Concept explainers
(a)
Interpretation: The building blocks which represents the sphingosine residues in the given block diagram of sphingoglycolipid have to be predicted.
Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
(b)
Interpretation: The building blocks which represents the mono- or oligosaccharide residues in the given block diagram of sphingoglycolipid have to be predicted.
Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
(c)
Interpretation: The linkage which represents the glycosidic linkage in the given block diagram of sphingoglycolipid has to be predicted.
Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
(d)
Interpretation: The linkages which involve both sphingosine and fatty acid residues in the given block diagram of sphingoglycolipid have to be predicted.
Concept introduction: The lipid that is composed of one fatty acid and one carbohydrate unit which is joined to a sphingosine molecule is known as sphingoglycolipid. The fatty acid of sphingoglycolipid is also joined to the sphingosine molecule with the help of amide linkage. The carbohydrate unit joined to a sphingosine molecule with the help of glycosidic linkage.
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Chapter 8 Solutions
Organic And Biological Chemistry
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- . (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forwardWhich carbocation is more stable?arrow_forwardAre the products of the given reaction correct? Why or why not?arrow_forward
- The question below asks why the products shown are NOT the correct products. I asked this already, and the person explained why those are the correct products, as opposed to what we would think should be the correct products. That's the opposite of what the question was asking. Why are they not the correct products? A reaction mechanism for how we arrive at the correct products is requested ("using key intermediates"). In other words, why is HCl added to the terminal alkene rather than the internal alkene?arrow_forwardMy question is whether HI adds to both double bonds, and if it doesn't, why not?arrow_forwardStrain Energy for Alkanes Interaction / Compound kJ/mol kcal/mol H: H eclipsing 4.0 1.0 H: CH3 eclipsing 5.8 1.4 CH3 CH3 eclipsing 11.0 2.6 gauche butane 3.8 0.9 cyclopropane 115 27.5 cyclobutane 110 26.3 cyclopentane 26.0 6.2 cycloheptane 26.2 6.3 cyclooctane 40.5 9.7 (Calculate your answer to the nearest 0.1 energy unit, and be sure to specify units, kJ/mol or kcal/mol. The answer is case sensitive.) H. H Previous Nextarrow_forward
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