Concept explainers
(a)
To determine: The synthesis of
Interpretation: The synthesis of
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(b)
To determine: The synthesis of
Interpretation: The synthesis of
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(c)
To determine: The synthesis of
Interpretation: The synthesis of
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(d)
To determine: The synthesis of
Interpretation: The synthesis of
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(e)
To determine: The synthesis of
Interpretation: The synthesis of
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(f)
To determine: The synthesis of
Interpretation: The synthesis of
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(g)
To determine: The synthesis of pentanoic acid, using
Interpretation: The synthesis of pentanoic acid, using
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(h)
To determine: The synthesis of pentanal, using
Interpretation: The synthesis of pentanal, using
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
(i)
To determine: The synthesis of
Interpretation: The synthesis of
Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that are used during the reactions. The mechanism in alkene and alkynes proceed through the breaking of double or triple bonds because pi bonds are less stable.
Stability of product should be high for the formation of a high yield product. The reagents perform numerous functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.
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Chapter 9 Solutions
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
- Draw the structures for the following molecules. Write your answers on clean scratch papers and upload it after you've taken the exam. A. (R)-pentane-1,2,4-triol B. Cyclopentyloxycycloheptane C. (1R,2R)-Cyclohexane-1,2-diol D. Isobutyl phenyl ether (hint: phenyl is a benzene ring acting as a substituent) E. 2-methyl-3-propylpentane-1,5-diol F. 2-ethyl-3-isopropylbutane-1,4-diolarrow_forwardGive the structure corresponding to each name. a. 3-chloro-2-methylhexane b. 4-ethyl-5-iodo-2,2-dimethyloctane c. cis-1,3-dichlorocyclopentane d. 1,1,3-tribromocyclohexane e. propyl chloride f. sec-butyl bromidearrow_forward1. 2-bromobutane + cyclohexanol + NaH à (major product) c. 2-butoxycyclohexane a.. 2-butene reaction b. 1-butene d. no e. something else! 2. t-butylbromide + sodium ethoxide in ethanol à (major product) a. 2-methylpropene reaction b. t-butyl ethyl ether c. 1-methylbutene d. no e. something else! 3. potassium t-butoxide + 1-bromobutane in t-butyl alcohol room temperature à (major product) a. 1-butene reaction c. 2-methylpropene d. no b. butyl t-butyl ether e. something else! 4. t-butyl bromide + boiling hot water à (major product) a. 2-methylpropene reaction b. t-butyl ethyl ether c. t-butanol d. no e. something else! 5. 2-chloropropane + acetic acid (2 eq) / KOH (1 eq) / DMF à(major product) c. b. d. no reaction e. something а. HO. else! Br KOH / DMSO 6. b. 2-methyl-1-propanol d. 1,2- a. 2-methylpropene propanediene c. no reaction e. something else! 7. cyclopentanol+ NaH + DMSO + bromopropane à(major product) a. cyclopentene reaction b. propene e. something else!! c. propyl cyclopentyl…arrow_forward
- Give the structure corresponding to each name. a.3-chloro-2-methylhexane b.4-ethyl-5-iodo-2,2-dimethyloctane c.cis-1,3-dichlorocyclopentane d.1,1,3-tribromocyclohexane e. 6-ethyl-3-iodo-3,5-dimethylnonane f.(R)-1-fluoro-2,6,6-trimethylnonanearrow_forward2. Draw the structure corresponding to the provided name. a. 3,4-dimethyl-1-pentyne b. 2,5-dimethyl-3-hexyne c. 3-methoxy-1-pentyne d. 4-methyl-1-hepten-5-yne e. 4,9-dimethyl-3-decen-7-yne f. 2-methyl-1-penten-3-yne g. 3,6-dimethyl-1,4-octadiyne h. 7-ethyl-1,4-nonadiynearrow_forwardReagents a. C6H5CHO b. NaOH, ethanol h. BrCH2CH=CH2 i. Na* OEt, ethanol j. Br2, H* k. K* t-BuO c. Pyrrolidine, cat. H* d. H2C=CHCN e. H3O* f. I. CH2(CO2ET)2 -CH2CH2CN LDA m. heat g. ELOC(=0)CO2ET Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).arrow_forward
- Please do the following. Step by step. A. 1-butyne + HCl B. 1-butyne + Cl2arrow_forward2. Name each alkyne. a. CH3CH₂CH₂C=CH b. CH3CH₂CH₂C=CCH3 3. Predict the product of the following reactions. a. CH = CCH3 + HCI b. CH CCH₂CH3 + O2arrow_forward22. Which of the following hydrocarbons requires 2 moles of Br2? A. 1-butene B. 1-butyne C. 1,3-butadiene D. B and C 23. Which of the following generates the most stable carbonium ion? A. Methyl carbonium ion B. tertiary carbonium ion C. allyl carbonium ion D. ethyl carbonium ion 24. If the reaction below is conducted under kinetic controlled conditions, which is the major product? 20=20 toarrow_forward
- 1. An alkene reacts with water with an acid catalyst results into a formation of: A. Aldehyde B. Ketone C. Alcohol D. Ester 2. 3-Methylhexanal with K2Cr2O7 will yield: A. 3-Methyl-1-hexanol B. 3-Methylhexanoic acid C. 3-Methyl-1-hexanone D. 3-Methyl-1-hexanethiol 3. This is a reverse process of Hydration reaction: A. Oxidation reaction B. Reduction reaction C. Dehydration reaction D. Hydration reaction 4. Acetic acid reacts with a strong base forms: A. Salt B. Water C. Salt and Water D. No reaction 5. Ketones can be further oxidized with benedict's solution into: A. Alcohol B. Aldehyde C. Catalysts D. No reactionarrow_forwardDraw the products obtained from the SN2 reaction of a. 2-bromobutane and methoxide ion. b. (R)-2-bromobutane and methoxide ion. c. (S)-3-chlorohexane and hydroxide ion. d. 3-iodopentane and hydroxide ion.arrow_forwardThe dehydrochlorination of 3-chloro-2-methylpentane in the presence of (CH3)3N, Ag2O and heat produces A. 2-methypent-2-ene B. 2-methypentane C. 2-methypent-3-ene D. 4-methypent-2-ene Which of the following species is electron repelling? A. –N2 B. –S- C. –Br D. –OHarrow_forward
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