ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Textbook Question
Chapter 9.1, Problem 9.1P
- a. Count the elements of unsaturation in parsalmide, ethynyl estradiol and dynemicm A.
- b. Draw structural formulas of at least two
alkynes of each molecular formula.- 1. C6H10
- 2. C8H12
- 3. C7H8
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C. Draw a structural formula for the principal organic product formed when each compound is treated with
K2CrzOr/H2SO4 if there is no reaction, say so.
1. butanal
2. benzaldehyde
3. cyclohexanone
4. cyclohexanol
5. 2-pentanone
3. Draw a structure (your preferred type) for each of the following unsaturated
hydrocarbons.
a. 2,5,6-trimethyl-3-heptyne
b. p-difluorobenzene
4. Draw a structure (your preferred type) for each of the following:
a. m-lodobenzoic acid
b. Ethyl propyl ether
c. 5-ethyloctanal
d. 4-isopropyl-3-hexanone
4. How many actual double bonds does the benzene ring possess?
a. 4
b. 3
c. 2
d. 1
e. 0
5.
H2C-CH
The correct name for the compound given above is which of the following?
a. 2-methy-1-butene
b. pentene
c. 2-ethy-l-propene
d. 3-methy-2-butene
e. 2-ethyl-l-pentene
6.
CH3
H;C-C-CH-CH;
CH,
What is the correct name for the above compound?
a. 2,3-dimethylbutane
b. hexane
d. 2,2-dimethylbutane
e. isohexane
c. 2-methylpentane
Chapter 9 Solutions
ORGANIC CHEMISTRY
Ch. 9.1 - a. Count the elements of unsaturation in...Ch. 9.2 - Prob. 9.2PCh. 9.4B - What reaction would acetylene likely undergo if it...Ch. 9.6 - Prob. 9.4PCh. 9.6 - Predict the products of the following acid-base...Ch. 9.7A - Solved Problem9-1 showed the synthesis of...Ch. 9.7A - Show how you might synthesize the following...Ch. 9.7B - Prob. 9.8PCh. 9.7B - Show how you would synthesize...Ch. 9.8 - When 2,2-dibromo-1-phenylpropane is heated...
Ch. 9.8 - When 2,2-dibromo-1-phenylpropane is heated...Ch. 9.9C - Show how you would convert a. oct-3-yne to...Ch. 9.9C - The fragrance of (Z)-1-phenylhex-2-en-1-ol...Ch. 9.9D - In the addition of just 1 mole of bromine to 1...Ch. 9.9E - Propose a mechanism for the entire reaction of...Ch. 9.9E - Predict the major product(s) of the following...Ch. 9.9E - Propose a mechanism for the reaction of pent-1-yne...Ch. 9.9E - Show how hex-1-yne might be converted to a....Ch. 9.9F - When pent-2-yne reacts with mercuric sulfate in...Ch. 9.9F - Prob. 9.20PCh. 9.9F - Prob. 9.21PCh. 9.9F - Prob. 9.22PCh. 9.10A - Predict the product(s) you would expect from...Ch. 9.10B - Prob. 9.24PCh. 9.10B - Prob. 9.25PCh. 9 - Prob. 9.26SPCh. 9 - Give common names for the following compounds. a....Ch. 9 - Prob. 9.28SPCh. 9 - Prob. 9.29SPCh. 9 - Using cyclooctyne as your starting material, show...Ch. 9 - Prob. 9.31SPCh. 9 - Prob. 9.32SPCh. 9 - Predict the products of reaction of pent-1-yne...Ch. 9 - Show how you would accomplish the following...Ch. 9 - Show how you would synthesize the following...Ch. 9 - Predict the products formed when CH3CH2C C : Na+...Ch. 9 - Prob. 9.37SPCh. 9 - Prob. 9.38SPCh. 9 - When compound Z is treated with ozone, followed by...Ch. 9 - Show how you would convert the following starting...Ch. 9 - The following functional-group interchange is a...Ch. 9 - Using any necessary inorganic reagents, show how...Ch. 9 - Prob. 9.43SP
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