ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
Question
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Chapter 9.10B, Problem 9.24P

(a)

Interpretation Introduction

To determine: The structure of the alkyne that undergoes oxidative cleavage to give adipic acid and two equivalents of acetic acid.

Interpretation: The structure of the alkyne that undergoes oxidative cleavage to give adipic acid and two equivalents of acetic acid is to be proposed.

Concept introduction: An oxidative cleavage results in formation of CO bonds in place of CC bonds. The unknown reactants in the reaction can be found from retro synthesis process. Retro synthesis solves the problems related to the organic reactions and aids in planning of desired molecules.

Ozonolysis is the process, in which triple bonds of alkyne molecules cleave with ozone.

(b)

Interpretation Introduction

To determine: The structure of the alkyne that undergoes oxidative cleavage to give a triacid and propionic acid.

Interpretation: The structure of the alkyne that undergoes oxidative cleavage to give a triacid and propionic acid is to be shown.

Concept introduction: The oxidative cleavage results in the formation of CO bonds in place of CC bonds. The unknown reactants in the reaction can be found from retro synthesis process. Retro synthesis solves the problems related to the organic reactions and aids in planning of desired molecules.

Ozonolysis is the process, in which triple bonds of alkyne molecules cleave with ozone.

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Students have asked these similar questions
3. Please draw the most important (stable) resonance form of the carbonation that mediates the following reaction: OH H3O+ O 4. Draw the structure of the alkene isomer (with the molecular formula of C5H10) that is most reactive one in the addition reaction with Br₂.
9. The following picture which illustrates the overlap of 2p orbitals to form the T-bonds of an alkyne clearly shows that the angle of the o-bonds must be (a) 120°, (b) 180°, (c) 109.5°. (d) 60° TT H. TT 10. What is the correct name for the following alkyne? (a) 2-chloro-6-methyl-4-heptyne (b) 6-chloro-2-pethyl-3-heptyne (c) 4-chloro-1-isopropyl-1-pentyne (d) isopropyl 2-chloropropyl acetylene CI 11. Select the structure which corresponds to the name 1-methyl-1,3,5-cyclooctatriene (а) (b) (c) (d)
问题5 5分 Which of the following describe the major product(s) of this reduction reaction (you may assume excess LIAIH4 is used)? 1. LİAIH4 2. H20 rning primary alcohol secondary alcohol tertiary alcohol aldehyde ketone ester

Chapter 9 Solutions

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