Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Question
Chapter F, Problem 3PP
Interpretation Introduction
Interpretation:
The given allyl disulfide is to be synthesised from allyl bromide.
Concept introduction:
Thiols and disulphides undergo
This can be depicted as:
Sulphur ylide acts as a nucleophile and attacks the carbonyl carbon of
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Practice Question:
Outline all the necessary reactions with the minimum number of steps required to synthesize tert-butyl pentanoate from alkenes. Show the different organic reactions needed, starting from the reaction of an alkene. There is 5 reactions.
For each reaction, you must name the type of reaction, the reactant(s), and the product(s).
PROBLEM F.5 Write the IUPAC name for each of the following compounds.
tod
N
(a)
(b)
-OH
(c)
N
Problem 1
1. NaH,
2. LiAlH4
O
NaH/
1. LIAIH
2. TsCl, pyridine
3. NaH/ EtooC
COOEt
1. NaCl/heat (decarboxylation)
2. LiAlH4
3. PCC
Chapter F Solutions
Organic Chemistry
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- Problem 5) Identify the product. HO 2 2 8 8 8 OH A 1) NaOH 2) LAH B C D Earrow_forwardProblem 2 Give IUPAC names for the following compounds: (a) CI Br (b) CH3 (c) „NH2 CH2CH;ĊHCH3 (d) CI CH3 (e) CH2CH3 (T) CH3 CH3 'CI O,N NO2 H3C `CH3arrow_forwardProblem 1 1. NaH, 2. LiAlH4 NaH/ 1. LIAIH 2. TSCI, pyridine 3. NaH/ Etooc COOEt 1. NaCl/heat (decarboxylation) 2. LIAIH 3. PCCarrow_forward
- Reduction In organic chemistry, reduction is defined as a reaction in which a carbon atom forms fewer bonds to oxygen, O, or more bonds to hydrogen, H. OH H3C-C-CH3 + [H] →>>> H3C-C-CH3 H propanone 2-propanol Practice Problems; Draw and name the product of each reduction. →> (d) CH2=CH2 + [H] − (e) 3-pentanone + [H] - →> (f) CH3CH2C=CH + [H] → (i) + [H] → (ii) (g) 2-ethyl-3,4-dimethyloctanal + [H] →arrow_forwardProble Write the IUPAC name of each compound. =+ (a) (b) (c) = -Brarrow_forwardPROBLEM 3-4 Provide IUPAC names for the following compounds. (a) (CH3)2CHCH½CH3 (b) CH3— С (СН3)2 — СHз - CH,CH, CH, CH,CH, (c) CH,CH,CH,CH–CH(CH,), (d) CH,-CH-CH,-CH-CH, | Ç(CH,), CH,-CHCH,CH, e) CH,CH,CHCHCH, (f) (CH,),C-CH–CH,CH,CH, CH(CH,),arrow_forward
- PROBLEM F.2 Write the IUPAC name for each of the following compounds. (a) НО (b) EN H₂N 0 0 (c) NH₂arrow_forwardWhich of the compounds below can only form a single product upon exposure to NaOMe in MeOH (select all that apply): Ph A B C Darrow_forwardwhich of the following structures is aromatic (select all that apply)? N A B C D E F G Harrow_forward
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