the corresponding divalent metal (M²+) of each (e.g. Cr²+ vs Cr3+). EDTA is a common ligand which bonds a metal center through four oxygen and two nitrogen atoms in an octahedral geometry (Figure 1). Figure 1. EDTA binds in an octahedral geometry

Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
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2. Explain the following observations: (a) Co(III) forms strong bonds to O- and N-donor ligands, moderately strong bonds to P-donor ligand, and weak bonds to As-donor ligands. (b) EDTA4 forms more stable complexes with trivalent first-row transition metals (M3+) than it does with the corresponding divalent metal (M²+) of each (e.g. Cr²+ vs Cr3+). EDTA is a common ligand which bonds a metal center through four oxygen and two nitrogen atoms in an octahedral geometry (Figure 1). Figure 1. EDTA binds in an octahedral geometry
Transcribed Image Text:2. Explain the following observations: (a) Co(III) forms strong bonds to O- and N-donor ligands, moderately strong bonds to P-donor ligand, and weak bonds to As-donor ligands. (b) EDTA4 forms more stable complexes with trivalent first-row transition metals (M3+) than it does with the corresponding divalent metal (M²+) of each (e.g. Cr²+ vs Cr3+). EDTA is a common ligand which bonds a metal center through four oxygen and two nitrogen atoms in an octahedral geometry (Figure 1). Figure 1. EDTA binds in an octahedral geometry
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