(a)
Interpretation: The relationship between pair 1 and 6 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. They may have different arrangements but by rotation the molecule become superimposable to the other.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(b)
Interpretation: The relationship between pair 2 and 3 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(c)
Interpretation: The relationship between pair 2 and 4 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(d)
Interpretation: The relationship between pair 4 and 5 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(e)
Interpretation: The relationship between pair 5 and 8 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(f)
Interpretation: The relationship between pair 2 and 7 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(g)
Interpretation: The relationship between pair 8 and 9 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(h)
Interpretation: The relationship between pair 7 and 10 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(i)
Interpretation: The relationship between pair 11 and 12 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(j)
Interpretation: The relationship between pair 11 and 13 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(k)
Interpretation: The relationship between pair 12 and 13 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(l)
Interpretation: The relationship between pair 11 and 2 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(m)
Interpretation: The relationship between pair 11 and 3 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(m)
Interpretation: The relationship between pair 12 and 2 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(n)
Interpretation: The relationship between pair 12 and 3 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
(o)
Interpretation: The relationship between pair 7 and 14 needs to be described.
Concept Introduction: The possible relationship between two structures depends on the molecular formula and structural arrangement of atoms in the molecules.
The possible relations are as follows:
Identical: Two molecular structures are identical if they have same molecular formula as well as same arrangement of atoms. The bonding substituent and their positions are same in the identical molecules.
Conformers: Two molecules are said to be conformer if they have different orientation of atoms by rotation around a single bond. They are also known as conformational isomer. For example, eclipse and staggered conformation.
Configurational isomer: They cannot be converted into one another due to the rotation around a single bond. For example, geometric and optical isomers. They can be interconverted after breaking of old bonds and making of new bonds.
Constitutional isomer: They are also known as structural isomers. They have same molecular formula, but the bonding of groups is different. For example, n-pentane and isopentane.
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Organic Chemistry: A Guided Inquiry
- FOR/ • Ang • Tors • Ster O what structural cfects do the ff. opds exhivit? Enumate all. Then idenbify the pred ommant effect. (a) 언 NO2 (c) 1.4 S Elecarrow_forward12) How are these molecules related? А. conformational isomers В. enantiomers C. diastereomers F D. constitutional isomersarrow_forwardI need help with both parts here. An FYI if you need, Part 2 means enantiomers, diasteromers, or constitutional isomers.arrow_forward
- Which structure (or structures) represents (or represent) the enantiomer of the molecule below? I OCH 3 &&&* IV I III and IV ||| || OCH3 OH OCH 3 & II || Br III OCH3 H3CO/I IVarrow_forwardButanal (C4H&O) has eight H atoms. Suppose that any of these H atoms can be replaced by a Cl atom to yield a molecule with the formula C4H¬CIO. (a) Identify two H atoms where this substitution would yield constitutional isomers of C4H7CIO; (b) enantiomers of C4H;CIO; (c) conformers of C4H;CIO. H. H H H нн H Butanal O=Uarrow_forwardFor the pair of structures indicate what type of isomeric relationship they have at room temperature. The possibilities are structural isomers, conformational isomers, enantiomers, diastereomers, and meso compound. O |||||OH CH3 "1110 ...IOH CH3 AV Aarrow_forward
- Classifying Compounds as Stereoisomers or Different Conformations Classify each pair of compounds as stereoisomers or conformations: (a) X and Y; (b) X and Z.arrow_forwardDetermine whether each pair of molecules represent: (a) identical compounds; (b) constitutional (structural) isomers, (c) enantiomers, or (d) diastereomers. А. В. OH Br Br Он F F OH OH С. D. CH3 H H .CI CI CI Br Br ČH3 Е. CI H Но CI `CH3 HO. CI CH2CH3arrow_forward4. For each pair Stute whetter th two are DJ HHe Same moleclle, b) defferent compounds that ave not isomers, C) constitutonal isomers dl diastereomers, or e enantiomers, SH a) Hs Octs Br CH3 iBr b)arrow_forward
- Q2 Give the stereochemical relationships between each pair of structures. Examples are same compound, structural isomers, enantiomers, diastereomers fa CH. OH HO- OR HO CH, CH. CH,arrow_forward• Question 5: Label each stereogenic center as R or S. CH₂ a. CH₂CH₂ b. CH H 1 NH₂ H CH3 CH₂CH₂ T C. D CI CH3 d. Br C ICH₂ H e. f. H* HO C HOOC CH₂ HO CH(CH3)2 -C₂ C CH3 SH NH₂ H CH3 g. h. .CI CIarrow_forwardClassify each attached pair of compounds as stereoisomers or conformations: (a) X and Y; (b) X and Z.arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning