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Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 8.7, Problem 8.58PP
A gas mixture containing oxygen, nitrogen, and neon exerts a total pressure of 1.20 atm. If helium added to the mixture increases the pressure to 1.50 atm, what is the partial pressure, in atmospheres, of the helium?
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
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21.6
172.0
17
181.0
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183.0
197.0
100.0
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784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 8 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 8.1 - Prob. 8.1PPCh. 8.1 - Use the kinetic molecular theory of gases to...Ch. 8.1 - Identify the property of a gas that is measured in...Ch. 8.1 - Identify the property of a gas that is measured in...Ch. 8.1 - Prob. 8.5PPCh. 8.1 - Prob. 8.6PPCh. 8.1 - Prob. 8.7PPCh. 8.1 - On a climb up Mount Whitney, the atmospheric...Ch. 8.2 - Why do scuba divers need to exhale air when they...Ch. 8.2 - Why does a sealed bag of chips expand when you...
Ch. 8.2 - The air in a cylinder with a piston has a volume...Ch. 8.2 - A balloon is filled with helium gas. When each of...Ch. 8.2 - Prob. 8.13PPCh. 8.2 - Prob. 8.14PPCh. 8.2 - A 10.0-L balloon contains helium gas at a pressure...Ch. 8.2 - Prob. 8.16PPCh. 8.2 - A sample of nitrogen N2 has a volume of 50.0 L at...Ch. 8.2 - A sample of methane CH4 has a volume of 25 mL at a...Ch. 8.2 - A sample of Ar gas has a volume of 5.40 L with an...Ch. 8.2 - A sample of Ne gas has a pressure of 654 mmHg with...Ch. 8.2 - Prob. 8.21PPCh. 8.2 - A patient’s oxygen tank holds 20.0 L of oxygen O2...Ch. 8.2 - Prob. 8.23PPCh. 8.2 - Prob. 8.24PPCh. 8.3 - Select the diagram that shows the final volume of...Ch. 8.3 - Indicate whether the final volume of gas in each...Ch. 8.3 - A sample of neon initially has a volume of 2.50 L...Ch. 8.3 - Prob. 8.28PPCh. 8.3 - A balloon contains 2500 ml- of helium gas at 75C ....Ch. 8.3 - Prob. 8.30PPCh. 8.3 - A gas sample has a volume of 0.256 L with an...Ch. 8.3 - Prob. 8.32PPCh. 8.4 - Prob. 8.33PPCh. 8.4 - Prob. 8.34PPCh. 8.4 - Calculate the final temperature, in degrees...Ch. 8.4 - Calculate the final temperature, in degrees...Ch. 8.4 - A gas sample has a pressure of 744 mmHg when the...Ch. 8.4 - Prob. 8.38PPCh. 8.4 - A tank contains isoflurane, an inhaled anesthetic,...Ch. 8.4 - Bacteria and viruses are inactivated by...Ch. 8.5 - Prob. 8.41PPCh. 8.5 - Prob. 8.42PPCh. 8.5 - Prob. 8.43PPCh. 8.5 - A sample of argon gas has a volume of 735 mL at a...Ch. 8.5 - A 124-mL bubble of hot gas initially at 212 °C and...Ch. 8.5 - A scuba diver 60 ft below the ocean surface...Ch. 8.6 - What happens to the volume of a bicycle tire or a...Ch. 8.6 - Prob. 8.48PPCh. 8.6 - Prob. 8.49PPCh. 8.6 - Prob. 8.50PPCh. 8.6 - Prob. 8.51PPCh. 8.6 - Prob. 8.52PPCh. 8.7 - A typical air sample in the lungs contains oxygen...Ch. 8.7 - Prob. 8.54PPCh. 8.7 - Prob. 8.55PPCh. 8.7 - In a gas mixture, the partial pressures are argon...Ch. 8.7 - A gas mixture containing oxygen, nitrogen, and...Ch. 8.7 - A gas mixture containing oxygen, nitrogen, and...Ch. 8.7 - Prob. 8.59PPCh. 8.7 - Prob. 8.60PPCh. 8.7 - Prob. 8.61PPCh. 8.7 - Prob. 8.62PPCh. 8 - Two flasks of equal volume and at the same...Ch. 8 - Prob. 8.64UTCCh. 8 - At 100 °C, which of the following diagrams (1, 2,...Ch. 8 - Indicate which diagram (1, 2, or 3) represents the...Ch. 8 - A balloon is filled with helium gas with a partial...Ch. 8 - Prob. 8.68UTCCh. 8 - Prob. 8.69UTCCh. 8 - Prob. 8.70UTCCh. 8 - Prob. 8.71APPCh. 8 - Prob. 8.72APPCh. 8 - Prob. 8.73APPCh. 8 - Prob. 8.74APPCh. 8 - A weather balloon has a volume of 750 L when...Ch. 8 - Prob. 8.76APPCh. 8 - A weather balloon is partially filled with Helium...Ch. 8 - Prob. 8.78APPCh. 8 - A gas mixture contains Oxygen and Argon at partial...Ch. 8 - Prob. 8.80APPCh. 8 - Prob. 8.81CPCh. 8 - You are doing research on planet X. The...Ch. 8 - Prob. 8.83CPCh. 8 - Prob. 8.84CP
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
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