Concept explainers
The structure of borazine, B3N3H6, is a six-membered ring of altemating B and N atoms. There is one H atom bonded to each B and to each N atomThe molecule is planar.
a. Wrlte a Lewis structure for borazine in Which the formal charge on every atom is zero,
b. Write a Lewis structure for borazine in which the octet rule is satisfied for every atom.
c. What are the formal charges on the atoms in the Lewis structure from part (b)? Given the
electronegativites of B and N, do the formal charges seem favorable or unfavorable?
d. Do either of the Lewis structures in parts (a) and (b) have multiple resonance structures?
e. What are the hybridizations at the B and N atoms in the Lewis structures from parts (a) and (b)? Would you expect the molecule to be planar for both Lewis structures?
f. The six bonds in the borazine molecule are all identical in length at 1.44 A Typical values for the bond lengths Of single and double bonds are 1.51 and 1.31 A, respectively Does the value of the BiN bond length seem to favor one Lewis structure over the other?
g. How many electrons are in the r system of borazine?
Want to see the full answer?
Check out a sample textbook solutionChapter 9 Solutions
Chemistry: The Central Science (14th Edition)
- These are NOTlegitimate Lewisstructures (and aremissing formalcharges). Show (as inthe example) how apair of electrons canbe moved to make theLewis structurelegitimate.arrow_forward7.50 Chemical species are said to be isoelectronic if they have the same Lewis structure (regardless of charge). Consider these ions and write a Lewis structure for a neutral molecule that is isoelectronic with each of them, (a) CN , (b) NH4+ . (c) CO32arrow_forwardWrite Lewis structures for the following: (a) ClF3 (b) PCl5 (c) BF3 (d) PF6arrow_forward
- The molecular ion S3N3 has the cyclic structure All SN bonds are equivalent. (a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion. (b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams. (c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b). (d) An advanced calculation suggests that the actual charge resident on each N atom is 0.375 and on each S atom is +0.041 . Show that this result is consistent with the overall +1 charge on the molecular ion.arrow_forwardChloromethane has the Lewis structure _______________________________ The carbon atom is sharing 4 electron pairs. In each shared pair the carbon atom “owns” 1 electron. The number of electrons that “belong” to carbon is ___. Carbon, being a Group ___ element would have 4 , outer shell electrons in the unbonded, neutral state. Therefore, the carbon atom in chloromethane has a formal charge of zero.arrow_forwardGiven the bonds C N, C H, C Br, and S O, (a) which atom in each is the more electronegative? (b) which of these bonds is the most polar?arrow_forward
- Write Lewis structures for the following: (a) O2 (b) H2CO (c) AsF3 (d) ClNO (e) SiCl4 (f) H3O+ (g) NH4+ (h) BF4 (i) HCCH (j) ClCN (k) C22+arrow_forwardG. N. Lewis developed a model for chemical bonding that you have learned in this chapter. His theory was extremely successful and is used today at all levels of chemistry, from the introductory class to the research laboratory. Why was Lewis theory so successful?arrow_forwardDraw resonance structures for each of these ions: NSO− and SNO−. (The atoms are bonded in the order given in each case, that is, S is the central atom in NSO−.) Use formal charges to determine which ion is likely to be more stable. Explain why the two ions cannot be considered resonance structures of each other.arrow_forward
- Based on the concept of formal charge, what is the central atom in (a) HCN (do not include H as a possibility)? b) NOCI (Cl is always a terminal atom)?arrow_forwardTwo arrangements of atoms are possible for a compound with a molar mass of about 45 g/mol that contains 52.2% C, 13.1% H, and 34.7% 0 by mass. Write the Lewis structures for the two molecules.arrow_forwardIn Section 12.10 of your text, the term “effective pairs" is used. What does this mean?arrow_forward
- Chemical Principles in the LaboratoryChemistryISBN:9781305264434Author:Emil Slowinski, Wayne C. Wolsey, Robert RossiPublisher:Brooks ColePrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning