University Physics Volume 3
17th Edition
ISBN: 9781938168185
Author: William Moebs, Jeff Sanny
Publisher: OpenStax
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Textbook Question
Chapter 9, Problem 50P
In a physics lab, you measure the vibrational- rotational spectrum of potassium bromide (KBr). The estimated separation between absorption peaks is
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An H2 molecule is in its vibrational and rotational ground states. It absorbs aphoton of wavelength 2.2112 µm and makes a transition to the ν = 1, J = 1energy level. It then drops to the ν = 0, J = 2 energy level while emitting6/9SIX1011a photon of wavelength 2.4054 µm. Calculate (i) the moment of inertia of theH2 molecule about an axis through its centre of mass and perpendicular tothe H − H bond, (ii) the vibrational frequency of the H2 molecule, and (iii) theequilibrium separation distance for this molecule.
p9C.1 Familiarity with the magnitudes of overlap integrals is useful when con-
sidering bonding abilities of atoms, and hydrogenic orbitals give an indication
of their values. (a) The overlap integral between two hydrogenic 2s orbitals is
1 ( ZR
ZR
+.
2а, " 12 а,
1
+
ZR
240 a,
-ZR/Z0
S(2s, 2s)={1+
Plot this expression. (b) For what internuclear distance is S(2s,2s) = 0.50?
(c) The side-by-side overlap of two 2p orbitals of atoms of atomic number Z is
ZR
1 ( ZR
ZR
S(2p,2p) ={1+
10 a,
2a,
120
a.
Plot this expression. (d) Evaluate S(2s,2p) at the internuclear distance you
calculated in part (b).
(b): the potential energy of a diatomic molecule is given by U =
B
where A and B are constants and r is the separation
A
r12
r6
distance between the atoms. For the H2 molecule, take A = 0.124
x 10-120 eV. m² and B = 1.488 × 10-60 eV . m°. Find the
separation distance at which the energy of the molecule is a
%3D
minimum.
Chapter 9 Solutions
University Physics Volume 3
Ch. 9 - Check Your Understanding Why is the potential...Ch. 9 - Check Your Understanding What does the energy...Ch. 9 - Check Your Understanding If the dissociation...Ch. 9 - Check Your Understanding What happens to the...Ch. 9 - Check Your Understanding How does the magnitude of...Ch. 9 - Check Your Understanding What conditions are...Ch. 9 - What is the main difference between an ionic bond,...Ch. 9 - For the following cases, what type of bonding...Ch. 9 - Describe three steps to ionic bonding.Ch. 9 - What prevents a positive and negative ion from...
Ch. 9 - For the H2 molecule, why must the spins the...Ch. 9 - Does the absorption spectrum of the diatomic...Ch. 9 - Rank the energy spacing (E) of the following...Ch. 9 - Explain key features of a vibrational-rotation...Ch. 9 - Why is tbe equilibrium separation distance between...Ch. 9 - Describe the difference between a face-centered...Ch. 9 - In sodium chloride, how many Clatoms are “nearest...Ch. 9 - In cesium iodide, how many Clatoms are "nearest...Ch. 9 - The NaCl crystal structure is FCC. The equilibrium...Ch. 9 - Why does the Fermi energy (EF) increase with the...Ch. 9 - If the election number density (N/V) of a metal...Ch. 9 - Why does the horizontal Line in the graph in...Ch. 9 - Why does the graph in Figure 9.12 increase...Ch. 9 - Why are the sharp transitions at the Fermi energy...Ch. 9 - What are the two main approaches used to determine...Ch. 9 - Describe two features of energy levels for an...Ch. 9 - How does the number of energy levels in a band...Ch. 9 - Why are some materials very good conductors and...Ch. 9 - Why are some materials semiconductors?Ch. 9 - Why does the resistance of a semiconductor...Ch. 9 - What kind of semiconductor is produced if...Ch. 9 - What kind of semiconductor is produced if silicon...Ch. 9 - What is the Hall effect and what is it used for?Ch. 9 - For an n-type semiconductor, how do impurity atoms...Ch. 9 - For a p-type semiconductor, how do impurity atoms...Ch. 9 - When p- and n-type materials are joined, why is a...Ch. 9 - When p- and n-type materials are joined, why does...Ch. 9 - How do you know if a diode is in the forward...Ch. 9 - Why does the reverse bias configuration lead to a...Ch. 9 - What happens in the extreme case that where the n-...Ch. 9 - Explain how an audio amplifier works, using the...Ch. 9 - Describe two main features of a superconductor.Ch. 9 - How does BCS theory explain superconductivity?Ch. 9 - What is the Meissner effect?Ch. 9 - What impact does an increasing magnetic field have...Ch. 9 - The electron configuration of carbon is 1s22s22p2....Ch. 9 - Potassium chloride (KCl) is a molecule formed by...Ch. 9 - The electron affinity of Cl is 3.89 eV and the...Ch. 9 - The measured energy dissociated energy of KC1 is...Ch. 9 - In a physics lab, you measure the vibrational-...Ch. 9 - For the preceding problem, find the equilibrium...Ch. 9 - The separation between oxygen atoms in an O2...Ch. 9 - The characteristic energy of the N2 molecule is...Ch. 9 - The characteristic energy for KCl is 1.4105eV ....Ch. 9 - A diatomic F2 molecule is in the l = 1 state, (a)...Ch. 9 - In a physics lab, you measure the vibrational-...Ch. 9 - The Csl crystal structure is BCC. The equilibrium...Ch. 9 - The potential energy of a crystal is - 8.10 eV/ion...Ch. 9 - The measured density of a NaF crystal is 2.558...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - Determine the dissociation energy of 12 moles of...Ch. 9 - The measured density of a KCl crystal is 1.984...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - The measured density of a CsCl crystal is 3.988...Ch. 9 - What is the difference in energy between the...Ch. 9 - An electron is confined to a metal cube of I = 0.8...Ch. 9 - What value of energy corresponds to a density of...Ch. 9 - Compare the density of states at 2.5 eV and 0.25...Ch. 9 - Consider a cube of copper with edges 1.50 mm long....Ch. 9 - If there is one free electron per atom of copper,...Ch. 9 - Determine the Fermi energy and temperature for...Ch. 9 - For a one-dimensional crystal, write the lattice...Ch. 9 - What is the main difference between an insulator...Ch. 9 - What is the longest wavelength for a photon that...Ch. 9 - A valence electron in a crystal absorbs a photon...Ch. 9 - An experiment is performed to demonstrate the Hall...Ch. 9 - Suppose that the cross-sectional area of the strip...Ch. 9 - A current-carrying copper wire with cross-section...Ch. 9 - The Hall effect is demonstrated in the laboratory....Ch. 9 - Show that for V less than zero, InetI0.Ch. 9 - A p-n diode has a reverse saturation current...Ch. 9 - The collector current of a transistor is 3.4 A for...Ch. 9 - Applying the positive end of a battery to the...Ch. 9 - The base current of a transistor is 4.4 A, and its...Ch. 9 - At what temperature, in terms of Tc, is the...Ch. 9 - What is the critical magnetic field for lead at T...Ch. 9 - A Pb wire wound in a tight solenoid of diameter of...Ch. 9 - A tightly wound solenoid at 4.0 K is 50 cm long...Ch. 9 - Potassium fluoride (KF) is a molecule formed by...Ch. 9 - For the preceding problem, sketch the potential...Ch. 9 - The separation between hydrogen atoms in a H2...Ch. 9 - The characteristic energy of the Cl2 molecule is...Ch. 9 - Determine the lowest three rotational energy...Ch. 9 - A carbon atom can hybridize in the...Ch. 9 - List five main characteristics of ionic crystals...Ch. 9 - Why is bonding in favorable? Express your answer...Ch. 9 - Astronomers claim to find evidence of He2 from...Ch. 9 - Show that the moment of inertia of a diatomic...Ch. 9 - Show that the average energy of an electron in a...Ch. 9 - Measurements of a superconductor's critical...Ch. 9 - Estimate the fraction of Si atoms that must be...Ch. 9 - Transition in the rotation spectrum are observed...Ch. 9 - Determine the Fermi energies for (a) Mg, (b) Na,...Ch. 9 - Find the average energy of an electron in a Zn...Ch. 9 - What value of the repulsion constant, n, gives the...Ch. 9 - A physical model of a diamond suggests packing...Ch. 9 - For an electron in a three-dimensional metal, show...
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Similar questions
- One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. For the H2 molecule, take A = 0.124 x 10-120 eV ⋅ m12 and B = 1.488 x 10-60 eV ⋅ m6. Find (a) the separation distance r0 at which the energy of the molecule is a minimum and (b) the energy E required to break up theH2 molecule.arrow_forwardplease asaparrow_forwardIn solid KCI the smallest distance between the centers of a. potassium ion and a chloride ion is 314 pm. Calculate the length of the edge of the unit cell and the density of KCI, assuming it has the same structure as sodium chloride.arrow_forward
- In vibrational spectroscopy, the fundamental band refers to a transition from the n = 0 state to n = 1, and the first overtone would be from the n = 0 state to n = 2. For carbon monoxide (CO), the fundamental occurs at 2143.4 cm-¹ and the first overtone at 4259.6 cm-¹. (a) For an anharmonic oscillator, the energy levels can be written (in wavenumbers) as 2 En ) ²³ = ve (n + ¹) - xeve (n +. + Find the values of ve and xeve from the fundamental and overtone transitions in CO. Report your results in units of cm-¹. (b) Use the values found for ve and xeve in part (a) to estimate the number of bound energy levels in CO. (Hint: For an anharmonic oscillator this number is determined by the point at which the spacing between consecutive levels goes to zero.) (c) If CO could be modeled as a Morse oscillator, and the values of ve and xeve provide energy levels consistent with the Morse potential what would be the value of the parameter D in units of cm-¹? How does this compare with the observed…arrow_forwardIn this question, we will consider the vibration of the diatomic molecule, H2, found in an eigenstate whose wave function is 1/4 1 p(x) V48 \T where a = ku/ħ. k is the force constant and u is the reduced mass. The vibrational frequency of H2 is 4401 cm-'. а) How many nodes are present in p(x)? b) What is the quantum number that characterizes p(x)? c) Calculate the vibrational energy of the H2 molecule when it is described by the eigenfunction p(x).arrow_forwardThe angular frequency of vibrations in a one-dimensional monatomic crystal are given by where w (k) = 4K m sin k = ka 2 2π λ is the wavenumber of the vibration pattern in terms of its wavelength >, the spring constant between neighbouring atoms, and m the mass of each atom. (i) Show that the frequency does not change if one shifts 2π k→ k +. a (ii) Briefly explain the physical reason for this periodicity.arrow_forward
- Consider a Face Centered Cubic (FCC) lattice structured Nickel crystal. We are looking to find the surface energy of the new surface that is formed after it is sliced at the (100) plane. a- Find the value of R as function of the lattice constant a. 4R Oa = 2R Oa = 4R Oa = = 2/2R V2 Find the area A11 of (111) surface as function of R. 04R? O16R? O8R? OR? How many atoms lie on the plane (111) within the unit cell? N111 = atoms within the unit cell Find the number of atoms per unit surface area. 2 2 R2 8R2 16R? 4R? Which of the following represents the expression of the surface energt? ON BEPAarrow_forwardQ#04. (a) Calculate the number of atoms per unit area in (100), (110) and (111) planes of in bcc crystal with the lattice parameter of 2.5 angstrom.arrow_forwardAssume the distance between the protons in the H2 molecule is 0.750 x 10-10 m. (a) Find the energy of the first excited rotational state, with J = 1. (b) Find the wavelength of radiation emitted in the transition from J = 1 to J = 0.arrow_forward
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