(a) Interpretation: The structures of two optically active stereoisomers of 1 , 2 , 3 , 4 , 5 , 6 -hexachlorocyclohexane that could be isolated under ordinary conditions are to be predicted. Concept introduction: A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also termed as asymmetric or stereo-genic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

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Answer 1

Question

Chapter 7, Problem 7.58AP

Interpretation Introduction

(a)

Interpretation:

The structures of two optically active stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane that could be isolated under ordinary conditions are to be predicted.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also termed as asymmetric or stereo-genic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The structures of two stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane for which the chair interconversion results in identical molecules are to be predicted.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation.

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Answer 2

Question

Chapter 7, Problem 7.58AP

Interpretation Introduction

(a)

Interpretation:

The structures of two optically active stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane that could be isolated under ordinary conditions are to be predicted.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also termed as asymmetric or stereo-genic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The structures of two stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane for which the chair interconversion results in identical molecules are to be predicted.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation.

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Answer 3

Question

Chapter 7, Problem 7.58AP

Interpretation Introduction

(a)

Interpretation:

The structures of two optically active stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane that could be isolated under ordinary conditions are to be predicted.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also termed as asymmetric or stereo-genic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The structures of two stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane for which the chair interconversion results in identical molecules are to be predicted.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation.

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Answer 4

Question

Chapter 7, Problem 7.58AP

Interpretation Introduction

(a)

Interpretation:

The structures of two optically active stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane that could be isolated under ordinary conditions are to be predicted.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also termed as asymmetric or stereo-genic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The structures of two stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane for which the chair interconversion results in identical molecules are to be predicted.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation.

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Answer 5

Chapter 7, Problem 7.58AP

Interpretation Introduction

(a)

Interpretation:

The structures of two optically active stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane that could be isolated under ordinary conditions are to be predicted.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also termed as asymmetric or stereo-genic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The structures of two stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane for which the chair interconversion results in identical molecules are to be predicted.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation.

Answer 6

Chapter 7, Problem 7.58AP

Interpretation Introduction

(a)

Interpretation:

The structures of two optically active stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane that could be isolated under ordinary conditions are to be predicted.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also termed as asymmetric or stereo-genic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Answer 7

Chapter 7, Problem 7.58AP

Interpretation Introduction

(a)

Interpretation:

The structures of two optically active stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane that could be isolated under ordinary conditions are to be predicted.

Concept introduction:

A carbon atom that has four nonequivalent atoms or groups attached to it is known as the chiral carbon atom. Chiral carbon centers are also termed as asymmetric or stereo-genic centers. The chiral atom sometimes results in the formation of enantiomers which are the non-superimposable mirror images of each other.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structures of two stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane for which the chair interconversion results in identical molecules are to be predicted.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structures of two stereoisomers of 1,2,3,4,5,6-hexachlorocyclohexane for which the chair interconversion results in identical molecules are to be predicted.

Concept introduction:

The conformation of cyclohexane is a type of 3−D shape of cyclohexane molecule. There are total four types of significant conformations of cyclohexane exists which are chair conformation, half-chair conformation, boat conformation and twist-boat conformation.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

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