The resonance contributors for the cyclooctatrienyldianion has to be investigated. Concept Introduction: Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure. Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds. Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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Answer 1

Question

Chapter 8, Problem 107P

(a)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyldianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyl dianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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a. HN02 H12504 b. draw the resonance C. Which resonance Structure is most stable ? would react faster than tollene at 400°C. Wing?

Draw the resonance contributors of the cyclooctatrienyl dianion. a. Which of the resonance contributors is the least stable? b. Which of the resonance contributors makes the smallest contribution to the hybrid

a. Rank in order of S,2 reactivity (1= most reactive) b. Rank in order of leaving group ability (1= best leaving group) NH2 H20 cr c. Rank in order of nucleophilicity (1= best nucleophile) он Draw hypothetical reaction coordinate diagrams for: (a) An endergonic, two-step reaction with the first step being the rate- determining step. (b) A reaction with three transition states and DG > 0.

Answer 2

Question

Chapter 8, Problem 107P

(a)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyldianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyl dianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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Answer 3

Question

Chapter 8, Problem 107P

(a)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyldianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyl dianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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Answer 4

Question

Chapter 8, Problem 107P

(a)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyldianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyl dianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

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Answer 5

Chapter 8, Problem 107P

(a)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyldianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

(b)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyl dianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 6

Chapter 8, Problem 107P

(a)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyldianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 7

Chapter 8, Problem 107P

(a)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyldianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyl dianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The resonance contributors for the cyclooctatrienyl dianion has to be investigated.

Concept Introduction:

Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.

Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.

Resonance hybrid: the actual structure with delocalized electrons is called a resonance hybrid.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 5P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 7P Ch. 8.6 - Prob. 8P Ch. 8.8 - Prob. 9P Ch. 8.9 - Prob. 10P Ch. 8.9 - Prob. 12P

Solution Summary: The author explains that the resonance contributors for the cyclooctatrienyl dianion have to be investigated.

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