Questions 2 What product would you expect to obtain from aldol cyclization of adipaldehyde in basic solution. Show your work. adipaldehyde base
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- Question 1: Identify the starting compounds necessary to synthesize the product below by an aldol condensation reaction.lomatudlvrismib 3) Which of the following reagents will quantitatively convert an enolizable ketone to its enolate salt? A) lithium hydroxide B) pyridine miegunthed gaisnasab to do C) methyllithium lonnard- D) diethylamine E) lithium diisopropylamide > IIIQUESTIONS 1. Examine the given reaction below. This is a intramolecular Friedel Crafts acylation reaction. As you can see from the product, the acylation undergoes only with the right ring. Why do you think it doesnt undergo with the left ring? CI AICI, + HCI + AICI,a) The reaction below concerns an intramolecular Aldol condensation reaction. NaOH E CH3 H i) Redraw the above dicarbonyl compound and identify the most acidic hydrogen. ii) Draw the structure of two resonance contributors of the enolate anions derived from the above compound. iii) Propose the step-wise mechanism for the formation of the Aldol product and consequently the dehydrated product by showing all curve arrows.1. Provide the mechanism of the reaction shown in the picture. 2. Explain why it cannot be done in basic conditions. 3. Why is the enol tautomer favored over the keto tautomer? Ph H3C OH H H3O+/H₂O HO H3C PhQUESTIONS 1. Examine the given reaction below. This is a intramolecular Friedel Crafts acylation reaction. As you can see from the product, the acylation undergoes only with the right ring. Why do you think it doesnt undergo with the left ring? CI AICI, + HCI + AICl3 CIWhat is occuring in this aldol reaction?The aldol reaction is catalyzed by acid as well as by base. Write a detailed mechanism for the acid-catalyzed condensation of acetaldehyde (equation below), and use it to respond. H₂C H acetaldehyde Draw the reactive electrophile. HCI H3C OH O H B-hydroxybutanal HCI warm • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • When there is a choice, draw the most stable resonance form. H3C 2-butenal H1. NaOEt 2. H2SO4 / heat Which compound is the correct product for the intramolecular Aldol reaction shown?SEE MORE QUESTIONS
