a) Interpretation: The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene is to be given. Concept introduction: Alkenes react with H 2 in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene. To give: The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene.

Question

5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

Answer 1

Question

Chapter 8.6, Problem 12P

Interpretation Introduction

a)

Interpretation:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene.

Interpretation Introduction

c)

Interpretation:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?

13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…

Answer 2

Question

Chapter 8.6, Problem 12P

Interpretation Introduction

a)

Interpretation:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene.

Interpretation Introduction

c)

Interpretation:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 8.6, Problem 12P

Interpretation Introduction

a)

Interpretation:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene.

Interpretation Introduction

c)

Interpretation:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 8.6, Problem 12P

Interpretation Introduction

a)

Interpretation:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene.

Interpretation Introduction

c)

Interpretation:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 8.6, Problem 12P

Interpretation Introduction

a)

Interpretation:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene.

Interpretation Introduction

c)

Interpretation:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene.

Answer 6

Chapter 8.6, Problem 12P

Interpretation Introduction

a)

Interpretation:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene.

Answer 7

Chapter 8.6, Problem 12P

Interpretation Introduction

a)

Interpretation:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 2-methyl-2-pentene.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3,3-dimethylcyclopentene.

Answer 10

Interpretation Introduction

c)

Interpretation:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene.

Answer 11

Interpretation Introduction

c)

Interpretation:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene is to be given.

Concept introduction:

Alkenes react with H₂ in the presence of metal catalysts such as palladium or platinum to yield the corresponding alkanes as the products. The addition occurs with syn stereochemistry. Normally only a single product is produced as the catalyst will interact only from the least hindered and most accessible face of the alkene.

To give:

The product obtained by the catalytic hydrogenation of 3-tert-butylcyclohexene.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 15

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 16

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 17

Trending nowThis is a popular solution!

Answer 18

Trending nowThis is a popular solution!

Answer 19

Trending nowThis is a popular solution!

Answer 20

Trending now

Answer 21

This is a popular solution!

Answer 22

See solution

Check out sample textbook solution

Answer 23

Ch. 8.1 - Prob. 1P Ch. 8.1 - How many alkene products, including E,Z isomers,...Ch. 8.2 - Prob. 3P Ch. 8.2 - Addition of HCl to 1, 2-dimethylcyclohexene yields...Ch. 8.3 - Prob. 5P Ch. 8.3 - Prob. 6P Ch. 8.4 - Prob. 7P Ch. 8.4 - From what alkenes might the following alcohols...Ch. 8.5 - Prob. 9P Ch. 8.5 - What alkenes might be used to prepare the...

Concept explainers

Chapter 8 Solutions