Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 11, Problem 11.5P
Interpretation Introduction
Interpretation: The reason corresponding to the fact that an
Concept introduction: The temperature at which a liquid starts changing its phase into a gas is known as boiling point.
The
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Cyclopentane has a higher boiling point than pentane even though both compounds have the same number of carbons (49 °C vs. 36 °C). Can you suggest a reason for this phenomenon?
Give at least 3 features in the structure of an alkene.
Which one of the following compounds is an alkene?
CH3-CH2-0-CH2–CH3
||
CH 3-CH 2-C -H
OH
CH3 -CH-CH 3
CH3-CH-CH-CH2–CH3
O CH3-S-H
Chapter 11 Solutions
Organic Chemistry
Ch. 11 - Draw structures for the three alkynes having...Ch. 11 - Prob. 11.2PCh. 11 - Give the IUPAC name for each compound.Ch. 11 - Give the structures corresponding to each of the...Ch. 11 - Prob. 11.5PCh. 11 - Prob. 11.6PCh. 11 - Which bases can deprotonate acetylene? The pKa...Ch. 11 - Draw the organic products formed when each alkyne...Ch. 11 - Prob. 11.9PCh. 11 - Problem 11.9 Draw the products formed when is...
Ch. 11 - Explain the following result. Although alkenes...Ch. 11 - Problem 11.11 Draw the keto tautomer of each...Ch. 11 - Prob. 11.13PCh. 11 - a Draw two different enol tautomers of...Ch. 11 - Prob. 11.15PCh. 11 - Prob. 11.16PCh. 11 - Prob. 11.17PCh. 11 - Problem. 11.17 Show how , and can be used to...Ch. 11 - Prob. 11.19PCh. 11 - Draw the products of each reaction. a. b.Ch. 11 - Prob. 11.21PCh. 11 - Problem 11.21 Use retrosynthetic analysis to show...Ch. 11 - Prob. 11.23PCh. 11 - Give the IUPAC name for each compound. a. b.Ch. 11 - Prob. 11.25PCh. 11 - 11.25 Answer the following questions about...Ch. 11 - Prob. 11.27PCh. 11 - Give the IUPAC name for each alkyne.Ch. 11 - Prob. 11.29PCh. 11 - Which of the following pairs of compounds...Ch. 11 - Prob. 11.31PCh. 11 - 11.30 How is each compound related to A? Choose...Ch. 11 - Prob. 11.33PCh. 11 - Prob. 11.34PCh. 11 - Prob. 11.35PCh. 11 - 11.33 Draw the products formed when is treated...Ch. 11 - Draw the products formed when 3-hexyne is treated...Ch. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - What alkynes give each of the following ketones as...Ch. 11 - Prob. 11.41PCh. 11 - 11.37 What alkyne gives each compound as the only...Ch. 11 - Prob. 11.43PCh. 11 - Draw the structure of compounds A-E in the...Ch. 11 - Prob. 11.45PCh. 11 - Prob. 11.46PCh. 11 - 11.42 What reactions are needed to convert alcohol...Ch. 11 - Prob. 11.48PCh. 11 - Prob. 11.49PCh. 11 - 11.45 Explain the following statement. Although ...Ch. 11 - Draw a stepwise mechanism for the following...Ch. 11 - Prob. 11.52PCh. 11 - Prob. 11.53PCh. 11 - Prob. 11.54PCh. 11 - Prob. 11.55PCh. 11 - Synthesize each compound from acetylene. You may...Ch. 11 - Prob. 11.57PCh. 11 - Prob. 11.58PCh. 11 - 11.55 Devise a synthesis of the ketone, , from ...Ch. 11 - 11.56 Devise a synthesis of each compound using ...Ch. 11 - Prob. 11.61PCh. 11 - Prob. 11.62PCh. 11 - 11.60 Draw a stepwise mechanism for the following...Ch. 11 - Draw a stepwise mechanism for the following...Ch. 11 - Prob. 11.65PCh. 11 - Write a stepwise mechanism for each of the...Ch. 11 - Prob. 11.67PCh. 11 - 11.65 Explain why an optically active solution of ...
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- How could 2,6-dimethylheptane be prepared from an alkyne and an alkyl halide? (The prime in R′ signifies that R and R′ can be different alkyl groups.)arrow_forwardWhich reagent is needed to change an alkyne to an alkane? * Н:0+, Hg (COОH)2 N2, Pt Ог, Pd Н, Pt What reaction takes place when an alcohol is produced during the net addition of water across the double bond of an alkene? * Dehydrogenation Hydrogenation Dehydration Hydrationarrow_forwardCompounds with two carbonyl groups are named as alkane diones, for example: R 2,3-butanedione The compound above is an artificial flavor added to microwave popcorn and movie-theater popcorn to simulate the butter flavor. Interestingly, this very same compound is also known to contribute to body odor. Name the following compounds: cyclohexane-1,3-dione cycloheptane-1,4-dione gily nonane-2,8-dionearrow_forward
- Draw the structure of the given compound. Identify if the given name is correct of incorrect. If not, provide the correct IUPAC name of the compound. Don’t use CIS/TRANS or E/Z in naming the compounds. 1) 1-ETHYLCYCLOPENT-2-ENE 2) 7-HYDROXYNONAN-3-OL 3) 4-ETHYL-5,5-DIMETHYLNON-8-EN-1-YNE Note: need answers immediately. Will give a good rate right away as well.arrow_forwardHeats of hydrogenation for alkenes. Hydrogenation of alkenes and alkynes are exothermic. Compare the hydrogenations (1 or 2 H2(g), Pt) of the following pairs of compounds. For each pair, circle the compound which you expect will have the larger heat of hydrogentation. or or orarrow_forwardCollege Chem II CHE 132 Saturated & Unsaturated Hydrocarbons 1. The following compounds are named incorrectly. Draw the structure of each compound and give it a correct IUPAC name. a) 2-ethyl-4-methylbutane b) 2-isopropyl-3-ethylpentane Hs C - CH-CH3 ansiba C H3- CH - CH-CH2-CH3 A14-ethyl-2,3-dimethyinexane) CH z opanthine CH3 c) 1-propyl-2-ethylbutane CH3 -CH2 - CH- CH2-,CH-CH>-CH; 13-0thylpetane) CHa d) 2,2-diethylpropane e) 3-sec-butylpentane f) 2,4-diethylhexanearrow_forward
- 33) Cis-trans isomerism occurs when a branched alkane has a halogen added to two adjacent carbon atoms. an alkene is hydrated according to Markovnikov's Rule. the carbons in an alkene double bond have different substituent groups. the carbons in an alkene double bond each have the same substituent groups. hydrogen is added to both of the carbon atoms in a double bond.arrow_forwardWhat alkane, with molecular formula C5H12, forms only one monochlorinated product when it is heated with Cl2?arrow_forward3 Give the systematic name of the given alkene based on its semi-structural formula. CH, CH, CH3 CH, - C = CH — с %3 CH - CH, CH - - CH2 CH, Systematic name:arrow_forward
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