Macroscale and Microscale Organic Experiments
7th Edition
ISBN: 9781305577190
Author: Kenneth L. Williamson, Katherine M. Masters
Publisher: Brooks Cole
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Chapter 8, Problem 6Q
Arrange the following in order of increasing
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When 2-Methylpropene undergoes oxidation in the
presence of acidic K2Cr2O7, the products obtained are
CH3 – CH + CO2
CH3 — СH — С—ОН-СО,
CH, -C =0+CO2 +H2O
CH3
CH; – CH2 – CH + CO2 + H20
Clear Response
III
CrO3
CH3CH2CH2OH
CH3CH2COH
CH3CH2COCH2CH2CH3
A problem often encountered in the oxidation of primary alcohols is that esters are sometimes produced as by-products. For example, oxidation of propyl alcohol yields
propanoic acid and propyl propanoate.
Draw curved arrows to show the movement of electrons in this step of the reaction mechanism.
Arrow-pushing Instructions
B:
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CH3CH2CH-
A:
BH*
CH;CH,CH
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H-A
Chemistry:
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SAM reacts with nucleophiles in an SN2-like reaction in our body for a variety of
important biosynthetic reactions. Below on the molecule of SAM, please circle and
label which part of the molecule would act as the electrophile, and which part of the
molecule is the leaving group. (5 pts)
HO
NH2
NH2
N
N
CH 3
N
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+
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S-Adenosyl methionine
Chapter 8 Solutions
Macroscale and Microscale Organic Experiments
Ch. 8 - Prob. 1QCh. 8 - Prob. 2QCh. 8 - What problem will ensue if the level of the...Ch. 8 - Prob. 4QCh. 8 - Prob. 5QCh. 8 - Arrange the following in order of increasing Rf...Ch. 8 - What will be the result of applying too much...Ch. 8 - Prob. 8QCh. 8 - Prob. 9QCh. 8 - A TLC plate showed two spots with Rf values of...
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